Environmental Protection in Enhanced Oil Recovery and Its Waste and Effluents Treatment: A Critical Patent-Based Review of BRICS and Non-BRICS (2004–2023)
Abstract
1. Introduction
2. Materials and Methods
- EOR—Patents classified under enhanced and improved oil recovery IPCs;
- EOR and Env—Patents from the EOR group that also contain IPCs from the WIPO Environmental Domain;
- GEOR—Patents from the EOR and Env group with green EOR IPCs;
- WT—Patents from the EOR and Env group with IPCs related to the treatment of water, waste, sludge, and solids in EOR processes.
- BRICS—Patents from BRICS countries;
- Total—Total patents;
- Non-BRICS—Patents from non-BRICS countries, obtained by subtracting BRICS from Total.
3. Results and Discussion
3.1. Technology Distribution Among BRICS and Non-BRICS
3.2. Science and Technology Distribution Among Countries
3.3. Technological Methods Distribution Among BRICS and Non-BRICS
3.4. Growth Rates and Temporal Tendencies
3.5. Technological Methods Growth Rates
3.6. Technological Concentration and Competitivity
4. Conclusions
Supplementary Materials
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
Abbreviations
| BRICS | Brazil, China, Egypt, Ethiopia, India, Iran, Russia, Saudi Arabia, South Africa, and United Arab Emirates |
| CAGR | Compound annual growth rate |
| CV | Specialization |
| DIS | Technological specialization distance |
| DIV | Technological diversification |
| EOR | Enhanced oil recovery |
| EOR and Env | Enhanced oil recovery with environmental protection |
| GDP | Gross domestic product |
| GEOR | Green EOR |
| HH | Herfindahl–Hirschman Index |
| IPC | International patent classification |
| MEOR | Microbially-enhanced oil recovery |
| nonBRICS | Non-BRICS countries |
| RTA | Revealed technological advantage |
| SDG | Sustainable development goals |
| TRL | Technology readiness levels |
| UN | United Nations |
| WAG | Water alternating gas, combinations with injected gas |
| WIPO | World Intellectual Property Organization |
| WT | EOR waste and effluent treatment |
References
- Almgren, R.; Skobelev, D. Evolution of Technology and Technology Governance. Open Innov. Technol. Mark. Complex. 2020, 6, 22. [Google Scholar] [CrossRef]
- United Nations. Transforming Our World: The 2030 Agenda for Sustainable Development. Available online: https://sdgs.un.org/publications/transforming-our-world-2030-agenda-sustainable-development-17981 (accessed on 18 February 2025).
- United Nations. Sustainable Development Goals. Available online: https://sdgs.un.org/goals (accessed on 18 February 2025).
- Joseph, J.A. The Ethical Interface of Sustainable Prosperity in the Teachings of Pope Francis. J. Dharma 2021, 46, 279–294. Available online: https://dvkjournals.in/index.php/jd/article/view/3530 (accessed on 18 February 2025).
- Fincham, G. A World Not Our Own to Define: Ecological Solutions to Global Catastrophe in the Works of Barry Lopez. Engl. Acad. Rev. 2023, 41, 33–46. [Google Scholar] [CrossRef]
- Ahmad, T.; Zhang, D. A Critical Review of Comparative Global Historical Energy Consumption and Future Demand: The Story Told So Far. Energy Rep. 2020, 6, 1973–1991. [Google Scholar] [CrossRef]
- The Breakthrough Agenda Report 2022. Accelerating Sector Transitions Through Stronger International Collaboration. International Energy Agency (IEA), the International Renewable Energy Agency (IRENA) and the UN Climate Change High-Level Champions. Available online: https://www.iea.org/reports/breakthrough-agenda-report-2022 (accessed on 18 February 2025).
- Bloomberg Media Studios. Resetting Globalisation: Catalysts for Change. White Paper. Available online: https://sponsored.bloomberg.com/immersive/sc/resetting-globalisation (accessed on 9 December 2023).
