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Open AccessArticle

Reduced Sintering Temperatures of Li+ Conductive Li1.3Al0.3Ti1.7(PO4)3 Ceramics

Fraunhofer IKTS, Fraunhofer Institute for Ceramic Technologies and Systems IKTS, Winterbergstrasse 28, 01277 Dresden, Germany
Author to whom correspondence should be addressed.
Crystals 2020, 10(5), 408;
Received: 6 April 2020 / Revised: 14 May 2020 / Accepted: 15 May 2020 / Published: 20 May 2020
(This article belongs to the Special Issue Conducting Ceramics)
All-solid-state batteries (ASSB) are considered promising candidates for future energy storage and advanced electric mobility. When compared to conventional Li-ion batteries, the substitution of Li-ion conductive, flammable liquids by a solid electrolyte and the application of Li-metal anodes substantially increase safety and energy density. The solid electrolyte Li1.3Al0.3Ti1.7(PO4)3 (LATP) provides high Li-ion conductivity of about 10−3 S/cm and is considered a highly promising candidate for both the solid electrolyte-separator and the ionically conductive part of the all-solid state composite cathode, consisting of the cathode material, the solid electrolyte, and an electron conductor. Co-sintering of the composite cathode is a sophisticated challenge, because temperatures above 1000 °C are typically required to achieve the maximum ionic conductivity of LATP but provoke reactions with the cathode material, inhibiting proper electrochemical functioning in the ASSB. In the present study, the application of sintering aids with different melting points and their impact on the sinterability and the conductivity of LATP were investigated by means of optical dilatometry and impedance spectroscopy. The microstructure of the samples was analyzed by SEM. The results indicate that the sintering temperature can be reduced below 800 °C while maintaining high ionic conductivity of up to 3.6 × 10−4 S/cm. These insights can be considered a crucial step forward towards enable LATP-based composite cathodes for future ASSB. View Full-Text
Keywords: Li-ion conductive ceramic; solid electrolyte; Li-ion batteries; all-solid-state batteries; LATP Li-ion conductive ceramic; solid electrolyte; Li-ion batteries; all-solid-state batteries; LATP
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Waetzig, K.; Heubner, C.; Kusnezoff, M. Reduced Sintering Temperatures of Li+ Conductive Li1.3Al0.3Ti1.7(PO4)3 Ceramics. Crystals 2020, 10, 408.

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