Kinetic, Isotherm, and Thermodynamic Studies for Ag(I) Adsorption Using Carboxymethyl Functionalized Poly(glycidyl methacrylate)
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. The Synthesis Process of Carboxymehyl Functionalized PGMA
2.3. Characterization
2.4. Adsorption Experiment
3. Results and Discussion
3.1. Characterization of BA-PGMA
3.2. Effect of Experimental Parameters on Adsorption of Ag(I)
3.2.1. Effect of pH
3.2.2. Effect of Time on Adsorption Capacity of Ag(I) and Kinetics
3.2.3. Effect of Initial Concentration of Ag(I) and Adsorption Isotherm
3.2.4. Selectivity of BA-PGMA for Ag(I)
3.2.5. Reuse Performance of BA-PGMA
3.2.6. Adsorption Mechanism of Ag(I) by BA-PGMA
3.2.7. Thermodynamic Studies
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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First-Order Model | Ka (g/(mg·min)) | Ue (mg/g) | R2 Reduced Chi-Square |
0.06 | 108.51 | 0.9124 12.75 | |
Second-Order Model | Kb (g/(mg·min)) | Ue (mg/g) | R2 Reduced Chi-Square |
8.20 | 116.84 | 0.9914 1.24 | |
Intra-Particle Diffusion Model | Kc (mg/(g·min1/2) | R2 | |
3.32 | 0.7993 |
Stage | Kc | R2 | C |
I | 11.46 | 0.9953 | 22.95 |
II | 2.16 | 0.8583 | 78.62 |
III | 0.03 | −0.8881 | 114.61 |
Freundlich | Kh | n | R2 Reduced Chi-Sqr |
79.02 | 8.19 | 0.8387 8.39 | |
Langmuir | Um (mg/g) | Ki | R2 Reduced Chi-Sqr |
163.46 | 0.08 | 0.9927 0.37 | |
Temkin | Kj | VT | R2 Reduced Chi-Sqr |
29.22 | 17.49 | 0.8747 6.52 | |
Hill | KL | N | R2 Reduced Chi-Sqr |
12.14 | 0.91 | 0.9848 0.78 | |
D-R | ω | E (kj/mol) | R2 Reduced Chi-Sqr |
0.0041 | 11.04 | 0.9974 0.13 |
Cα (mg/L) | RL |
---|---|
100 | 0.0808 |
150 | 0.0554 |
200 | 0.0421 |
300 | 0.0285 |
400 | 0.0215 |
500 | 0.0172 |
Sorbent | Um (mg/g) | Reference |
---|---|---|
Natural Clinoptilolites | 31.44 | [48] |
Active carbon | 32.80 | [49] |
Nanocelluloses and their phosphorylated derivatives | 56 | [50] |
MFT chelating resin | 60.05 | [51] |
Bentonite clay | 61.48 | [52] |
Ion-imprinted chitosan gel beads | 80.50 | [53] |
Ag+-imprinted chitosan gel bead | 89.20 | [54] |
Valonia tannin resin | 97.08 | [55] |
BA-PGMA | 157.05 | This work |
Coexisting Ions | Kf (mL/g) | K |
---|---|---|
Ag+ | 4097.0 | - |
Ni2+ | 81.3 | 50.4 |
Co2+ | 41.9 | 97.8 |
Zn2+ | 97.4 | 42.1 |
Cu2+ | 409.1 | 10.0 |
Initial Ag(I) Concentration | T (K) | ΔSθ (J∙K−1∙moL−1) | ΔHθ (kJ∙moL−1) | ΔGθ (kJ∙moL−1) |
---|---|---|---|---|
100 (mg/L) | 25 °C (298 K) | 163.95 | 28.22 | −20.68 |
35 °C (303 K) | −21.79 | |||
45 °C (313 K) | - | −23.19 | ||
200 (mg/L) | 25 °C (298 K) | 159.7 | 29.60 | −18.05 |
35 °C (303 K) | −19.25 | |||
45 °C (313 K) | - | −20.48 | ||
300 (mg/L) | 25 °C (298 K) | 147.73 | 27.52 | −16.50 |
35 °C (303 K) | −17.71 | |||
45 °C (313 K) | - | −18.74 |
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Zhao, J.; Wang, S.; Zhang, L.; Wang, C.; Zhang, B. Kinetic, Isotherm, and Thermodynamic Studies for Ag(I) Adsorption Using Carboxymethyl Functionalized Poly(glycidyl methacrylate). Polymers 2018, 10, 1090. https://doi.org/10.3390/polym10101090
Zhao J, Wang S, Zhang L, Wang C, Zhang B. Kinetic, Isotherm, and Thermodynamic Studies for Ag(I) Adsorption Using Carboxymethyl Functionalized Poly(glycidyl methacrylate). Polymers. 2018; 10(10):1090. https://doi.org/10.3390/polym10101090
Chicago/Turabian StyleZhao, Jiling, Shixing Wang, Libo Zhang, Chen Wang, and Bing Zhang. 2018. "Kinetic, Isotherm, and Thermodynamic Studies for Ag(I) Adsorption Using Carboxymethyl Functionalized Poly(glycidyl methacrylate)" Polymers 10, no. 10: 1090. https://doi.org/10.3390/polym10101090