- Mahmood, Y.; Afrin, T.; Huang, Y.; Yodo, N. Sustainable Development for Oil and Gas Infrastructure from Risk, Reliability, and Resilience Perspectives. Sustainability 2023, 15, 4953. [Google Scholar] [CrossRef]
- Alvarado, V.; Manrique, E. Enhanced Oil Recovery: An Update Review. Energies 2010, 3, 1529–1575. [Google Scholar] [CrossRef]
- Muggeridge, A.; Cockin, A.; Webb, K.; Frampton, H.; Collins, I.; Moulds, T.; Salino, P. Recovery Rates, Enhanced Oil Recovery and Technological Limits. Phil. Trans. R. Soc. A 2014, 372, 20120320. [Google Scholar] [CrossRef]
- Haq, B.; Liu, J.; Liu, K. Green Enhanced Oil Recovery (GEOR). APPEA J. 2017, 57, 150–170. [Google Scholar] [CrossRef]
- Abdelhamid, C.; Latrach, A.; Rabiei, M.; Venugopal, K. Produced Water Treatment Technologies: A Review. Energies 2025, 18, 63. [Google Scholar] [CrossRef]
- Amakiri, K.T.; Ramirez Canon, A.; Molinari, M.; Angelis-Dimakis, A. Review of Oilfield Produced Water Treatment Technologies. Chemosphere 2022, 298, 134064. [Google Scholar] [CrossRef]
- Wang, X.; Jin, W.; Li, Y.; Liu, S.; Xu, J.; Liu, J.; Li, H.; Long, T. Treatment Advances of Hazardous Solid Wastes from Oil and Gas Drilling and Production Processes. Chem. Eng. J. 2024, 497, 154182. [Google Scholar] [CrossRef]
- Lodge, M. The International Seabed Authority and Deep Seabed Mining; United Nations: New York, NY, USA, 2017; Available online: https://www.un.org/en/chronicle/article/international-seabed-authority-and-deep-seabed-mining (accessed on 12 March 2025).
- United Nations Convention on the Law of the Sea—UNCLOS. United Nations. 1994. Available online: https://www.un.org/depts/los/convention_agreements/texts/unclos/unclos_e.pdf (accessed on 12 March 2025).
- Stuiver, M.; Soma, K.; Koundouri, P.; Van den Burg, S.; Gerritsen, A.; Harkamp, T.; Dalsgaard, N.; Zagonari, F.; Guanche, R.; Schouten, J.-J.; et al. The Governance of Multi-Use Platforms at Sea for Energy Production and Aquaculture: Challenges for Policy Makers in European Seas. Sustainability 2016, 8, 333. [Google Scholar] [CrossRef]
- US Energy Information Administration. Oil Producers and Consumers. Available online: https://www.eia.gov/tools/faqs/faq.php?id=709&t=6 (accessed on 18 February 2025).
- Energy Institute. Statistical Review of World Energy 2023. Heriot-Watt University. 2023. Available online: https://www.energyinst.org/statistical-review (accessed on 18 February 2025).
- Ministry of Science and Technology, Government of India. BRICS Countries Give Unanimous Support to India’s Draft BRICS Innovation Action Plan 2021–2024. Available online: https://dst.gov.in/brics-countries-give-unanimous-support-indias-draft-brics-innovation-action-plan-2021-2024 (accessed on 18 February 2025).
- New Development Bank. Available online: https://www.ndb.int/about-ndb/history/ (accessed on 18 February 2025).
- Government of Brazil. Treaty for the Establishment of a BRICS Contingent Reserve Arrangement. Available online: https://web.archive.org/web/20150925234418/http://brics.itamaraty.gov.br/media2/press-releases/220-treaty-for-the-establishment-of-a-brics-contingent-reserve-arrangement-fortaleza-july-15 (accessed on 9 December 2023).
- BRICS Portal. Presidency of the Republic, Brazil. 2025. Available online: https://www.gov.br/planalto/pt-br/agenda-internacional/brics/brasil-lanca-portal-do-brics-2025 (accessed on 12 March 2025).
- BRICS. 2025. Available online: https://brics.br/en (accessed on 12 March 2025).
- Thompson, T.L. Plate Tectonics in Oil and Gas Exploration of Continental Margins. AAPG Bull. 1976, 60, 1463–1501. [Google Scholar] [CrossRef]
- Current Contracts. Pre-Salt Petroleum SA. Available online: https://www.presalpetroleo.gov.br/eng/current-contracts/ (accessed on 12 March 2025).
- Patent Cooperation Treaty (PCT)—The International Patent System. World Intellectual Property Organization (WIPO). Available online: https://www.wipo.int/treaties/en/registration/pct/ (accessed on 12 March 2025).
