2.1. Raw Materials
Porous asphalt concrete (PAC) primarily consists of asphalt binder, a large proportion of coarse aggregates, a small amount of fine aggregates, and mineral filler. The properties of these raw materials play a critical role in determining the performance of PAC. Therefore, the selection of high-quality materials is essential.
- (1)
Asphalt Binder
In this study, a SK70# base asphalt binder produced by SK Corporation (Seoul, Republic of Korea) was used, which was provided by Gansu Gongfa Longzhong High Tech Highway Maintenance Technology Co., Ltd., Lanzhou, China. The technical performance indicators of the asphalt binder are summarized in
Table 1. It can be seen that all technical properties meet the requirements of the specification JTG E20-2011 [
26].
- (2)
TPS High-Viscosity Modifier
To improve the bonding performance of the asphalt and mitigate raveling issues in porous asphalt mixtures, a high-viscosity modifier—TPS (TAFPACK-Super)—was selected. TPS is a specialized additive developed by DAIYU Co., Ltd., Shinjo, Japan, specifically for porous asphalt pavements. The primary component of TPS is thermoplastic rubber, with other ingredients including tackifying resins and plasticizers. It appears as yellow elastomeric granules measuring approximately 2–3 mm in diameter.
Figure 1 shows the appearance of the TPS modifier, and its technical specifications are listed in
Table 2.
- (3)
Coarse Aggregates
High-quality basalt was selected as the coarse aggregate for this study, sourced from the Yongdeng Jianxin Quarry in Lanzhou of Gansu Province. The fundamental physical properties were tested according to JTG E42-2005 [
27]. The results are presented in
Table 3.
- (4)
Fine Aggregates
Machine-manufactured sand from the same quarry was used as the fine aggregate. The basic physical properties were tested, and the results are shown in
Table 4.
- (5)
Mineral Filler
Limestone powder provided by Gansu Gongfa Longzhong Highway Maintenance Technology Co., Ltd., Lanzhou, China was used as the mineral filler in this study. The basic properties of the filler are summarized in
Table 5.
2.2. PAC Mix Design
Two different nominal maximum aggregate sizes were used in this study, namely 13.2 mm (PAC-13) and 9.5 mm (PAC-10). The procedures of the gradation curves determination for PAC-10 and PAC-13 are shown in
Figure 2. The key difference between the two gradations lies in the proportion of aggregates retained on each sieve, especially for the 9.5 mm and 4.75 mm sieves.
- (1)
Gradation design
In general, the permeability of porous asphalt concrete (PAC) increases with higher porosity. However, excessive air voids may compromise the durability of the mixture. Conversely, a void content that is too low may result in poor drainage performance and moisture retention, which could lead to water-induced damage. Therefore, the porosity of PAC is typically controlled within the range of 18% to 25% [
28].
1. Preliminary gradation design
Previous studies have shown that the porosity of PAC is closely related to the passing rate of the 2.36 mm sieve. Accordingly, three preliminary gradations were designed by adjusting the passing percentage of the 2.36 mm sieve within ±3% of the median value specified by the technical specifications. The corresponding gradation curves are shown in
Figure 3 and
Figure 4, respectively. G1 denotes the gradation where the passing percentage through the 2.36 mm sieve exceeds the median value by 3%, G2 represents the gradation where the passing percentage through the 2.36 mm sieve equals the median value, and G3 signifies the gradation where the passing percentage through the 2.36 mm sieve is below the median value by 3%.
2. Estimation of initial asphalt content
The asphalt content of PAC mixtures is typically estimated based on the surface area of the aggregate and its asphalt absorption capacity. Accordingly, the preliminary asphalt content for each gradation was calculated using Equation (1).
where
Pb is asphalt content, %;
h is asphalt film thickness, μm;
A is specific surface area of aggregates. The asphalt film thickness of 12 μm was assumed for PAC mixture, within the typical range of 10~14 μm [
29].
The specific surface area
A of the aggregates was calculated using Equation (2) [
29].
where
a,
b,
c,
d,
e,
f,
g, and
h represent the mass passing percentages through the 19 mm, 4.75 mm, 2.36 mm, 1.18 mm, 0.6 mm, 0.3 mm, 0.15 mm, and 0.075 mm sieves, respectively, %.
The estimated asphalt content for each PAC-13 and PAC-10 mixture are shown in
Table 6.
