Cerium Coordination Polymer Based Composite Mimicking Peroxidase for Detection of Nitroaniline
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterization of Pt Deposited Ce Coordination Polymer
2.2. Peroxidase Activity of CeCP@Pt
2.3. Detection of Nitroaniline by CeCP@Pt
3. Experimental Section
3.1. Materials
3.2. Preparation of CeCP@Pt
3.3. Measurement of Peroxidase Activity of CeCP@Pt
3.4. Characterization
4. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Percentage of Pt Loaded (%) | Average Size of Pt Particle (nm) |
---|---|
5.4 | 4.5 |
10 | 5.8 |
19.9 | 8.5 |
32.6 | 11.0 |
52.7 | 14.5 |
Catalyst | Substrate | Km [mM] | Vmax [Ms−1] | Kcat [s−1] | Refrences |
---|---|---|---|---|---|
Au@Pd particles | TMB | 0.17 | 2.00 × 10−6 | 2.1 × 104 | [6] |
H2O2 | 1100 | 4.40 × 10−6 | 4.6 × 104 | [6] | |
HRP | TMB | 0.434 | 10 × 10−8 | 0.4 × 104 | [25] |
H2O2 | 3.70 | 8.71 × 10−8 | 0.348 × 104 | [25] | |
Fe3O4 particles | TMB | 0.098 | 3.4 × 10−8 | 3.0 × 104 | [25] |
H2O2 | 150 | 9.8 × 10−8 | 8.6 × 104 | [25] | |
Pt particles | TMB | 1.2 | 1.30 × 10−6 | 2.3 × 104 | [26] |
H2O2 | 770 | 1.9 × 10−6 | 1.6 × 104 | [26] | |
Pd-Ir cubes | TMB | 0.13 | 6.5 × 10−8 | 1.90 × 106 | [27] |
H2O2 | 340 | 5.1 × 10−8 | 1.50 × 106 | [27] | |
ZnFe2O4 | TMB | 0.85 | 1.33 × 10−7 | 4.36 × 1010 | [28] |
H2O2 | 1.66 | 7.74 × 10−8 | 2.54 × 1010 | [28] | |
CeCP@Pt | TMB | 0.4585 | 7.71 × 10−6 | 1.19 × 109 | This work |
H2O2 | 92.7 | 9.69 × 10−6 | 0.947 × 109 | This work |
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Wang, X.; Zheng, K.; Ji, P. Cerium Coordination Polymer Based Composite Mimicking Peroxidase for Detection of Nitroaniline. Catalysts 2017, 7, 206. https://doi.org/10.3390/catal7070206
Wang X, Zheng K, Ji P. Cerium Coordination Polymer Based Composite Mimicking Peroxidase for Detection of Nitroaniline. Catalysts. 2017; 7(7):206. https://doi.org/10.3390/catal7070206
Chicago/Turabian StyleWang, Xi, Kunkun Zheng, and Peijun Ji. 2017. "Cerium Coordination Polymer Based Composite Mimicking Peroxidase for Detection of Nitroaniline" Catalysts 7, no. 7: 206. https://doi.org/10.3390/catal7070206