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Open AccessArticle

Microwave-Mediated Continuous Hydrogen Abstraction Reaction from 2-PrOH Catalyzed by Platinum on Carbon Bead

1
Laboratory of Organic Chemistry, Gifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, Japan
2
Laboratory of Organic Chemistry, Daiichi University of Pharmacy, 22-1, Tamagawa-cho, Minami-ku, Fukuoka 815-8511, Japan
*
Author to whom correspondence should be addressed.
Catalysts 2019, 9(8), 655; https://doi.org/10.3390/catal9080655
Received: 27 June 2019 / Revised: 23 July 2019 / Accepted: 29 July 2019 / Published: 31 July 2019
(This article belongs to the Special Issue Microwave-Assisted Catalysis)
We developed a microwave-mediated continuous hydrogen production method from 2-PrOH using platinum on a spherical carbon-bead catalyst. The catalyst cartridge consisted of helical glass part, and straight glass part (helix−straight cartridge) was newly developed for the effective microwave heating of 2-PrOH in the presence of 5% Pt/CB. The microwave resonance was properly adjusted within 2.4−2.5 GHz using the helix−straight cartridge with the glass resonance-adjuster tube. The reaction was conducted by the irradiation of only 10 W of single-frequency microwaves and the catalyst was used continuously for at least 13 h without any loss of catalyst activity. View Full-Text
Keywords: carbon; flow process; heterogeneous catalyst; hydrogen production; microwave chemistry; platinum carbon; flow process; heterogeneous catalyst; hydrogen production; microwave chemistry; platinum
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MDPI and ACS Style

Ichikawa, T.; Matsuo, T.; Tachikawa, T.; Teranishi, W.; Yamada, T.; Sawama, Y.; Monguchi, Y.; Sajiki, H. Microwave-Mediated Continuous Hydrogen Abstraction Reaction from 2-PrOH Catalyzed by Platinum on Carbon Bead. Catalysts 2019, 9, 655.

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