3. Determination of target-porosity gradations
Using the gradation and asphalt content values in
Table 3 and
Table 4, Marshall specimens were prepared. Porosities were determined using volumetric measurement method. The volumetric results are shown in
Table 7. The regression relationships between the 2.36 mm passing rate and porosity are plotted in
Figure 5.
As illustrated in
Figure 5, a strong linear correlation exists between the porosity and the 2.36 mm sieve passing percentage for both PAC-13 and PAC-10 mixtures, where the coefficient of determination R
2 is larger than 0.95. This indicates that porosity can be predicted based on the 2.36 mm passing percentage, and conversely, desired void levels can be achieved by adjusting the 2.36 mm passing percentage. Based on this correlation, the passing rates corresponding to target porosities of 18%, 20%, and 25% were back-calculated, and the corresponding gradations were designed by adjusting the aggregate proportions. The results are summarized in
Table 8.
Based on the 2.36 mm sieve passing percentage corresponding to each target porosity level for PAC-13 and PAC-10 in
Table 8, and after appropriate adjustments, the final aggregate gradations were determined. The gradation curves are shown in
Figure 6 and
Figure 7, respectively.
- (2)
Determination of optimum asphalt content
The initial asphalt content was calculated using Equations (2) and (3), and the asphalt content varies by ±0.5% around this baseline value according to JTG E42-2005 [
27]. Asphalt mixtures with different binder contents were prepared following the standard PAC mixing procedure. Subsequently, a binder drainage test, Cantabro test, and Marshall stability tests were conducted in accordance with relevant specifications. The optimum asphalt content range was determined based on the drainage test and Cantabro test results, while the final optimum content for each PAC mixture was selected with reference to the Marshall stability results.
The binder drainage test is used to identify the maximum allowable asphalt content that prevents binder segregation, whereas the Cantabro test determines the minimum binder content needed to avoid significant aggregate loss. In this study, the binder drainage test was performed using the beaker method as specified in the Specification JTG E20-2011 [
26]. This method simulates asphalt drainage conditions during storage and transportation under elevated temperatures to evaluate the mixture’s resistance to drainage, where the drainage loss as a quantifiable indicator, defined as the mass ratio of drained asphalt binder to the total mixture, is calculated. The Cantabro test was conducted to evaluate the bonding strength between aggregates and binder, where the Cantabro loss, defined as the mass ratio of loss particles to the total mixture, was calculated according to JTG E20-2011.
The initial asphalt content for the PAC-13 mixture with a target porosity of 20% was calculated as 4.9% using Equation (1). Accordingly, five asphalt contents (4.0%, 4.5%, 5.0%, 5.5%, and 6.0%) were selected for testing.
Figure 8 illustrates the relationship between asphalt content and both drainage loss and Cantabro loss. Moreover,
Table 9 presents the corresponding porosities and Marshall stability values at different asphalt contents.
As shown in
Figure 8, Cantabro loss decreases as the asphalt content increases, whereas drainage loss increases. The intersection points of the two curves indicate that the minimum and maximum allowable asphalt contents are 4.6% and 5.0%, respectively. Therefore, the optimum asphalt content range for PAC-13 with 20% target porosities was determined to be 4.6–5.0%. As presented in
Table 9, the porosity decreases with increasing asphalt content. All mixtures tested exhibited Marshall stability values exceeding the minimum required standard of 3.5 kN. Considering the open-graded nature and durability requirements of PAC mixtures, a slightly higher asphalt content was selected to enhance the thickness of the asphalt film. Therefore, an optimum asphalt content of 4.9% was determined for the PAC-13 mixture with 20% target porosities.
The same procedure was employed to determine the optimum asphalt contents for all other PAC mixtures. The final optimum asphalt contents for PAC-10 and PAC-13 at different target porosity levels are summarized in
Table 10.
2.3. Test Methods
- (1)
Preparation method of PAC specimen
According to the asphalt mixture specimen preparation method specified in the Specifications JTG E20-2011 [
26], the porous asphalt concrete (PAC) was prepared as follows. It should be noted that the following used temperature and time are all from this specification.
Firstly, based on the pre-determined PAC gradation, a total of 1100 g of aggregate and mineral filler (by mass) was weighed according to each particle size category. The materials were then placed in an oven at 185 °C for 6 h for preheating.
Secondly, SK70# asphalt was placed in an oven at 135 °C for 1 h and then rapidly heated to 160 °C using an electric heater before mixing.
