Modification of MCM-22 Zeolite and Its Derivatives with Iron for the Application in N2O Decomposition
Abstract
:1. Introduction
2. Results
2.1. MCM-22 and ITQ-2 Modified with FeSO4∙7H2O and [Fe3(OCOCH3)7∙OH∙2H2O]NO3 by Ion-Exchange
2.2. MCM-22 Zeolite Modified with Fe(NO3)3∙9H2O by Direct Synthesis
2.3. Fe2(N,DS)MCM-22 Zeolite Modified with Different Iron Precursors by Post-Synthesis Ion-Exchange
3. Materials and Methods
3.1. Catalysts Synthesis
3.1.1. MCM-22 and ITQ-2
3.1.2. FeX(N,DS)MCM-22 Modified with Fe(III) by Direct Synthesis
3.1.3. Ion-Exchange
3.2. Catalysts Characterization
3.3. Catalytic Tests
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Sample Code. | Iron Source | Modification Method | SBET/ m2/g | SEXT/ m2/g | VMIC /cm3/g | VMES/ cm3/g | Fe (%) | H2/Fe |
---|---|---|---|---|---|---|---|---|
MCM-22 | ---- | ---- | 622 | 117 | 0.202 | 0.281 | --- | --- |
ITQ-2 | ---- | ---- | 608 | 186 | 0.178 | 0.384 | --- | --- |
Fe(S,IE)MCM-22 | S | IE | 611 | 117 | 0.198 | 0.287 | 0.82 | 1.44 |
Fe(S,IE)ITQ-2 | S | IE | 586 | 173 | 0.173 | 0.359 | 0.80 | 1.29 |
Fe(O,IE)MCM-22 | O | IE | 519 | 131 | 0.156 | 0.285 | 12.67 | 0.45 |
Fe(O,IE)ITQ-2 | O | IE | 519 | 173 | 0.145 | 0.353 | 9.79 | 0.43 |
Fe0.25(N,DS)MCM-22 | N | DS | 614 | 53 | 0.223 | 0.125 | 1.65 | 0.83 |
Fe1(N,DS)MCM-22 | N | DS | 514 | 69 | 0.177 | 0.171 | 3.40 | 0.56 |
Fe2(N,DS)MCM-22 | N | DS | 563 | 79 | 0.193 | 0.200 | 4.50 | 0.56 |
Fe4(N,DS)MCM-22 | N | DS | 531 | 74 | 0.183 | 0.177 | 5.28 | 0.43 |
Fe(N,DS)MCM-22 | N | DS | 561 | 74 | 0.195 | 0.178 | 6.51 | 0.51 |
Fe2(N/S,DS/IE)MCM-22 | N/S | DS/IE | 542 | 92 | 0.180 | 0.219 | 6.70 | 0.48 |
Fe2(N/O,DS/IE)MCM-22 | N/O | DS/IE | 473 | 100 | 0.149 | 0.217 | 13.50 | 0.43 |
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Rutkowska, M.; Jankowska, A.; Różycka-Dudek, E.; Dubiel, W.; Kowalczyk, A.; Piwowarska, Z.; Llopis, S.; Díaz, U.; Chmielarz, L. Modification of MCM-22 Zeolite and Its Derivatives with Iron for the Application in N2O Decomposition. Catalysts 2020, 10, 1139. https://doi.org/10.3390/catal10101139
Rutkowska M, Jankowska A, Różycka-Dudek E, Dubiel W, Kowalczyk A, Piwowarska Z, Llopis S, Díaz U, Chmielarz L. Modification of MCM-22 Zeolite and Its Derivatives with Iron for the Application in N2O Decomposition. Catalysts. 2020; 10(10):1139. https://doi.org/10.3390/catal10101139
Chicago/Turabian StyleRutkowska, Małgorzata, Aleksandra Jankowska, Ewelina Różycka-Dudek, Wiktoria Dubiel, Andrzej Kowalczyk, Zofia Piwowarska, Sebastián Llopis, Urbano Díaz, and Lucjan Chmielarz. 2020. "Modification of MCM-22 Zeolite and Its Derivatives with Iron for the Application in N2O Decomposition" Catalysts 10, no. 10: 1139. https://doi.org/10.3390/catal10101139