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Article

Manufacturing of Clayey Bricks by Synergistic Use of Waste Brick and Ceramic Powders as Partial Replacement of Clay

1
Department of Civil Engineering, Mirpur University of Science and Technology, Mirpur 10250, Pakistan
2
Department of Civil Engineering, Lahore Leeds University, Lahore 54792, Pakistan
3
Department of Architecture, Engineering-Architecture Faculty, Nişantaşi University, Istanbul 34398, Turkey
*
Author to whom correspondence should be addressed.
Sustainability 2021, 13(18), 10214; https://doi.org/10.3390/su131810214
Submission received: 25 July 2021 / Revised: 5 September 2021 / Accepted: 7 September 2021 / Published: 13 September 2021
(This article belongs to the Special Issue Green Design: A Nexus between Waste and Materials)

Abstract

:
Clay bricks are extensively used as building material worldwide. Natural soil deposits are in constant reduction due to the frequent use of clay to manufacture bricks. About 1600 billion bricks are produced annually by the consumption of millions of tons of natural resources. The prime focus of this study is to assess the feasibility of using a composite mixture of waste brick powder (WBP) and waste ceramic powder (WCP) as a replacement for depleting natural resource “clay” in brick manufacturing. Based upon the previous studies, the replacement levels were kept as (4 + 5)%, (8 + 10)%, and (12 + 15)% of WCP and WBP, respectively. The brick specimens were evaluated in terms of compressive strength, modulus of rupture, density, water absorption, efflorescence, apparent porosity, resistance to chemical attack and sulfate attack, and freeze-thaw resistance. The study reveals that about 27% of clay can be replaced with ceramic waste powder and waste brick powder, which can preserve a massive amount of natural clay without compromising the quality of the bricks.

