CO2 Separation and Capture Properties of Porous Carbonaceous Materials from Leather Residues
by
José M. Bermúdez 1,2, 
Pablo Haro Dominguez 3, Ana Arenillas 2, Jaume Cot 4, Jens Weber 3 and Rafael Luque 1,*
José M. Bermúdez 1,2, Pablo Haro Dominguez 3, Ana Arenillas 2, Jaume Cot 4, Jens Weber 3 and Rafael Luque 1,*
1
Departamento de Química Orgánica, Universidad de Córdoba, Edif. Marie Curie, Ctra Nnal IV-A, Km 396, Córdoba E14014, Spain
2
Instituto Nacional del Carbón, CSIC, Apartado 73, Oviedo 33080, Spain
3
Max Planck Institute for Colloids and Interfaces, Department of Colloid Chemistry, Science Park Golm, Potsdam 14424, Germany
4
Institut de Quiımica Avancada de Catalunya (IQAC)—Consejo Superior de Investigaciones Cientıficas (CSIC), C/Jordi Girona, 18–26, Barcelona 08034, Spain
*
Author to whom correspondence should be addressed.
Materials 2013, 6(10), 4641-4653; https://doi.org/10.3390/ma6104641
Received: 2 September 2013 / Revised: 3 October 2013 / Accepted: 9 October 2013 / Published: 18 October 2013
(This article belongs to the Section Porous Materials)
Carbonaceous porous materials derived from leather skin residues have been found to have excellent CO2 adsorption properties, with interestingly high gas selectivities for CO2 (α > 200 at a gas composition of 15% CO2/85% N2, 273K, 1 bar) and capacities (>2 mmol·g−1 at 273 K). Both CO2 isotherms and the high heat of adsorption pointed to the presence of strong binding sites for CO2 which may be correlated with both: N content in the leather residues and ultrasmall pore sizes.
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MDPI and ACS Style
Bermúdez, J.M.; Dominguez, P.H.; Arenillas, A.; Cot, J.; Weber, J.; Luque, R. CO2 Separation and Capture Properties of Porous Carbonaceous Materials from Leather Residues. Materials 2013, 6, 4641-4653.
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