Thirdly, the preheated aggregates were added to a mixing pot preheated to 185 °C. A pre-measured amount of TPS modifier (at a ratio of TPS to base asphalt is 12 to 88) was added and dry mixed for 90 s.
Fourthly, after dry mixing, the preheated SK70# asphalt and mineral filler were added into mixing pot of mixing machine, followed by wet mixing for 90 s.
Fifthly, the prepared asphalt mixture was removed from the mixing pot and kept in an oven at 175 °C for 10 min. The mixture was then placed into a standard Marshall mold and compacted using a Marshall compactor with 50 blows on each side. The specimen was demolded after cooling for 24 h to ensure sufficient cooling to room temperature.
- (2)
Porosity measurement method of PAC specimen
The porosity of asphalt mixtures is generally controlled by the bulk volume density, apparent density, and maximum theoretical density. The Specifications JTG E20-2011 provide four methods for density measurement, namely the saturated surface-dry (SSD) method, immersion method, wax-sealing method, and volume method [
26]. For PAC, the bulk volume density was measured using the volume method for the large porosity.
The bulk volume of a Marshall specimen is calculated by Equation (3).
where
V is bulk volume of the specimen, cm
3;
d is diameter of the Marshall specimen, cm;
h is height of the specimen, cm.
The bulk density is calculated by Equation (4).
where
is bulk density, measured using the volume method, g/cm
3;
ma is mass of the dry specimen, g.
The bulk specific gravity at 25 °C is calculated by Equation (5).
where
is bulk specific gravity, dimensionless.
The porosity
VV is calculated by Equation (6).
where
VV is porosity of the Marshall specimen, %.
As shown in
Figure 9, the voids calculated by Equation (6) include three types, namely connected voids, semi-connected voids, and seal voids. In practical water infiltration processes, only connected voids contribute to permeability, which was defined as the effective porosity.
The connected void is measured using the submerged method, as calculated by Equations (7) and (8).
where
is the connected void volume, %;
is the volume of the mixture excluding seal voids, mm
3;
is the total volume of the specimen, mm
3;
is the mass of the dry specimen, g;
is the mass of the specimen in water, g;
is water density at room temperature, g/cm
3.
- (3)
Permeability coefficient testing method for PAC
The permeability coefficient is derived based on Darcy’s law, which describes the inverse relationship between the flow velocity and the cross-sectional area of a pipeline under steady-state flow conditions when a fluid passes through it. The most commonly used measurement methods are the variable head test and the constant head test [
30]. The constant head test is suitable for media with a large number of voids and a relatively high permeability coefficient. Such media usually require a relatively low starting pressure for the water flow. In the constant head test, a relatively small constant head difference is specified, and the permeability coefficient is measured by controlling the water flow velocity to ensure that the water flow state inside the medium is in a laminar flow state. The amount of seepage generated by the test specimen per unit time is measured. On the other hand, the variable head test is suitable for media with few voids and a low permeability coefficient. Such media require a relatively high starting pressure. The test is carried out by specifying an initial head height, and what is measured is the time required for a unit volume of water to pass through the test piece. The head is expressed as a function of time. The previous investigation found that the permeability coefficient of PAC mixtures can be measured with either a constant head method or a variable head method, while the variable head method mitigates measurement inaccuracies associated with low-flow-rate conditions [
31].
In this study, the variable head test method was used. Referring to the variable head permeability apparatus and method proposed in the literature [
20], some modifications were made. A schematic diagram of the test setup is shown in
Figure 10.
Prior to testing, the entire edge of the specimen was wrapped in plastic film. To seal any small gaps between the specimen and the inner wall of the standpipe, a silicone ring was added outside the plastic wrap, followed by another plastic film layer. Vaseline was applied to the outermost layer to prevent water leakage from the interface. Water was added until the level reached approximately 375 mm above the top surface of the specimen. After waiting for air to escape from the voids, the valve was opened. When the water level dropped to 300 mm above the specimen surface (
h1), timing began. Timing stopped when the water level dropped to 75 mm above the specimen surface (
h2). The permeability coefficient was then calculated using Darcy’s Law, as shown in Equation (9).
where
K is permeability coefficient, mm/s;
a is cross-sectional area of the standpipe, mm
2;
L is height of the specimen, mm;
A is cross-sectional area of the specimen, mm
2;
t is permeability time, s.