Engineering Photocatalytic Membrane Reactors for Sustainable Energy and Environmental Applications

Photocatalytic membrane reactors (PMRs), which combine photocatalysis with membrane separation, represent a pivotal technology for sustainable water treatment and resource recovery. Although extensive research has documented various configurations of photocatalytic-membrane hybrid processes and their potential in water treatment applications, a comprehensive analysis of the interrelationships among reactor architectures, intrinsic physicochemical mechanisms, and overall process efficiency remains inadequately explored. This knowledge gap hinders the rational design of highly efficient and stable reactor systems—a shortcoming that this review seeks to remedy. Here, we critically examine the connections between reactor configurations, design principles, and cutting-edge applications to outline future research directions. We analyze the evolution of reactor architectures, relevant reaction kinetics, and key operational parameters that inform rational design, linking these fundamentals to recent advances in solar-driven hydrogen production, CO₂ conversion, and industrial scaling. Our analysis reveals a significant disconnect between the mechanistic understanding of reactor operation and the system-level performance required for innovative applications. This gap between theory and practice is particularly evident in efforts to translate laboratory success into robust and economically feasible industrial-scale operations. We believe that PMRs will realize their transformative potential in sustainable energy and environmental applications in future.