Evaluation of Matricaria aurea Extracts as Effective Anti-Corrosive Agent for Mild Steel in 1.0 M HCl and Isolation of Their Active Ingredients
Abstract
:1. Introduction
2. Experimental Section
2.1. Materials
2.1.1. Collection and Identification of Plant Material
2.1.2. Test Specimen Preparation
2.2. Methods
2.2.1. Purification of the Active Phytomolecule
2.2.2. 1D and 2D Nuclear Magnetic Resonance (NMR) Analysis
2.2.3. UV-Visible Spectroscopy
2.2.4. Mass Spectrometry (MS) Analysis
2.2.5. Chemical Structure Identification of MAB
2.2.6. Weight Loss Experiments
2.2.7. Electrochemical Studies
2.2.8. SEM and EDS Measurements
3. Results and Discussion
3.1. Screening of M. aurea Extracts for Their Corrosion Inhibitive Properties
3.2. Identification of the Compound MAB Isolated from M. aurea
3.3. Detailed Study of Corrosion Inhibitive Properties of MAB
3.3.1. Weight Loss Study
3.3.2. Tafel Plots Measurements
3.3.3. EIS Measurements
3.3.4. Adsorption Isotherm and Mechanism of Inhibition
3.3.5. EDS and SEM Analysis
4. Conclusions
- The corrosion inhibitive capability of MAB increases with increasing the concentration of MAB, and highest IE (94.0%) was achieved at 0.464 mM.
- Electrochemical studies demonstrated a mixed-type inhibitor for MAB with the inclining cathodic efficacy.
- This novel green inhibitor MAB obeys Langmuir adsorption method isotherm, protects MS specimen through physical adsorption route, and process was exothermic and spontaneous.
- EDS and SEM analysis showed highly improved surface of MS specimen with MAB in corrosive media.
- Corrosion inhibitive properties evaluation of MAB using different methods such as weight loss, Tafel plots, EIS, SEM, and EDS analysis revealed that MAB has excellent inhibitive properties for MS sample in HCl corrosive environment.
- Corrosion inhibitive properties of M. aurea extracts and its isolated compound MAB is being reported here for the first time.
- The consistent results of the electrochemical and weight loss experiments is evident that this green inhibitor can be effectively utilized as a potent corrosion inhibitor for MS in aggressive solution (1.0 M HCl).
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Concentration of Inhibitor (mM) | Weight Loss (g) | Surface Coverage | Corrosion Rate | |
---|---|---|---|---|
0 (Blank) | 0.2587 | - | 0.1354 | - |
0.116 | 0.0370 | 0.86 | 0.0194 | 85.70 ± 0.84 |
0.232 | 0.0304 | 0.88 | 0.0159 | 88.25 ± 0.98 |
0.348 | 0.0243 | 0.91 | 0.0127 | 90.61 ± 0.83 |
0.464 | 0.0161 | 0.94 | 0.0084 | 93.78 ± 0.91 |
0.580 | 0.0158 | 0.94 | 0.0083 | 93.89 ± 0.95 |
Temperatures (K) | Weight Loss (g) | Surface Coverage | Corrosion Rate | |
---|---|---|---|---|
298 ± 1 | 0.0161 | 0.94 | 0.0084 | 93.78 ± 0.91 |
313 ± 1 | 0.0174 | 0.93 | 0.0091 | 93.27 ± 0.85 |
328 ± 1 | 0.0258 | 0.93 | 0.0135 | 90.03 ± 1.02 |
MAB Concentration (mM) | (mV) | (µAcm−) | (mV/dec) | (mV/dec) | Tafel | LPR | |
---|---|---|---|---|---|---|---|
0 (Blank) | 486.6 | 213.0 | 99.85 | 110.73 | 54.5 | - | - |
0.116 | 515.5 | 29.0 | 57.31 | 73.42 | 339.64 | 86.38 | 83.95 |
0.232 | 508.7 | 23.4 | 61.16 | 75.90 | 499.18 | 89.01 | 89.08 |
0.348 | 521.8 | 19.8 | 59.25 | 80.71 | 576.39 | 90.70 | 90.54 |
0.464 | 513.5 | 10.2 | 63.41 | 83.62 | 907.02 | 95.21 | 94.00 |
Concentration (mM) | ||||
---|---|---|---|---|
0 (Blank) | 57.1 | 533.0 | - | - |
0.116 | 385.0 | 352.3 | 0.85 | 85.17 |
0.232 | 479.7 | 348.2 | 0.88 | 88.10 |
0.348 | 634.0 | 222.3 | 0.91 | 91.00 |
0.464 | 886.4 | 118.4 | 0.94 | 93.56 |
Compound | |||
---|---|---|---|
MAB | 19.66 | 10.23 | 31.64 |
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Khan, M.; Abdullah, M.M.S.; Mahmood, A.; Al-Mayouf, A.M.; Alkhathlan, H.Z. Evaluation of Matricaria aurea Extracts as Effective Anti-Corrosive Agent for Mild Steel in 1.0 M HCl and Isolation of Their Active Ingredients. Sustainability 2019, 11, 7174. https://doi.org/10.3390/su11247174
Khan M, Abdullah MMS, Mahmood A, Al-Mayouf AM, Alkhathlan HZ. Evaluation of Matricaria aurea Extracts as Effective Anti-Corrosive Agent for Mild Steel in 1.0 M HCl and Isolation of Their Active Ingredients. Sustainability. 2019; 11(24):7174. https://doi.org/10.3390/su11247174
Chicago/Turabian StyleKhan, Merajuddin, Mahmood M. S. Abdullah, Adeem Mahmood, Abdullah M. Al-Mayouf, and Hamad Z. Alkhathlan. 2019. "Evaluation of Matricaria aurea Extracts as Effective Anti-Corrosive Agent for Mild Steel in 1.0 M HCl and Isolation of Their Active Ingredients" Sustainability 11, no. 24: 7174. https://doi.org/10.3390/su11247174