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Polymers 2018, 10(10), 1049; https://doi.org/10.3390/polym10101049

Preparation and Characterization of DOPO-ITA Modified Ethyl Cellulose and Its Application in Phenolic Foams

1
College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China
2
Institute of Chemical Industry of Forestry Products, CAF, Nanjing 210042, China
3
Chinese Academy of Forestry, Beijing 100091, China
*
Author to whom correspondence should be addressed.
Received: 15 August 2018 / Revised: 14 September 2018 / Accepted: 17 September 2018 / Published: 20 September 2018
(This article belongs to the Special Issue Polymeric Foams)
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Abstract

In order to improve the performance of phenolic foam, an additive compound of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and Itaconic acid (ITA) were attached on the backbone of ethyl cellulose (EC) and obtained DOPO-ITA modified EC (DIMEC), which was used to modify phenolic resin and composite phenolic foams (CPFs). The structures of DOPO-ITA were verified by Fourier transform infrared spectroscopy (FT-IR) and nuclear magnetic resonance (1H NMR). The molecular structure and microstructure were characterized by FT-IR spectra and SEM, respectively. Compared with EC, the crystallinity of DIMEC was dramatically decreased, and the diffraction peak positions were basically unchanged. Additionally, thermal stability was decreased and Ti decreased by 24 °C. The residual carbon (600 °C) was increased by 25.7%. With the dosage of DIMEC/P increased, the Ea values of DIMEC composite phenolic resins were increased gradually. The reaction orders were all non-integers. Compared with PF, the mechanical properties, flame retardancy, and the residual carbon (800 °C) of CPFs were increased. The cell size of CPFs was less and the cell distribution was relatively regular. By comprehensive analysis, the suitable dosage of DIMEC/P was no more than 15%. View Full-Text
Keywords: DOPO; itaconic acid; ethyl cellulose; phenolic foams; composites DOPO; itaconic acid; ethyl cellulose; phenolic foams; composites
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
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Ma, Y.; Gong, X.; Liao, C.; Geng, X.; Wang, C.; Chu, F. Preparation and Characterization of DOPO-ITA Modified Ethyl Cellulose and Its Application in Phenolic Foams. Polymers 2018, 10, 1049.

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