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Article

Titania-Based Oxide Catalysts for Removing Nitrogen Oxides

1
AGH University of Krakow, Faculty of Energy and Fuels, Mickiewicza 30, 30-059 Krakow, Poland
2
Jerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, Niezapominajek 8, 30-239 Krakow, Poland
*
Author to whom correspondence should be addressed.
Materials 2026, 19(1), 20; https://doi.org/10.3390/ma19010020 (registering DOI)
Submission received: 29 October 2025 / Revised: 16 December 2025 / Accepted: 17 December 2025 / Published: 20 December 2025
(This article belongs to the Special Issue Advanced Nanoporous and Mesoporous Materials)

Abstract

Titania catalysts containing cerium, copper, or iron were obtained using the sol–gel method and tested in the selective reduction of nitrogen oxide. Samples with cerium and iron showed high activity at temperatures ranging from 200 to 400 °C, without the formation of N2O. The materials crystallized in anatase structure, and only a small amount of ceria was detected by XRD. Their crystallites were nanometric in size. The solids were mesoporous, with a specific surface area between 74 and 160 m2/g, determined based on nitrogen sorption at low temperature. The optimum Ce/Ti and Fe/Ti atomic ratio was 0.1 to 0.9, and such catalysts were composed of small anatase crystallites, although the presence of ceria also resulted in high catalytic activity. This activity was due to the presence of Fe3+ or Ce3+ ions on the surface of the material.
Keywords: sol–gel; titania; cerium; iron; SCR NO sol–gel; titania; cerium; iron; SCR NO

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MDPI and ACS Style

Białas, A.; Kowalska, N.; Zimowska, M.; Mordarski, G.; Gurgul, J. Titania-Based Oxide Catalysts for Removing Nitrogen Oxides. Materials 2026, 19, 20. https://doi.org/10.3390/ma19010020

AMA Style

Białas A, Kowalska N, Zimowska M, Mordarski G, Gurgul J. Titania-Based Oxide Catalysts for Removing Nitrogen Oxides. Materials. 2026; 19(1):20. https://doi.org/10.3390/ma19010020

Chicago/Turabian Style

Białas, Anna, Natalia Kowalska, Małgorzata Zimowska, Grzegorz Mordarski, and Jacek Gurgul. 2026. "Titania-Based Oxide Catalysts for Removing Nitrogen Oxides" Materials 19, no. 1: 20. https://doi.org/10.3390/ma19010020

APA Style

Białas, A., Kowalska, N., Zimowska, M., Mordarski, G., & Gurgul, J. (2026). Titania-Based Oxide Catalysts for Removing Nitrogen Oxides. Materials, 19(1), 20. https://doi.org/10.3390/ma19010020

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