1. Introduction

The construction industry plays a vital role in the socio-economic development of any country [1]. Nevertheless, it is also a significant source of greenhouse gas emissions and depletion of natural resources. A shift in the construction approach towards sustainable development is the critical need of the day. In construction projects, bricks are extensively used as they possess beneficial properties like ease of handling, high durability, and low cost [2]. They are used in almost every type of civil engineering project, including commercial, industrial, and residential. The primary raw material used for the manufacturing of bricks is clay. Every year almost 340 billion tons of clay are consumed worldwide to manufacture bricks, and in Pakistan, about 59 billion bricks are produced in 1200 brick kilns [3]. Brick manufacturing involves collecting, mixing, molding, drying, and burning raw materials in brick kilns. Bricks are usually composed of various types of clays and other ingredients like sand. Clays suitable for brick manufacturing usually comprise 20–30% alumina, 50–60% silica, 1–5% lime, and 5–6% iron oxide, along with various other carbonates and oxides in minor quantities [4]. The mineralogical composition of the clay is important for the quality of the end product. Carbonates lead to the formation of pores when bricks are manufactured at a temperature of 800–1000 °C [5], alkalis (Na and K salts) absorb moisture from the atmosphere and lead to dampness and efflorescence [6], quartz mainly acts as a filler and maintains the shape of the bricks and improves the mechanical properties [7], and iron oxide (hematite or magnetite) is responsible for the color and strength of the bricks [8]. It is imperative to have a clear understanding of different types of waste that can be used in brick manufacturing to partially replace clay.
The properties of bricks are greatly affected by the following factors:
(a)
Properties of raw material used
(b)
Manufacturing techniques
(c)
Temperature
Many researchers have forecasted that natural soil deposits are on a constant decline because of the large quantity of production of clayey bricks and ceramic tiles worldwide. Countries like Pakistan are also facing the issue of disturbance in the natural balance of fertile soil due to the manufacturing of large quantities of bricks throughout the year. This issue sometimes becomes more critical due to the lack of an efficient solid waste management system. Developing countries with struggling economies are adversely affected by the hazardous impacts of unmanaged solid waste generated from domestic and commercial activities. This waste is a potential threat to environmental sustainability and human health. Recycling wastes addresses environmental concerns and is also an economically viable approach towards environmentally friendly construction. Many researchers in the past have used many other waste materials. In the following paragraph, a brief introduction is presented.
Andreola et al. studied clay recycling via rice husk ash (RHA) [9]. Their study revealed that RHA produces lightweight bricks with low strength. A 5% replacement as the optimum percentage for load-bearing purposes was reported. Kazmi et al. replaced clay with sugarcane bagasse ash [10] and showed that the replacement leads to lighter bricks with lower compressive and flexural strengths. Ibrahim et al. used sawdust to partially replace clay (0–10%) [11]. It was concluded that the replacement leads to lighter bricks but with a drastic reduction in compressive strength from 14.5 to 6.7 MPa at a 10% substitution level. Ahmed et al. studied the effect of coal and wheat husk additives on the properties of clayey bricks [12]. It was demonstrated that both the additives induce porosity and reduce strength. Munir et al. used waste marble powder (WMP) as a partial replacement of clay in bricks [13] and confirmed a subsequent strength reduction and increased porosity. Mandal et al. used iron slime as an additive in making bottom ash bricks [14]. The addition enhanced both strength and density. Riaz et al. added WBP to partially replace clay to manufacture eco-friendly bricks [15]. The addition led to lightweight porous bricks with reduced strength. Riaz et al. incorporated WCP as a partial replacement of clay in making clayey bricks [4]. The incorporation resulted in bricks with enhanced strength as well as weight. Hasan et al. investigated the effect of the partial replacement of clay by waste glass [15]. Their findings revealed that the replacement increases compressive strength and density. All the above research indicates that the partial replacement of clay by any one material reduces strength and weight or increases both. Keeping that in mind, it would be logical to use binary or ternary mixes instead of unary ones. For example, Li et al. used iron ore tailing (IOT) to prepare bricks [16]. The addition increased not only the strength but also the weight due to the heavier density of iron. In order to induce different porosity and reduce weight, they used foam gel casting technology. In the same way, Quero et al. used a binary mixture (screened clay + fly ash (FA)) as a partial replacement of clay in brick manufacturing and reported products with enhanced porosity and compressive strength [17].
Besides the bricks, recycling waste materials has been investigated in ceramic tiles and traditional ceramics. In this regard, significant work has been carried out by Jordan et al. [18] and Montero et al. [19,20]. Sludge rich in calcium carbonate was successfully utilized in traditional ceramics as a secondary raw material, resulting in significant cost savings [20]. The beneficial use of sewage sludge and marble residues in ceramic tile was also corroborated [19], wherein the reactivity of added residues (sewage sludge and marble sludge) with the clay minerals and quartz was shown.
The focus of this study is to introduce environmentally friendly bricks that are durable and sustainable and help preserve the natural environment. Existing research findings on waste utilization in brick manufacturing were carefully reviewed to develop a base for the study. An effort has been made to devise new ways to preserve natural clay by replacing it with waste ceramic powder (WCP) and waste brick powder (WBP) in the manufacturing of bricks. The present study is based on some previous work conducted in our research group. In one study, clay was partially replaced by WBP in the range of 5–15%—the resulting bricks were lightweight but had lower mechanical strength than the control specimens [21]. In the other study, the clay was replaced by WCP in the range of 4–12%—the modified bricks exhibited high density with higher mechanical strength. In this study, a composite replacement of WCP and WBP, i.e., 4 + 5%, 8 + 10%, and 12 + 15% WCP and WBP, respectively, is proposed. The goal is to produce bricks with acceptable density, durability, and mechanical strength (comparative to those of the control products) by using the composite advantage of the proposed binary mix. This would also ensure efficient utilization of wastes generated from two different resources.

