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Crystals
Volume 9
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10.3390/cryst9100529
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Article

Trinodal Self-Penetrating Nets from Reactions of 1,4-Bis(alkoxy)-2,5-bis(3,2’:6’,3’’-terpyridin-4’-yl)benzene Ligands with Cobalt(II) Thiocyanate

by
Giacomo Manfroni
1,
Alessandro Prescimone
1,
Stuart R. Batten
2,
Y. Maximilian Klein
3,
Dariusz J. Gawryluk
3,
Edwin C. Constable
1 and
Catherine E. Housecroft
1,*
1
Department of Chemistry, University of Basel, BPR 1096, Mattenstrasse 24a, CH-4058 Basel, Switzerland
2
School of Chemistry, Monash University, Victoria 3800, Australia
3
Laboratory for Multiscale Materials Experiments, Paul Scherrer Institut, CH-5232 Villigen PSI, Switzerland
*
Author to whom correspondence should be addressed.
Crystals 2019, 9(10), 529; https://doi.org/10.3390/cryst9100529
Received: 27 September 2019 / Revised: 8 October 2019 / Accepted: 10 October 2019 / Published: 15 October 2019
(This article belongs to the Special Issue Synthesis, Crystal Structures and Hirshfeld Surface Analysis of Coordination Compounds)
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Abstract

The tetratopic ligands 1,4-bis(2-ethylbutoxy)-2,5-bis(3,2’:6’,3’’-terpyridin-4’-yl)benzene (1) and 1,4-bis(3-methylbutoxy)-2,5-bis(3,2’:6’,3’’-terpyridin-4’-yl)benzene (2) have been prepared and characterized by 1H and 13C{1H} NMR, IR, and absorption spectroscopies and mass spectrometry. Reactions of 1 and 2 with cobalt(II) thiocyanate under conditions of crystal growth at room temperature result in the formation of [{Co(1)(NCS)2}·MeOH·3CHCl3]n and [{Co(2)(NCS)2}·0.8MeOH·1.8CHCl3]n. Single-crystal X-ray diffraction reveals that each crystal lattice consists of a trinodal self-penetrating (62.84)(64.82)(65.8)2 net. The nodes are defined by two independent cobalt centres and the centroids of two crystallographically independent ligands which are topologically equivalent. View Full-Text
Keywords: three-dimensional network; self-penetration; 3,2’:6’,3’’-terpyridine; tetratopic ligand; cobalt(II) thiocyanate three-dimensional network; self-penetration; 3,2’:6’,3’’-terpyridine; tetratopic ligand; cobalt(II) thiocyanate
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited

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MDPI and ACS Style

Manfroni, G.; Prescimone, A.; Batten, S.R.; Klein, Y.M.; Gawryluk, D.J.; Constable, E.C.; Housecroft, C.E. Trinodal Self-Penetrating Nets from Reactions of 1,4-Bis(alkoxy)-2,5-bis(3,2’:6’,3’’-terpyridin-4’-yl)benzene Ligands with Cobalt(II) Thiocyanate. Crystals 2019, 9, 529. https://doi.org/10.3390/cryst9100529

AMA Style

Manfroni G, Prescimone A, Batten SR, Klein YM, Gawryluk DJ, Constable EC, Housecroft CE. Trinodal Self-Penetrating Nets from Reactions of 1,4-Bis(alkoxy)-2,5-bis(3,2’:6’,3’’-terpyridin-4’-yl)benzene Ligands with Cobalt(II) Thiocyanate. Crystals. 2019; 9(10):529. https://doi.org/10.3390/cryst9100529

Chicago/Turabian Style

Manfroni, Giacomo, Alessandro Prescimone, Stuart R. Batten, Y. M. Klein, Dariusz J. Gawryluk, Edwin C. Constable, and Catherine E. Housecroft 2019. "Trinodal Self-Penetrating Nets from Reactions of 1,4-Bis(alkoxy)-2,5-bis(3,2’:6’,3’’-terpyridin-4’-yl)benzene Ligands with Cobalt(II) Thiocyanate" Crystals 9, no. 10: 529. https://doi.org/10.3390/cryst9100529

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