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Materials 2015, 8(1), 31-41;

Enhanced Photocatalytic Efficiency of N–F-Co-Embedded Titania under Visible Light Exposure for Removal of Indoor-Level Pollutants

Department of Environmental Engineering, Kyungpook National University, Daegu 702-701, Korea
Department of Naval Architecture and Ocean Engineering, Pusan National University, 63 Jangjeon-dong, Geumjeong-gu, Busan 609-735, Korea
Author to whom correspondence should be addressed.
Academic Editor: Klara Hernadi
Received: 13 September 2014 / Accepted: 1 December 2014 / Published: 24 December 2014
(This article belongs to the Special Issue Photocatalytic Materials)
Full-Text   |   PDF [1260 KB, uploaded 24 December 2014]   |  


N–F-co-embedded titania (N–F–TiO2) photocatalysts with varying N:F ratios were synthesized and tested for their ability to photocatalyze the degradation of pollutants present at indoor air levels using visible light. The synthesis was achieved using a solvothermal process with tetrabutyl titanate, urea and ammonium fluoride as sources of Ti, N and F, respectively. Three selected volatile organic compounds (toluene, ethyl benzene and o-xylene) were selected as the test pollutants. The prepared composites were characterized using X-ray diffraction, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy and Ultra-violet (UV)-visible spectroscopy. The photocatalytic degradation efficiencies of N–F–TiO2 composites were higher than those obtained using pure TiO2 and N–TiO2. Moreover, these efficiencies increased as the N:F ratio decreased from sixteen to eight, then decreased as it dropped further to three, indicating the presence of an optimal N:F ratio. Meanwhile, as retention time decreased from 12.4 to 0.62 s, the average photocatalytic efficiencies decreased from 65.4% to 21.7%, 91.5% to 37.8% and 95.8% to 44.7% for toluene, ethyl benzene and o-xylene, respectively. In contrast, the photocatalytic reaction rates increased as retention time decreased. In consideration of all of these factors, under optimized operational conditions, the prepared N–F–TiO2 composites could be utilized for the degradation of target pollutants at indoor air levels using visible light. View Full-Text
Keywords: N,F co-embedment; N:F ratio; retention time; indoor air levels N,F co-embedment; N:F ratio; retention time; indoor air levels

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Shin, S.-H.; Chun, H.-H.; Jo, W.-K. Enhanced Photocatalytic Efficiency of N–F-Co-Embedded Titania under Visible Light Exposure for Removal of Indoor-Level Pollutants. Materials 2015, 8, 31-41.

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