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Article

Controllable Functionalization of Carbon Dots as Selective and Sensitive Fluorescent Probes for Sensing Cu(II) Ions

1
Department of Intelligent Manufacturing, Yantai Vocational College, Yantai 264670, China
2
Department of Optoelectronic Science, Harbin Institute of Technology at Weihai, Weihai 264209, China
3
Department of Intelligent Control, Yantai Vocational College, Yantai 264670, China
*
Authors to whom correspondence should be addressed.
These authors contributed equally to this work.
Crystals 2025, 15(3), 205; https://doi.org/10.3390/cryst15030205
Submission received: 21 January 2025 / Revised: 11 February 2025 / Accepted: 17 February 2025 / Published: 21 February 2025
(This article belongs to the Special Issue Research Progress of Photoluminescent Materials)

Abstract

Carbon dots (CDs) are efficient fluorescent probes for metal ion detection due to their high sensitivity, nontoxicity and stability, but their rich functional groups lead to simultaneous responses to multiple ions. So, how to realize highly selective detection for specific ions is still a challenging task. In this work, “bare CDs” were synthesized using the electrochemical stripping method, followed by grafting with hydroxyl and carboxyl groups following the hydrothermal method with boric acid. Transmission electron microscopy, an X-ray diffractometer, Fourier transform infrared spectroscopy, UV–visible spectrophotometers and a fluorescence spectrometer were used to characterize their morphology, surface functional groups and optical properties, respectively. The modified CDs exhibit a high sensitivity of 65% and selectivity towards Cu2+. Meanwhile, they also exhibited a short response time of less than 1 min and a good stability in terms of pH and ionic strength.
Keywords: fluorescent sensors; copper ion detection; functionalization; functional groups; quenching mechanism fluorescent sensors; copper ion detection; functionalization; functional groups; quenching mechanism

Share and Cite

MDPI and ACS Style

Zheng, X.; Zhang, H.; Jiang, H.; Sun, L.; Sun, Y.; Liu, Q.; Ren, S.; Zhuang, Y.; Gong, X. Controllable Functionalization of Carbon Dots as Selective and Sensitive Fluorescent Probes for Sensing Cu(II) Ions. Crystals 2025, 15, 205. https://doi.org/10.3390/cryst15030205

AMA Style

Zheng X, Zhang H, Jiang H, Sun L, Sun Y, Liu Q, Ren S, Zhuang Y, Gong X. Controllable Functionalization of Carbon Dots as Selective and Sensitive Fluorescent Probes for Sensing Cu(II) Ions. Crystals. 2025; 15(3):205. https://doi.org/10.3390/cryst15030205

Chicago/Turabian Style

Zheng, Xiaochun, Hao Zhang, Haoming Jiang, Lei Sun, Yuanze Sun, Qingcao Liu, Shoutian Ren, Yunpeng Zhuang, and Xiaofeng Gong. 2025. "Controllable Functionalization of Carbon Dots as Selective and Sensitive Fluorescent Probes for Sensing Cu(II) Ions" Crystals 15, no. 3: 205. https://doi.org/10.3390/cryst15030205

APA Style

Zheng, X., Zhang, H., Jiang, H., Sun, L., Sun, Y., Liu, Q., Ren, S., Zhuang, Y., & Gong, X. (2025). Controllable Functionalization of Carbon Dots as Selective and Sensitive Fluorescent Probes for Sensing Cu(II) Ions. Crystals, 15(3), 205. https://doi.org/10.3390/cryst15030205

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