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Polymers 2018, 10(10), 1140; https://doi.org/10.3390/polym10101140

π-Stacked Polymer Consisting of a Pseudo–meta–[2.2]Paracyclophane Skeleton

1
Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan
2
Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan
*
Author to whom correspondence should be addressed.
Received: 27 August 2018 / Revised: 26 September 2018 / Accepted: 2 October 2018 / Published: 12 October 2018
(This article belongs to the Special Issue π-Stacked Polymers)
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Abstract

A novel π-stacked polymer based on a pseudo–meta–linked [2.2]paracyclophane moieties was synthesized by Sonogashira-Hagihara coupling. The UV-vis absorption spectra of the synthesized polymer and model compounds revealed an extension of the conjugation length owing to the through-space conjugation. The optical properties of the π-stacked dimer with the pseudo–meta–linked [2.2]paracyclophane unit were compared with those of the corresponding dimers with the pseudo–ortho– and pseudo–para–linked [2.2]paracyclophane units. View Full-Text
Keywords: [2.2]paracyclophane; π-stacked polymer; through-space conjugation [2.2]paracyclophane; π-stacked polymer; through-space conjugation
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Maeda, H.; Kameda, M.; Hatakeyama, T.; Morisaki, Y. π-Stacked Polymer Consisting of a Pseudo–meta–[2.2]Paracyclophane Skeleton. Polymers 2018, 10, 1140.

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