2. Materials and Methods

All laboratory work was carried out at a temperature of 20 ± 2 °C. Raw materials used in this research are fresh clay, waste bricks from demolished masonry, and waste ceramic from broken ceramic pottery. Clay was collected from local natural resources, and the wastes were ground to a fine powder in the laboratory milling machine. The oxide compositions of clay, waste brick powder, and waste ceramic powder were determined by the standard X-ray fluorescence technique and are shown in Table 1.
The composition revealed that the clay used for brick manufacturing has CaO above the recommended limits. Therefore, the lower percentages of CaO in the waste materials present an extra advantage in limiting the overall CaO content of the mix. Similarly, the higher SiO2 content in WCP is compensated by a lower one in WBP. The lower content of Fe2O3 in WCP is reinforced by the higher ones in clay and WBP. Overall, the oxide contents seem suitable for a good mix for clayey bricks.
The particle shape and sizes were determined using the Nova Nano SEM 450 field-emission scanning electron microscope (FE-SEM) under standard laboratory conditions. The microscopic images of clay, WCP, and WBP are shown in Figure 1.
The microscopic images reveal that the clay consisted of a wide range of particles, from a smaller tubular shape to a larger irregular shape with rough edges. The WCP particles were irregular in shape, with rough edges. However, the sizes of different particles were in a comparable range, whereas the particles of WBP were thinner in size and seemed to be porous. At first glance, it appears that whereas the WCP particles should result in denser mixes, the WBP particles should induce more porosity and result in lighter end products. This was evidenced in the previous studies of our group, where WBP resulted in porous lighter bricks with reduced strength and WCP produced heavier bricks with enhanced strength.
X-ray powder diffraction is a widely used technique for the identification of crystalline and amorphous phases in raw materials. XRD patterns of clay, waste brick powder (WBP), and ceramic waste powder (WCP) were determined using Bruker D2-Phaser and are shown in Figure 2.
Distinctive peaks of Q (quartz (SiO2)), C (calcite (CaCO3)), and Co (corundum (Al2O3)) minerals were identified in clay, which were mainly crystalline. This is in agreement with the findings reported earlier [22,23]. The crystal structure of WBP was found to be somewhat different. H (hematite (Fe2O3)), quartz ((SiO2), muscovite (KAl2(AlSi3O10)(OH)2), and A (albite (Na(AlSi3O8))) minerals were found. The clay peaks were more intense than those observed for WBP, whereas the WBP had a somewhat more amorphous structure. This is also corroborated by the XRD results shown earlier for WBP [24], where 27.08% of the phases were found to be amorphous. The XRD of WCP showed that the detected predominant peaks were noticeably present between the 2-theta values of 20° to 30° and 50° to 55°, signifying the presence of quartz (SiO2), as was also found for clay and WBP.
Bricks were prepared by replacing clay with different percentages ((4 + 5)%, (8 + 10)%, (12 + 15)%) of the binary composite of WCP and WBP. A total of 150 bricks were cast, which included 50 samples for each category. Numbering and relevant composition are shown in Table 2.
All the ingredients were passed through ASTM sieve #4 to minimize the inclusion of coarser particles in the mix. All the materials were homogeneously mixed following the proportions described in Table 2. The mixing, watering, and molding processes were carried out in the laboratory at a temperature of 20 ± 2 °C and are shown in Figure 3. As shown in the figure, the proposed mixture resulted in the same plasticity, ease of handling, and uniformity as the control specimens with 100% clay. About 50 L of water was added to a mix of 150 kg for adequate plasticity and consistency. Bricks were manufactured as per Pakistan standard sizes of 9 × 4½ × 3 inch (225 × 113 × 75 mm) for ordinary masonry works [25,26]. The bricks were air-dried for 14 days. Afterward, they were shifted to a Bull’s trench kiln and were dried for 21 days. The temperature was kept at 800 °C for 36 h.
Density was calculated using ASTM C67-17 [27]. The weight and dimensions of the specimen were measured after oven drying at 110 °C for 24 h. Density was calculated using Equation (1).
Density = M ( g ) V ( cm 3 )
The water absorption test was performed according to ASTM C67-17. The samples were kept in the oven at 110 °C for 24 h, and then dry weight (Wd) was measured. After that, the samples were kept in water for 24 h, and saturated weight (Ws) was measured.
The water absorption value was calculated using Equation (2).
Water   Absorption   ( % ) = Ws Wd Wd 100
The freeze-thaw resistance testing was performed according to ASTM C67-17. Cracks (if any) were observed carefully, and the initial dry weight (Wi) of the samples was measured after drying in the oven at 110 °C for 24 h. The samples were kept in water for 4.5 h and then 20 ± 2 h in the freezer, and this process was continued for 50 cycles. After the completion of 50 cycles, the oven-dried weight of the samples was measured (Wf). Weight loss was calculated using Equation (3).
Weight   Loss   % = Wi wf Wi 100
The efflorescence experiment was performed according to ASTM C67-17. The bricks were partially submerged in water for seven days. After that, the presence of salts on the surface of the bricks was observed.
A sulfate attack test was performed according to ASTM C 1012 [28]. The bricks were submerged in a 10% solution of sodium sulfate for one month. Afterward, their compression strength was measured. ASTM C_67-17 was used to check the chemical resistance of the bricks. The bricks were dipped in HCL and KOH for 3 hours, and a change in color and texture was observed.
The modulus of rupture (MOR) or flexural strength is the maximum bending stress a material can bear. It is more or less related to compressive strength [29]. The MOR test of the bricks was performed according to ASTM C67-17, using Controls EN—Standard Automatic Compression Testers for Cubes and Cylinders Wizard Auto. The test was conducted by the three-point loading method at a slow loading rate. The MOR was calculated according to Equation (4).
MOR   = 3 P ( L 2 x )
A compressive strength test was performed according to ASTM C67-17 using Controls EN—Standard Automatic Compression Testers for Cubes and Cylinders Wizard Auto. Gypsum was used for the capping of the bricks. The compressive strength was calculated from the load at failure and the surface area in accordance with Equation (5).
Compression   Strength ( MPa ) = P ( N ) A ( mm 2 )
The water absorption rate was performed according to ASTM C67-17. For the initial water absorption rate, the bricks were oven-dried and weighted (Wi), then partially submerged in water for 1 minute and weighted (W1min). The initial rate of water absorption was calculated using Equation (6).
Initial   Rate   of   Water   Absorption = W 1 min Wi Wi 100
The apparent porosity test was performed according to ASTM C20 [30]. The bricks were oven-dried and weighted (Wd). After that, the bricks were submerged in boiling water to open the pores and 6 hours in normal water to saturate them and then weighted (Wsat). They were further submerged in water and the suspended weight was measured (Ws). The porosity was calculated using Equation (7).
% age   Porosity = Volume   of   Voids Volume   of   Brick   sample 100

