Enhanced Adsorption of Bisphenol A from Aqueous Solution with 2-Vinylpyridine Functionalized Magnetic Nanoparticles
Abstract
:1. Introduction
2. Experimental Section
2.1. Chemicals
2.2. Syntheses of Fe3O4 Nanospheres
2.3. Preparation of γ-MPS-Modified Fe3O4 Nanospheres
2.4. Preparation of Fe3O4 Nanospheres Coated with 2-VP
2.5. Material Characterization
2.6. Batch Adsorption
2.7. HPLC Analysis
3. Results and Discussion
3.1. Characterization
3.2. Adsorption Equilibrium
3.3. Effect of Contact Time
3.4. Effect of Coexisting Ions and HA
3.5. Effect of pH
3.6. Effect of Environmental Matrix
3.7. Regeneration and Reuse
3.8. Comparison of BPA Adsorption on Mag-PVP with Other Adsorbents
4. Conclusions
Author Contributions
Acknowledgments
Conflicts of Interest
References
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Temperature (°C) | Langmuir Model | Freundlich Model | ||||
---|---|---|---|---|---|---|
Adsorbents | KL | Qm | R2 | KF | n | R2 |
Mag-PVP | 0.09 | 115.87 | 0.94 | 16.20 | 2.09 | 0.93 |
Fe3O4 nanospheres | 0.22 | 42.05 | 0.94 | 11.27 | 2.67 | 0.74 |
Water Samples | Deionized Water (D) | Tap Water (T) | Surface Water (S) | Effluent Water (E) |
---|---|---|---|---|
Temperature (°C) | 19.8 | 19.8 | 19.9 | 19.9 |
pH | 7.1 | 8.3 | 8.4 | 8.6 |
Conductivity (μS/cm) | 1.2 | 241.4 | 348.3 | 1120.3 |
Total organic carbon (mg/L) | 0 | 0.2 | 2.6 | 10.1 |
Name of Sorbent | pH | Temp. (°C) | Qm (mg/g) | Reference |
---|---|---|---|---|
Mag-PVP | 6–7 | 20 | 115.9 | Our study |
Porous carbon produced at 1000 from Moso bamboo | - | 23 | 41.8 | [41] |
AC purchased from Wako | - | 23 | 56.5 | [41] |
Modified CNTs | 6.0 | 7 | 70.0 | [42] |
Magnetic chitosan fly-ash-cenospheres | 7.0 | 20 | 31.9 | [18] |
Magnetic carbon nanotube | 6.2 | 25 | 45.3 | [17] |
Multi-walled carbon nanotube | 5.2 | 25 | 88.27 | [43] |
Magnetic particles MPDVB | 8.0 | 20 | 90.9 | [20] |
MAP-GBM | 7.0 | 20 | 324.0 | [44] |
Vc-GBM | 7.0 | 25 | 133.1 | [45] |
Graphene oxide | 6.0 | 25 | 87.8 | [46] |
KOH-activated tyre pyrolysis char | 6.5–7.5 | 25 | 123.0 | [47] |
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Li, Q.; Pan, F.; Li, W.; Li, D.; Xu, H.; Xia, D.; Li, A. Enhanced Adsorption of Bisphenol A from Aqueous Solution with 2-Vinylpyridine Functionalized Magnetic Nanoparticles. Polymers 2018, 10, 1136. https://doi.org/10.3390/polym10101136
Li Q, Pan F, Li W, Li D, Xu H, Xia D, Li A. Enhanced Adsorption of Bisphenol A from Aqueous Solution with 2-Vinylpyridine Functionalized Magnetic Nanoparticles. Polymers. 2018; 10(10):1136. https://doi.org/10.3390/polym10101136
Chicago/Turabian StyleLi, Qiang, Fei Pan, Wentao Li, Dongya Li, Haiming Xu, Dongsheng Xia, and Aimin Li. 2018. "Enhanced Adsorption of Bisphenol A from Aqueous Solution with 2-Vinylpyridine Functionalized Magnetic Nanoparticles" Polymers 10, no. 10: 1136. https://doi.org/10.3390/polym10101136