Sorption of Aromatic Compounds with Copolymer Sorbent Materials Containing β-Cyclodextrin
Abstract
:1. Introduction
2. Methods
2.1. Materials
2.2. Sorption Methods
2.3. Data Analysis
3. Results and Discussion
2,4 DCP | GAC | MDI-3 | CDI-3 | |
Qm (mmol/g) | 1.17 | 0.542 | 1.14 | |
KS (mM−1) | 656 | 444 | 391 | |
ns | 0.619 | 1.59 | 2.00 | |
2,4 D | Qm (mmol/g) | 0.641 | 0.607 | 0.0394 |
KS (mM−1) | 1.28 × 103 | 929 | 1.56 | |
ns | 0.390 | 2.08 | 1.08 | |
PCP | Qm (mmol/g) | 0.306 | 0.0860 | 0.0540 |
KS (mM−1) | 51.2 | 2.17 | 24.0 | |
ns | 0.816 | 0.717 | 1.65 |
Sorbent Material | SA (BET) (m2/g) a | Dye Method SA (m2/g) b | Vads(m3/g) c | Qm(mmol/g) d |
---|---|---|---|---|
CDI-3 | 0.332 | 620 | 33.9 | 1.96 |
MDI-3 | 2.96 | 449 | 24.6 | 1.42 |
GAC | 951 | 641 | 35.1 | 35.1 |
Adsorbate | Keq (L.mol−1) pH = 4.6 | Keq (L.mol−1) pH = 9.0 |
---|---|---|
2,4-DCP | 245 (350 ± 23)49 (556 ± 17)49 | 350 |
2,4-D | 197 (63.58 ± 5.77) 50 | 410 |
PNP | 338 (159)51 | 370 (1549)51 |
4. Conclusions
Acknowledgments
References
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Wilson, L.D.; Mohamed, M.H.; Berhaut, C.L. Sorption of Aromatic Compounds with Copolymer Sorbent Materials Containing β-Cyclodextrin. Materials 2011, 4, 1528-1542. https://doi.org/10.3390/ma4091528
Wilson LD, Mohamed MH, Berhaut CL. Sorption of Aromatic Compounds with Copolymer Sorbent Materials Containing β-Cyclodextrin. Materials. 2011; 4(9):1528-1542. https://doi.org/10.3390/ma4091528
Chicago/Turabian StyleWilson, Lee D., Mohamed H. Mohamed, and Christopher L. Berhaut. 2011. "Sorption of Aromatic Compounds with Copolymer Sorbent Materials Containing β-Cyclodextrin" Materials 4, no. 9: 1528-1542. https://doi.org/10.3390/ma4091528