The Complete Series of Lanthanoid-Chloranilato Lattices with Dimethylsulfoxide: Role of the Lanthanoid Size on the Coordination Number and Crystal Structure
Abstract
:1. Introduction
2. Materials and Methods
3. Results
3.1. Synthesis
3.2. Crystal Structure of [Ln2(C6O4Cl2)3(dmso)6] with Ln = La(1), Ce(2), Pr(3), Nd(4), Sm(5), Eu(6), Gd(7) and Tb(8)
3.3. Crystal Structure of [Ln2(C6O4Cl2)3(dmso)4]·2dmso·2H2O with Ln = Dy(9), Ho(10), Er(11), Tm(12) and Yb(13)
3.4. Magnetic Properties of Compounds 1–13
4. Discussion
5. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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HDC (mT) | A (K−1) | τ0 (s) | Ueff (K) |
---|---|---|---|
20 | 7.8(3) × 103 | 2(1) × 10−8 | 21(2) |
50 | 5.9(1) × 103 | 1.1(3) × 10−8 | 23(1) |
100 | 4.9(1) × 103 | 0.9(2) × 10−8 | 24(1) |
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Benmansour, S.; Gómez-García, C.J.; Hernández-Paredes, A. The Complete Series of Lanthanoid-Chloranilato Lattices with Dimethylsulfoxide: Role of the Lanthanoid Size on the Coordination Number and Crystal Structure. Crystals 2022, 12, 261. https://doi.org/10.3390/cryst12020261
Benmansour S, Gómez-García CJ, Hernández-Paredes A. The Complete Series of Lanthanoid-Chloranilato Lattices with Dimethylsulfoxide: Role of the Lanthanoid Size on the Coordination Number and Crystal Structure. Crystals. 2022; 12(2):261. https://doi.org/10.3390/cryst12020261
Chicago/Turabian StyleBenmansour, Samia, Carlos J. Gómez-García, and Antonio Hernández-Paredes. 2022. "The Complete Series of Lanthanoid-Chloranilato Lattices with Dimethylsulfoxide: Role of the Lanthanoid Size on the Coordination Number and Crystal Structure" Crystals 12, no. 2: 261. https://doi.org/10.3390/cryst12020261
APA StyleBenmansour, S., Gómez-García, C. J., & Hernández-Paredes, A. (2022). The Complete Series of Lanthanoid-Chloranilato Lattices with Dimethylsulfoxide: Role of the Lanthanoid Size on the Coordination Number and Crystal Structure. Crystals, 12(2), 261. https://doi.org/10.3390/cryst12020261