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Self-Templating Synthesis of 3D Hierarchical NiCo2O4@NiO Nanocage from Hydrotalcites for Toluene Oxidation

State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
University of Chinese Academy of Sciences, No. 19A Yuquan Road, Beijing 100049, China
Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Authors to whom correspondence should be addressed.
Catalysts 2019, 9(4), 352;
Received: 6 March 2019 / Revised: 24 March 2019 / Accepted: 29 March 2019 / Published: 11 April 2019
(This article belongs to the Special Issue Catalysis for the Removal of Gas-Phase Pollutants)
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Rational design LDHs (layered double hydroxides) with 3D hierarchical hollow structures have generated widespread interest for catalytic oxidation due to the high complexity in shell architecture and composition. Herein, we reported a handy two-step method to construct a 3D hierarchical NiCo2O4/NiO nanocage. This synthetic strategy contains a partial in situ transformation of ZIF-67 (zeolitic imidazolate framework-67) into Co-NiLDH yolk-shelled structures following ethanol etching, and a structure-preserved transformation from [email protected] to a biphase nanocage following calcination. CoNi-yh-T (varied reaction time and calcination temperature) nanocages were investigated systematically by Brunauer–Emmett–Teller (BET), X-ray photoelectron spectroscopy (XPS), H2- temperature-programmed reduction (TPR), NH3-temperature-programmed desorption (TPD) and studied for toluene oxidation. The CoNi-6h-350 sample showed much higher activity with 90% toluene conversion (T90) at 229 °C at a high space velocity (SV = 60,000 mL g−1 h−1) than other catalysts (T90 >240 °C). Abundant surface high valence Co ions caused by the novel hierarchical nanostructures, together with adsorbed oxygen species and abundant medium-strength surface acid sites, played a key role for catalytic activities. View Full-Text
Keywords: hierarchical nanocage; high surface area; toluene oxidation; lattice defect hierarchical nanocage; high surface area; toluene oxidation; lattice defect

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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Wang, D.; Li, S.; Du, Y.; Wu, X.; Chen, Y. Self-Templating Synthesis of 3D Hierarchical NiCo2O4@NiO Nanocage from Hydrotalcites for Toluene Oxidation. Catalysts 2019, 9, 352.

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