3. Results and Discussion

3.1. XRD of Brick Specimens

XRD analysis of the brick specimens was carried out to determine the changes in mineralogical composition and crystal structure after sintering at high temperatures (850 °C). The results are given in Figure 4. The different sets of specimens—one containing WCP only (C12 and C4, containing 12% and 4% WCP, respectively) and the other containing a blend of WCP and WBP—exhibited different peaks in the X-Ra diffractograms. Apparent quartz (Q) mineral as the primary crystalline phase was identified in all the samples. Certain broad humps, as seen in the XRD of the raw powders, disappeared, indicating the decomposition of phase from amorphous to crystalline. In the XRD patterns of the brick samples containing WCP and WBP, hematite (H) and albite (A) were also identified. These phases are the main mineral framework of the fired clay bricks and are responsible for the physical properties and mechanical strength of bricks [31].

3.2. Physical Properties

3.2.1. Density

The density of bricks is an important property, as it helps designers estimate the overall weight of the structure. Densities or weights of common bricks are usually mentioned in regional/local building codes. The densities obtained in the current study are presented in Figure 5. The results show that overall, the partial replacements did not significantly lower or enhance the density of the bricks. Moreover, even an overall partial replacement of 27% clay by WCP and WBP conserved the same density as the control. Comparatively, the highest density was obtained in C45 and the lowest density in C1215. The microscopic image of the C45 brick specimen is shown in Figure 6, revealing a densely packed material. Riaz et al. reported a density of 1.27 g/cc and 1.4 g/cc for the specimens with only 15% WBP and 12% WCP, respectively: The combined mixture (12 + 15)% resulted in a density of 1.42 g/cc, which was approximately equal to that of the control specimen. This shows that 27% hybrid mix produces bricks with the same density as those made of 100% clay. The density of common clayey bricks varies from country to country. Indian codes recommend a density of 1.6 to 1.92 g/cc for ordinary clayey bricks [32]. Pakistani standards recommend a minimum weight of 3000 g for clayey bricks [25]. The average weight of the bricks during this study was found to be 2600 g, which implies that the manufactured bricks were lighter in weight. Nevertheless, the lightweight bricks are advantageous in terms of the lower dead weight of the structures if mechanical and durability properties remain within the standard limits [33].

