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Polymers 2018, 10(12), 1324; https://doi.org/10.3390/polym10121324

Inclusion Complexes of Citronella Oil with β-Cyclodextrin for Controlled Release in Biofunctional Textiles

1
Institute of Textile Research and Cooperation of Terrassa, Polytechnic University of Catalonia, C/Colom 15, Terrassa, 08222 Barcelona, Spain
2
Textile Engineering, Federal University of Technology—Paraná, 635 Marcilio Dias St., Apucarana 86812-460, Parana, Brazil
*
Authors to whom correspondence should be addressed.
Received: 3 October 2018 / Revised: 23 November 2018 / Accepted: 26 November 2018 / Published: 29 November 2018
(This article belongs to the Special Issue Polymer Processing for Enhancing Textile Application)
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Abstract

Biofunctional textiles with integrated drug-delivery systems can help in the fight against vector-borne diseases. The use of repellent agents derived from plants and oils is an alternative to DEET (N,N-diethyl-m-methylbenzamide), which has disadvantages that include toxic reactions and skin damage. However, some researchers report that oils can be ineffective due to reasons related to uncontrolled release. In this work, the mechanism of control of citronella oil (OC) complexed with β-cyclodextrin (βCD) on cotton (COT) and polyester (PES) textiles was investigated. The results obtained reveal that finishing cotton and polyester with β-cyclodextrin complexes allows for control of the release mechanism of the drug from the fabric. To assess the complexes formed, optical microscopy, SEM, and FTIR were carried out; the yield of complex formation was obtained by spectroscopy in the ultraviolet region; and controlled release was performed in vitro. Oil complexation with βCD had a yield of 63.79%, and it was observed that the release, which was in seconds, moved to hours when applied to fabrics. The results show that complexes seem to be a promising basis when it comes to immobilizing oils and controlling their release when modified with chemical crosslinking agents. View Full-Text
Keywords: textile finishing; biopolymers; esterification; cotton; polyester; drug delivery textile finishing; biopolymers; esterification; cotton; polyester; drug delivery
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
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Lis, M.J.; García Carmona, Ó.; García Carmona, C.; Maestá Bezerra, F. Inclusion Complexes of Citronella Oil with β-Cyclodextrin for Controlled Release in Biofunctional Textiles. Polymers 2018, 10, 1324.

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