Plasma-Catalysis for Volatile Organic Compounds Decomposition: Complexity of the Reaction Pathways during Acetaldehyde Removal
Abstract
:1. Introduction
2. Results
2.1. Acetaldehyde Decomposition Using the Plasma-Driven Catalysis Process
2.2. Acetaldehyde Adsorption on Ag/TiO2/SiO2
2.3. Surface Species Formed during the PDC Process
3. Discussion
3.1. Acetaldehyde Adsorption Mechanism
3.2. Surface Species Formed during the PDC Process: Formation Mechanism
3.3. Proposed Simplified Mechanism for Acetaldehyde Decomposition Using the Plasma/Catalysis Process
4. Materials and Methods
4.1. Catalyst Preparation
4.2. Plasma/Catalysis Process
4.3. DRIFTS Measurements
5. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Specific Input Energy (SIE) (J·L−1) | Ag/TiO2/SiO2 | Plasma Alone | Plasma + Ag/TiO2/SiO2 | ||
---|---|---|---|---|---|
Alone | 150 | 70 | 350 | 1150 | |
Acetaldehyde removal (%) | 0 | 55 | 33 | 87 | 98 |
Vibrational Mode | Vibrational Assignments (cm−1) | Reference | |
---|---|---|---|
Gas Phase CH3CHO | CH3CHO Adsorbed on Ag/TiO2/SiO2 | ||
νas(CH3) | 2967 | 2974 | [30] |
νas(CH2) | 2936 | [30,31,32] | |
νs(CH3) | 2923 | 2922 | [30,33] |
2ν6A’ Fermi | 2840 | 2866 | [34] |
νs(CH2) | 2830 | [30] | |
ν(CH)η1-acetaldehyde | 2736, 2704 | 2770, 2748 | [31,33,35] |
ν(C=O) | 1735 | 1713 | [31] |
νas(COO) | 1555 | [36] |
Surface Species | IR Band (cm−1) | Reference |
---|---|---|
Acetate | 1560–1540/1450–1418 | [33,39,46,54,55,56] |
Formate | 1870–1828/1590–1550/1380–1350 | [42,44,45,47,54,55,57,58,59,60] |
Methoxy | 964/1100–1030 | [61,62] |
Ethoxy | 1456/1380–1390/1190–1090/1065–1050 | [37,49,56,63] |
Carbonate | 1680/1614/1520/1430/1310 | [42] |
Acetic acid | 1736/1675/1535/1453/1415/1341/1296/1025–1050 | [44,46,56] |
Formaldehyde | 1767–1746/1727–1713/1418/1260 | [42,43,52,55] |
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Vega-González, A.; Duten, X.; Sauce, S. Plasma-Catalysis for Volatile Organic Compounds Decomposition: Complexity of the Reaction Pathways during Acetaldehyde Removal. Catalysts 2020, 10, 1146. https://doi.org/10.3390/catal10101146
Vega-González A, Duten X, Sauce S. Plasma-Catalysis for Volatile Organic Compounds Decomposition: Complexity of the Reaction Pathways during Acetaldehyde Removal. Catalysts. 2020; 10(10):1146. https://doi.org/10.3390/catal10101146
Chicago/Turabian StyleVega-González, Arlette, Xavier Duten, and Sonia Sauce. 2020. "Plasma-Catalysis for Volatile Organic Compounds Decomposition: Complexity of the Reaction Pathways during Acetaldehyde Removal" Catalysts 10, no. 10: 1146. https://doi.org/10.3390/catal10101146