- Nesta, L.; Patel, P. National Patterns of Technology Accumulation: Use of Patent Statistics. In Handbook of Quantitative Science and Technology Research; Moed, H.F., Glänzel, W., Schmoch, U., Eds.; Springer: Dordrecht, The Netherlands, 2004; pp. 531–552. [Google Scholar] [CrossRef]
- JRC European Commission; OECD. Handbook on Constructing Composite Indicators: Methodology and User Guide. Available online: https://www.oecd.org/sdd/42495745.pdf (accessed on 18 February 2025).
- Quintella, C.M.; Pires, E.A.; Santos, W.P.C. Brazil’s Food Technology: A Pre-Pandemic Assessment to Achieve Zero Hunger SDG2 Goal, Benchmarking Against USA. World Patent Inf. 2023, 75, 102240. [Google Scholar] [CrossRef]
- Quintella, C.M.; Hanna, S.A.; Santos, S.C. Brazil’s Biotechnology Assessment of Potential to Achieve Sustainable Development Goals, Benchmarking Against the USA. World Patent Inf. 2024, 77, 102275. [Google Scholar] [CrossRef]
- Quintella, C.M.; Rodrigues, P.D.; Nicoleti, J.L.; Ramos-de-Souza, E.; Carvalho, E.B.; Hanna, S.A. EOR Technology (Patents) and Science (Articles) Assessment of BRICS and Non-BRICS with Growth Rates and Specializations within Responsible Global Energy Transition: A Critical Review. Energies 2024, 17, 3197. [Google Scholar] [CrossRef]
- Quintella, C.M.; Rodrigues, P.D.; Ramos-de-Souza, E.; Carvalho, E.B.; Nicoleti, J.L.; Hanna, S.A. Integration of EOR/IOR and Environmental Technologies in BRICS and Non-BRICS: A Patent-Based Critical Review. Energy Rep. 2025, 13, 747–758. [Google Scholar] [CrossRef]
- Questel Orbit. The Fampat Collection. Available online: https://static.orbit.com/orbit/help/1.9.8/en/index.html#!Documents/thefampatcollection.htm (accessed on 10 September 2023).
- Costa, B.M.G.; Silva Florencio, M.N.; Oliveira Junior, A.M. Analysis of Technological Production in EOR Technology in Northeast Brazil. World Patent Inf. 2018, 52, 42–49. [Google Scholar] [CrossRef]
- World Intellectual Property Organization (WIPO). International Patent Classification (IPC). Available online: https://www.wipo.int/classifications/ipc/en (accessed on 18 February 2025).
- Schmoch, U.; IPC and Technology Concordance Table. World Intellectual Property Organization. 2008. Available online: https://www.wipo.int/meetings/en/doc_details.jsp?doc_id=117672 (accessed on 18 February 2025).
- European Patent Office. Worldwide Database. Available online: https://worldwide.espacenet.com (accessed on 16 May 2023).
- Coverage Worldwide European Patent Office Database. Available online: https://static.orbit.com/imagination/orbit_welcome/prd/coverage/coverage.htm (accessed on 12 March 2025).
- Pires, E.A.; Ribeiro, N.M.; Quintella, C.M. Patent Search Systems: Comparative Analysis Between Espacenet, Patentscope, Google Patents, Lens, Derwent Innovation Index and Orbit Intelligence. Cad. Prospecção 2020, 13, 13–29. [Google Scholar] [CrossRef]
- Regulations on the Administration of Environmental Protection in the Exploration and Development of Offshore Petroleum. Ministry of Ecology and Environment of China. 1983. Available online: https://english.mee.gov.cn/Resources/laws/regulations/Marine_Environment/200710/t20071022_111648.shtml (accessed on 12 March 2025).
- 13th Five-Year Plan and the 2015 Environmental Protection Law Reform. Available online: https://www.mondaq.com/china/clean-air-pollution/955486/china39s-evolving-environmental-protection-laws (accessed on 12 March 2025).
- Meidan, M.; Hove, A.; Qin, Y. China’s Policy Pendulum Shifts Back Toward Environmental Protection, but Will Bureaucracy Get in the Way? The Oxford Institute for Energy Studies. February 2024. Available online: https://www.oxfordenergy.org/wpcms/wp-content/uploads/2024/02/Chinas-policy-pendulum-shifts-back-toward-environmental-protection.pdf (accessed on 12 March 2025).
- Ministry of Environmental Protection of China. Available online: https://english.mee.gov.cn/About_MEE/Mission (accessed on 12 March 2025).
