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Volume 14
Issue 6
10.3390/catal14060338
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This is an early access version, the complete PDF, HTML, and XML versions will be available soon.
Article

Na2SO3-Promoted Heck Coupling and Homo-Coupling of Arylhydrazines at Room Temperature

by
Jianxiong Du
1,
Wanhe Wang
2,
Jin-Biao Liu
1,* and
Nianhua Luo
3,*
1
Jiangxi Provincial Key Laboratory of Functional Crystalline Materials Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, China
2
Xi’an Key Laboratory of Stem Cell and Regenerative Medicine, Institute of Medical Research, Northwestern Polytechnical University, Xi’an 710072, China
3
School of Pharmaceutical Sciences, Gannan Medical University, Ganzhou 341000, China
*
Authors to whom correspondence should be addressed.
Catalysts 2024, 14(6), 338; https://doi.org/10.3390/catal14060338
Submission received: 19 April 2024 / Revised: 15 May 2024 / Accepted: 20 May 2024 / Published: 22 May 2024
(This article belongs to the Special Issue Catalysis for Functionalization Reaction of Hydrocarbons Compounds)
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Abstract

A novel protocol facilitated by Na2SO3 that enhances the efficiency of palladium-catalyzed Heck coupling and the homo-coupling reactions of arylhydrazines. This innovative method enables the effective construction of a diverse array of cinnamate derivatives and biphenyl compounds. Notably, these transformative reactions proceed smoothly at room temperature, leveraging the activation of C-N bonds. This technique not only streamlines the synthesis process but also expands our understanding and expertise in the realm of coupling reactions.
Keywords: Na2SO3; Heck coupling; homo coupling; arylhydrazine Na2SO3; Heck coupling; homo coupling; arylhydrazine

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MDPI and ACS Style

Du, J.; Wang, W.; Liu, J.-B.; Luo, N. Na2SO3-Promoted Heck Coupling and Homo-Coupling of Arylhydrazines at Room Temperature. Catalysts 2024, 14, 338. https://doi.org/10.3390/catal14060338

AMA Style

Du J, Wang W, Liu J-B, Luo N. Na2SO3-Promoted Heck Coupling and Homo-Coupling of Arylhydrazines at Room Temperature. Catalysts. 2024; 14(6):338. https://doi.org/10.3390/catal14060338

Chicago/Turabian Style

Du, Jianxiong, Wanhe Wang, Jin-Biao Liu, and Nianhua Luo. 2024. "Na2SO3-Promoted Heck Coupling and Homo-Coupling of Arylhydrazines at Room Temperature" Catalysts 14, no. 6: 338. https://doi.org/10.3390/catal14060338

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