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Communication

π-Stacked Polymer Consisting of a Pseudo–meta–[2.2]Paracyclophane Skeleton

1
Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan
2
Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan
*
Author to whom correspondence should be addressed.
Polymers 2018, 10(10), 1140; https://doi.org/10.3390/polym10101140
Received: 27 August 2018 / Revised: 26 September 2018 / Accepted: 2 October 2018 / Published: 12 October 2018
(This article belongs to the Special Issue π-Stacked Polymers)
A novel π-stacked polymer based on a pseudo–meta–linked [2.2]paracyclophane moieties was synthesized by Sonogashira-Hagihara coupling. The UV-vis absorption spectra of the synthesized polymer and model compounds revealed an extension of the conjugation length owing to the through-space conjugation. The optical properties of the π-stacked dimer with the pseudo–meta–linked [2.2]paracyclophane unit were compared with those of the corresponding dimers with the pseudo–ortho– and pseudo–para–linked [2.2]paracyclophane units. View Full-Text
Keywords: [2.2]paracyclophane; π-stacked polymer; through-space conjugation [2.2]paracyclophane; π-stacked polymer; through-space conjugation
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MDPI and ACS Style

Maeda, H.; Kameda, M.; Hatakeyama, T.; Morisaki, Y. π-Stacked Polymer Consisting of a Pseudo–meta–[2.2]Paracyclophane Skeleton. Polymers 2018, 10, 1140. https://doi.org/10.3390/polym10101140

AMA Style

Maeda H, Kameda M, Hatakeyama T, Morisaki Y. π-Stacked Polymer Consisting of a Pseudo–meta–[2.2]Paracyclophane Skeleton. Polymers. 2018; 10(10):1140. https://doi.org/10.3390/polym10101140

Chicago/Turabian Style

Maeda, Hazuki, Mayu Kameda, Takuji Hatakeyama, and Yasuhiro Morisaki. 2018. "π-Stacked Polymer Consisting of a Pseudo–meta–[2.2]Paracyclophane Skeleton" Polymers 10, no. 10: 1140. https://doi.org/10.3390/polym10101140

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