From Agricultural Waste to Green Binder: Performance Optimization of Wheat Straw Ash in Sustainable Cement Mortars

This study investigates the use of wheat straw ash (WSA) as a sustainable supplementary cementitious material, focusing on its mechanical performance optimization and environmental implications. WSA (ASTM C618, Class F), produced via controlled calcination at 700 °C, was used to replace cement at 2.5, 5, 7.5, 10% by mass. The optimal performance was observed at 5% substitution, achieving a 90-day compressive strength of 48.42 MPa (+4.7%) and a 28-day flexural strength of 7.93 MPa (+6.6%). To contextualize these findings, a multi-technique analytical approach was employed, including scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), Fourier-transform infrared spectroscopy (FT-IR), and ultrasonic pulse velocity (UPV). These methods confirmed that WSA enhances portlandite consumption through pozzolanic reactivity and improves matrix densification via secondary C-S-H gel formation. Additionally, satellite (Sentinel-5P) and ground-based measurements during a severe stubble fire event in Diyarbakir (20–24 June 2024) documented a fourfold increase in PM₁₀ concentrations (157 μg/m³ compared to the June average of ≈35 μg/m³), alongside 23% and 41% rises in NO₂ and SO₂ levels, respectively. These findings demonstrate that wheat straw ash utilization can mitigate agricultural waste burning, improve air quality, and reduce the carbon footprint of cement production. The study highlights WSA’s potential as a high-performance, eco-efficient construction material aligned with circular economy principles.