- Esarey, A.; Haddad, M.A.; Lewis, J.I.; Harrell, S. (Eds.) Greening East Asia: The Rise of the Eco-Developmental State; University of Washington Press: Seattle, WA, USA, 2020; Available online: http://www.jstor.org/stable/j.ctv19rs1b2 (accessed on 12 March 2025).
- Semenova, T.; Al-Dirawi, A.; Al-Saadi, T. Environmental Challenges for Fragile Economies: Adaptation Opportunities on the Examples of the Arctic and Iraq. Agronomy 2022, 12, 2021. [Google Scholar] [CrossRef]
- Bach, V.; Minkov, N.; Finkbeiner, M. Assessing the Ability of the Cradle to Cradle Certified™ Products Program to Reliably Determine the Environmental Performance of Products. Sustainability 2018, 10, 1562. [Google Scholar] [CrossRef]
- Peralta, M.E.; Alcalá, N.; Soltero, V.M. Weighting with Life Cycle Assessment and Cradle to Cradle: A Methodology for Global Sustainability Design. Appl. Sci. 2021, 11, 9042. [Google Scholar] [CrossRef]
- Alsalem, F.; Thiemann, T. Produced Water from the Oil and Gas Industry as a Resource—South Kuwait as a Case Study. Resources 2024, 13, 118. [Google Scholar] [CrossRef]
- Thiedemann, T.M.; Wark, M. A Compact Review of Current Technologies for Carbon Capture as Well as Storing and Utilizing the Captured CO2. Processes 2025, 13, 283. [Google Scholar] [CrossRef]










| EOR and Env Method | Patents (TRL4–5) (%) | |
|---|---|---|
| BRICS | Non-BRICS | |
| GEOR—(Polymers OR macro compounds) and Surfactants | 1.7 | 1.8 |
| GEOR—Combustion in situ | 3.8 | 7.5 |
| GEOR—Fracturing, fracture reinforcement, interconnecting wells | 1.2 | 2.2 |
| GEOR—Heat and steam | 14.2 | 20.0 |
| GEOR—MEOR (microbial enhanced oil recovery) | 0.6 | 1.0 |
| GEOR—Polymers and macromolecular compounds | 7.4 | 7.6 |
| GEOR—Repressuring or Vacuum | 1.4 | 3.1 |
| GEOR—Surfactants | 3.6 | 3.7 |
| GEOR—WAG (Water Alternating Gas, combinations with injected gas) | 0.4 | 1.5 |
| WT—Flocculation or precipitation of suspended impurities | 2.4 | 4.0 |
| WT—Sludge treatment devices | 7.6 | 2.2 |
| WT—Solid waste disposal | 4.5 | 4.1 |
| WT—Sorption | 1.9 | 4.0 |
| WT—Water treatment | 15.5 | 12.6 |
| WT—Water treatment contaminated by oil | 2.3 | 4.8 |
| WT—Water–oil separation | 1.2 | 2.2 |
| WT—Flotation | 17.2 | 16.4 |
| WT—Water multistage treatment devices | 13.1 | 1.4 |
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content. |
© 2025 by the author. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Share and Cite
Quintella, C.M. Environmental Protection in Enhanced Oil Recovery and Its Waste and Effluents Treatment: A Critical Patent-Based Review of BRICS and Non-BRICS (2004–2023). Sustainability 2025, 17, 2896. https://doi.org/10.3390/su17072896
Quintella CM. Environmental Protection in Enhanced Oil Recovery and Its Waste and Effluents Treatment: A Critical Patent-Based Review of BRICS and Non-BRICS (2004–2023). Sustainability. 2025; 17(7):2896. https://doi.org/10.3390/su17072896
Chicago/Turabian StyleQuintella, Cristina M. 2025. "Environmental Protection in Enhanced Oil Recovery and Its Waste and Effluents Treatment: A Critical Patent-Based Review of BRICS and Non-BRICS (2004–2023)" Sustainability 17, no. 7: 2896. https://doi.org/10.3390/su17072896
APA StyleQuintella, C. M. (2025). Environmental Protection in Enhanced Oil Recovery and Its Waste and Effluents Treatment: A Critical Patent-Based Review of BRICS and Non-BRICS (2004–2023). Sustainability, 17(7), 2896. https://doi.org/10.3390/su17072896

