Preparation and Evaluation of Glucose Based Non-Isocyanate Polyurethane Self-Blowing Rigid Foams
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Synthesis of the Glucose Based Non-Isocyanate Polyurethane(g-NIPU)
2.3. Preparation of NIPU Foams
2.4. FTIR
2.5. MALDI-TOF Analysis
2.6. Water Absorption (24 h)
2.7. Compression
2.8. Ignition Test
3. Results and Discussion
3.1. Effect of Amount of Maleic Acid Addition on Performance of the Foams
3.2. Effect of Glutaraldehyde Addition Amounts on Basic Performance of Foams
3.3. Foam Compression Resistance
3.4. SEM Analysis
3.5. FTIR Analysis
3.6. MALDI ToF Analysis
4. Conclusions
Author Contributions
Acknowledgments
Conflicts of Interest
References
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No. | g-NIPU (g) | Maleic Acid (g) | Glutaraldehyde (g) |
---|---|---|---|
F2 | 10 | 1.0 | 2.5 |
F3 | 10 | 1.2 | 2.5 |
F4 | 10 | 1.5 | 2.5 |
F5 | 10 | 1.2 | 1.8 |
F6 | 10 | 1.2 | 3.6 |
No. | Formulations | Density (g/cm3) | 2 h Water Absorption (%) | Ignition Time (s) |
---|---|---|---|---|
F2 | 10 g g-NIPU + 1.0 g MA + 2.5 g G | 0.13 | 352.6 | 140 |
F3 | 10 g g-NIPU + 1.2 g MA + 2.5 g G | 0.09 | 279.3 | 120 |
F4 | 10 g g-NIPU + 1.5 g MA + 2.5 g G | 0.08 | 276.9 | 88 |
F5 | 10 g g-NIPU + 1.2 g MA + 1.8 g G | 0.10 | 253.5 | 130 |
F6 | 10 g g-NIPU + 1.2 g MA + 3.6 g G | 0.13 | 332.4 | 175 |
236.9 Da (calc. 237) = Small molecule of maleic acid reacts with hexamethylenediamine with 23 (Na+) |
322 Da (calc. 322) = molecule of urethane structure of “glucose–carbonate–diamine” without Na+ |
409–411 Da (calc. 410) = reaction results of two molecules “maleic acid–diamine” without Na+ |
422 Da = 322Da react with glutaraldehyde without Na+ |
520 Da = 422 Da react with diamine without Na+ |
528 Da = urethane structure of “glucose–carbonate–diamine–carbonate–glucose” without Na+ |
541 Da = molecule of “glucose–carbonate–diamine–maleic acid–diamine” with Na+ |
564 Da = urethane structure of “glucose–carbonate–diamine–carbonate–diamine” with one aldehyde without Na+ |
618 Da = molecule of “glucose–carbonate–diamine–aldehyde–diamine–maleic acid” without Na+ |
644 Da = molecule of “glucose–2×carbonate–2×diamine–aldehyde–maleic acid” without Na+ |
731 Da = molecule of” 2×glucose–carbonate–diamine” connected with aldehyde as a bridge, with Na+ |
858 Da = Dendrimer of “glucose–2×carbonate–4×diamine–aldehyde–maleic acid” without Na+ |
873 Da = 731 Da react with carbonate and diamine, without Na+ |
1019 Da = 873 Da react with one aldehyde, with Na+ |
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Xi, X.; Pizzi, A.; Gerardin, C.; Lei, H.; Chen, X.; Amirou, S. Preparation and Evaluation of Glucose Based Non-Isocyanate Polyurethane Self-Blowing Rigid Foams. Polymers 2019, 11, 1802. https://doi.org/10.3390/polym11111802
Xi X, Pizzi A, Gerardin C, Lei H, Chen X, Amirou S. Preparation and Evaluation of Glucose Based Non-Isocyanate Polyurethane Self-Blowing Rigid Foams. Polymers. 2019; 11(11):1802. https://doi.org/10.3390/polym11111802
Chicago/Turabian StyleXi, Xuedong, Antonio Pizzi, Christine Gerardin, Hong Lei, Xinyi Chen, and Siham Amirou. 2019. "Preparation and Evaluation of Glucose Based Non-Isocyanate Polyurethane Self-Blowing Rigid Foams" Polymers 11, no. 11: 1802. https://doi.org/10.3390/polym11111802