3.2.2. Porosity

The porosity of the bricks is an important property. Higher porosity ensures good insulation, and lower porosity typically leads to higher strength due to dense packing. Higher porosity (if pores are interconnected) is also an indicator of higher water absorption, adversely affecting durability. The porosity results are shown in Figure 7. The results match with those of density in Figure 5. Overall, the density and porosity at all replacements remained in close range with those of the control specimen. However, with a slight increase in density, the porosity also slightly decreased, and vice versa. Riaz et al. reported a porosity of 38.3% and 33.2% for the specimens with only 15% WBP and 12% WCP, respectively. The combined mixture (12 + 15)% resulted in a porosity of 35.1%, which authenticates the synergic effect of the hybrid mixture. The porosity of the control specimens was 34.5%, slightly lower than that of the C1215.

3.3. Durability Properties

3.3.1. Water Absorption

Water absorption of clayey bricks directly affects durability [34]. Higher water absorption levels are associated with risk of degradation when exposed to aggressive environments. The variation of water absorption with replacement is shown in Figure 8. The results are in close coordination with the density and porosity values. Riaz et al. reported a water absorption of 24.1% and 19.5% for the specimens with only 15% WBP and 12% WCP, respectively. The combined mixture (12 + 15) % resulted in average water absorption of 23.1%, which was slightly more than expected but equal to that of the control specimen containing only clay. Pakistani building standards recommend 20% water absorption for first-class bricks and 28% for second class [25]. As such, all the bricks lay in the second-class range.

3.3.2. Initial Rate of Water Absorption

The variation of the initial rate of water absorption with partial replacement is shown in Figure 9.
The initial rate of absorption (IRA) values are not covered in the ASTM specification [35]. However, they are essential in the sense that they are a measure of how quickly the brick pulls away moisture from the overlying fresh mortar/plaster. The results show that IRA decreased with an increase in the percent replacement. According to Pavıa et al., the IRA values should range between 0.00035 and 0.0036 g/mm2/min [36]. The minimum IRA was obtained with C1215 specimens, which was about 0.0053 g/mm2/min. This indicates that the manufactured bricks should be properly wetted before laying.

3.3.3. Efflorescence

Efflorescence refers to the crystalline salt deposits that appear on the porous surface. Typical efflorescence is white but can vary in color, including yellow or brown, depending on the salt and accompanying chemicals. Common salts that lead to efflorescence include calcium sulfate, sodium sulfate, potassium sulfate, vanadyl sulfate, calcium carbonate, sodium carbonate, potassium carbonate, and manganese oxide. To examine efflorescence effects, the specimens were analyzed as per the ASTM C67-17 standard test. No efflorescence was observed in either the control or the modified bricks.

3.3.4. Sulfate Attack

When exposed to a sulfate environment, sulfate ions accumulate in the pores and exert stresses on the surrounding material. Consequently, the stresses generated by the sulfate crystals lead to the cracking of the material. The mechanism is analogous to that of chloride ingress in concrete, where chloride ions migrate inside concrete through pores and corroded steel, and the rust particles exert disruptive tensile stresses on the surrounding concrete [37]. ASTM C-67 was used to check the resistance to sulfate attacks in controlled and modified brick specimens. The bricks were immersed in a standard solution of sodium sulfate (5 gm/L) for 30 days, and the reduction in compressive strength was determined. The results are shown in Figure 10. The strength reduction decreased with an increase in replacement level, and the highest resistance to sulfate attack was seen in C1215.

3.3.5. Freeze and Thaw

Frost action, or freeze and thaw, is one of the main reasons for the deterioration of bricks in historical buildings situated in cold regions [38]. Ice owing to the larger volume exerts internal stresses that crack the bricks. In the current study, a freeze-and-thaw test was performed according to ASTM C67-17. The test results are shown in Figure 11. The minimum (0.87%) effect of freeze and thaw was observed in C45, whereas the maximum (0.96%) was seen in C1215. ASTM C67 declares a weight loss of more than 3% as a “fail” [4]. Hence, the composite mixture of WBP and WCP (up to 27%) was resistant to freeze-and-thaw action.

3.3.6. Chemical Resistance of Bricks

ASTM C-67 was used to check the chemical resistance of bricks. One end of the dried and cooled bricks was exposed to a depth of 38 mm in a 10% solution of hydrochloric acid (HCl) for 3 h. The opposite end of the bricks was submerged to the same depth in a 10% solution of potassium hydroxide (KOH) solution for 3 h. No color or texture change was observed in either the control or modified specimens. Both the control and modified specimens were found to be inert.

