The Selectivity of Different Sized Catalysts on DOM Fractional Removal during the Catalytic Ozonation of Municipal Sewage
Abstract
:1. Introduction
2. Results and Discussion
2.1. EEM (Excitation—Emission—Matrix Spectra) Analysis
2.2. Effect of Hydrophobics/Hydrophilics by O3 and γ-Al2O3
2.3. The Change of Different MW Organic Matter by O3 and γ-Al2O3/O3
2.4. Removal of DOM and Kinetics
2.5. Toxicity Study
3. Materials and Methods
3.1. Materials and Reagents
3.2. Catalyst Characterization
3.3. Raw Water Quality Indicators
3.4. Ozonation and Catalytic Ozonation of Biological Effluents
3.5. Water Sample Analysis
3.6. Toxicity Assay
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample | BET Surface Area (m2·g−1) | Pore Diameter (nm) | Concentration of Surface Hydroxyl Groups (mmol g−1) | pHpzc |
---|---|---|---|---|
γ-Al2O3(0.1 mm) | 322.43 | 5.08 | 1.83 | 7.73 |
γ-Al2O3(0.3 mm) | 320.28 | 5.39 | 1.72 | 7.42 |
γ-Al2O3(0.5 mm) | 306.93 | 5.56 | 1.56 | 7.23 |
γ-Al2O3(0.9 mm) | 302.63 | 5.67 | 0.59 | 7.22 |
Sample | COD(mg/L) | UV254 | pH | Total Nitrogen (mg/L) | Total Phosphorus (mg/L) | SUVA(L/m/mg) |
---|---|---|---|---|---|---|
Sample A | 29.0 | 0.220 | 7.01 | 13.7 | 0.17 | 2.03 |
Sample B | 30.1 | 0.182 | 7.18 | 14.2 | 0.19 | 1.59 |
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Wang, C.; Wu, J.; Li, A.; Shuang, C. The Selectivity of Different Sized Catalysts on DOM Fractional Removal during the Catalytic Ozonation of Municipal Sewage. Catalysts 2019, 9, 14. https://doi.org/10.3390/catal9010014
Wang C, Wu J, Li A, Shuang C. The Selectivity of Different Sized Catalysts on DOM Fractional Removal during the Catalytic Ozonation of Municipal Sewage. Catalysts. 2019; 9(1):14. https://doi.org/10.3390/catal9010014
Chicago/Turabian StyleWang, Cheng, Ji Wu, Aimin Li, and Chendong Shuang. 2019. "The Selectivity of Different Sized Catalysts on DOM Fractional Removal during the Catalytic Ozonation of Municipal Sewage" Catalysts 9, no. 1: 14. https://doi.org/10.3390/catal9010014