3.4. Mechanical Properties

3.4.1. Compressive Strength

The compressive strength of the bricks was determined according to ASTM C-67 [27] and is shown in Figure 12. The results seem to be the reflection of the porosity results shown in Figure 7. As the porosity increased, the strength also increased and vice versa.
Riaz et al. reported a compressive strength of 7.92 MPa and 10.72 MPa for specimens with only 15% WBP and 12% WCP, respectively. The combined mixture (12 + 15)% resulted in a compressive strength of 8.1 MPa, which reported a slight increase in compressive strength with the addition of 12% WCP to 15% WBC. However, 7.92 MPa strength was obtained with 15% WBP and 85% clay, whereas 8.1 MPa strength was achieved with 15% WBP, 12% WCP, and 73% clay and is, therefore, more ecological and green than the former one. The highest strength of 11 MPa was obtained with a (4 + 5)% mixture and was more than 10 MPa (threshold for first-class bricks). The second-class types had a minimum compressive strength of 7 MPa and water absorption of 25% [39]. Except for C45, all other bricks were second-class bricks suitable for external and internal walls without plastering. The first-class bricks are additionally recommended for flooring.

3.4.2. Modulus of Rupture

The MOR of the bricks was determined according to ASTM C-67. The results are shown in Figure 13. The maximum MOR of 3.3 MPa was obtained with C45, whereas the minimum was 1.84 MPa with C1215. The minimum MOR as specified by the Building Code of Pakistan, ASTM C67, and Indian Standards was 1 MPa [10,40]. Hence, all the bricks met the minimum MOR as recommended by the building codes.

4. Conclusions

Hazardous impacts of construction activities have forced researchers to innovate new ways to ensure the sustainable development of future generations. As the conservation of natural resources is a significant part of sustainability, recycling waste is a rational, logical, and economical step towards conserving these resources. The results indicated that brick and ceramic wastes are suitable for being used as a clay replacement in manufacturing bricks. The following conclusions have been drawn from the study:
  • Bricks containing waste ceramic and brick powder were free of efflorescence and had equal resistance against chemical attack, as observed in the ASTM C67 standard test.
  • Bricks containing 27% (15% WBP + 12% WCP) waste materials possessed the same density, porosity, and water absorption capacity as those containing 100% clay.
  • Bricks containing 27% (15% WBP + 12% WCP) waste materials possessed a 27% decreased initial water absorption rate compared to the control specimens.
  • Bricks with 9% (5% WBP + 4% WCP) waste materials had a compressive strength of 11 MPa, more than the control specimens with 9.8 MPa strength. However, bricks with 27% waste materials had a strength of 8.1 MPa.
  • Bricks with 9% (5% WBP + 4% WCP) waste materials had a modulus of rupture of 3.32 MPa, more than that of the control specimens with 3.26 MPa strength. However, bricks with 27% waste materials had a strength of 1.84 MPa.
  • The combination of waste brick and ceramic powder was effective against sulfate attack, and the resistance increased with an increase in the replacement level.
  • Bricks with 9% (5% WBP + 4% WCP) waste materials showed the highest resistance against freeze and thaw (only 0.87% weight loss). Nevertheless, the weight loss in all the specimens was found to be less than 1%.
Based on the current study, it is concluded that 27% mass of clay can be successfully replaced with 12% waste ceramic powder and 15% waste brick powder. The resulting end products show characteristics similar to the control specimens and overcome the deficiencies arising from using unary replacement either by waste brick powder or waste ceramic powder.

Author Contributions

Conceptualization, A.K. and R.B.N.K.; software, M.S.R. and R.B.N.K.; validation, A.K., M.S.K. and A.J.; formal analysis, R.A.K. and A.K.; investigation, M.S.K., R.B.N.K., M.T.A. and W.A.; resources, Z.T. and S.T.; writing-original draft preparation, A.K., M.S.R., R.B.N.K., A.J. and S.T.; writing-review and editing, A.K.; visulization, A.K.; supervision, A.K. and R.A.K.; project administration, A.K., R.B.N.K.,A.J., Z.T. All authors have read and agreed to the published version of the manuscript.

Funding

This research received no external funding.

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

The study did not report any data.

Acknowledgments

The authors are thankful to Asad Hanif and Junaid Tariq of the department of Civil Engineering, Mirpur University of Science and Technology (MUST) for providing assistance regarding correction of English language and evaluation of the effect of the mineralogical composition on the characteristics of the finished products.

Conflicts of Interest

The authors declare no conflict of interest.

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Figure 1. Microscopic images: (a) clay, (b) WCP, (c) WBP.
Figure 1. Microscopic images: (a) clay, (b) WCP, (c) WBP.
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Figure 2. XRD patterns of raw materials.
Figure 2. XRD patterns of raw materials.
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Figure 3. (a) Ingredients (clay (dark brown), WBP (light brown), WCP (white), (b) mixing water, (c) wet mix, (d) molding.
Figure 3. (a) Ingredients (clay (dark brown), WBP (light brown), WCP (white), (b) mixing water, (c) wet mix, (d) molding.
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Figure 4. XRD patterns of the bricks.
Figure 4. XRD patterns of the bricks.
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Figure 5. Variation of density as a function of replacement.
Figure 5. Variation of density as a function of replacement.
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Figure 6. Microscopic image of C45 showing density packed particle.
Figure 6. Microscopic image of C45 showing density packed particle.
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Figure 7. Variation of porosity with replacement.
Figure 7. Variation of porosity with replacement.
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Figure 8. Variation of water absorption with replacement.
Figure 8. Variation of water absorption with replacement.
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Figure 9. Variation of initial rate of water absorption with replacement.
Figure 9. Variation of initial rate of water absorption with replacement.
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Figure 10. Strength reduction in the sulfate attack test as a function of partial replacement.
Figure 10. Strength reduction in the sulfate attack test as a function of partial replacement.
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Figure 11. Variation of weight loss as a function of partial replacement in the freeze-and-thaw test.
Figure 11. Variation of weight loss as a function of partial replacement in the freeze-and-thaw test.
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Figure 12. Variation of compressive strength with partial replacement.
Figure 12. Variation of compressive strength with partial replacement.
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Figure 13. Variation of the modulus of rupture with partial replacement.
Figure 13. Variation of the modulus of rupture with partial replacement.
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Table 1. Oxide composition of the materials.
Table 1. Oxide composition of the materials.
ClayWCPWBPRecommended for Bricks [4]
SiO259.22771.00446.36250–60
Al2O316.60821.87729.72320–30
Fe2O36.9471.1697.785–6
SO3--5.174-
CaO13.1083.6824.8581–5
TiO20.8851.1043.929-
K2O2.920.3741.86-
Table 2. Marking of samples and material composition.
Table 2. Marking of samples and material composition.
Scheme NameClay (%)(WCP + WBP) (%)No. of Bricks
5C45914 + 550
6C810828 + 1050
7C12157312 + 1550
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Khitab, A.; Riaz, M.S.; Jalil, A.; Khan, R.B.N.; Anwar, W.; Khan, R.A.; Arshad, M.T.; Kirgiz, M.S.; Tariq, Z.; Tayyab, S. Manufacturing of Clayey Bricks by Synergistic Use of Waste Brick and Ceramic Powders as Partial Replacement of Clay. Sustainability 2021, 13, 10214. https://doi.org/10.3390/su131810214

AMA Style

Khitab A, Riaz MS, Jalil A, Khan RBN, Anwar W, Khan RA, Arshad MT, Kirgiz MS, Tariq Z, Tayyab S. Manufacturing of Clayey Bricks by Synergistic Use of Waste Brick and Ceramic Powders as Partial Replacement of Clay. Sustainability. 2021; 13(18):10214. https://doi.org/10.3390/su131810214

Chicago/Turabian Style

Khitab, Anwar, Muhammad Saqib Riaz, Affan Jalil, Raja Bilal Nasar Khan, Waqas Anwar, Riaz Akhtar Khan, Muhammad Tausif Arshad, Mehmet Serkan Kirgiz, Zeesshan Tariq, and Seemab Tayyab. 2021. "Manufacturing of Clayey Bricks by Synergistic Use of Waste Brick and Ceramic Powders as Partial Replacement of Clay" Sustainability 13, no. 18: 10214. https://doi.org/10.3390/su131810214

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