Recent Progress of Layered Double Hydroxide-Based Materials in Wastewater Treatment
Abstract
:1. Introduction
2. Preparation and Modification of LDHs
2.1. Coprecipitation Method
2.2. Hydrothermal Method
2.3. Ion Exchange Method
2.4. Calcination Recovery Method
2.5. Sol–Gel Method
3. Adsorptive Removal of Pollutants by LDH-Based Materials
3.1. Inorganic Pollutants
3.1.1. Heavy Metals
Adsorbent | Heavy Metal Ions | Adsorption Conditions | Theoretical Adsorption Capacity (mg/g) | Adsorption Mechanism | Ref. | ||
---|---|---|---|---|---|---|---|
Adsorbent Dosage | pH | Oscillation Time (min) | |||||
MgAl-CO3-LDH, Fe3O4/MgAl-CO3-LDH | Cd2+ Cd2+ | 0.08 g | 4 | 60 300 | 61.40~70.20 45.60~54.70 | precipitation, surface adsorption, surface complexation | [28] |
MgAl-Cys-LDH | Cu2+ Pb2+ Cd2+ | 0.05 g | 4 | 90 180 10 | 58.07 186.20 93.11 | precipitation, surface complexation, isomorphous replacement | [29] |
Fe3O4/LDH-AM | Cd2+ Pb2+ Cu2+ | 0.05 g | 5~6 | 240 180 240 | 74.06 266.60 64.66 | surface complexation, precipitation | [58] |
Magnetic MgAl-LDO/carbon | Cd2+ Pb2+ Cu2+ | 6 | 90 120 400 | 386.10 359.70 192.70 | precipitation, surface complexation, electrostatic attraction | [59] | |
CS/MgAl-LDH | Pb2+ Cu2+ | 0.05 g | 6 | 10 60 | 333.30 140.80 | precipitation, surface complexation, isomorphous replacement | [60] |
CaAl-LDH | Cu2+ Cd2+ | 0.01 g | 5/5.8 | 381.90 1035.40 | precipitation, isomorphous replacement, surface complexation | [57] | |
GO/LDH Fe3O4@GO/LDH | Cu2+ Cd2+ Pb2+ | 20 mg | 240 | 89.26~80.72 76.67~70.26 226.98~213.96 | surface complexation, precipitation, isomorphous replacement | [41] | |
LDH-EDTA-AM | Cr6+ | 30 | 48.47 | electrostatic attraction, surface complexation, ion exchange, reduction | [30] | ||
Fe3O4-ZnAl-LDH/TiO2 | Cr6+ | 0.02 g/L | 3 | 480 | electrostatic attraction, ion exchange, photoreduction | [61] | |
CaAl-LDH CAL-PPy | Cr6+ | 0.03 g | 34.06 66.14 | electrostatic attraction, surface complexation, anion exchange, reduction | [40] |
3.1.2. Inorganic Anions
3.2. Organic Pollutants
3.2.1. Dyes
3.2.2. Oil
3.2.3. Persistent Organic Pollutants (POPs)
3.3. Other Pollutants
4. Application of LDHs in Advanced Oxidation Processes
4.1. Fenton-like Reaction
4.2. Persulfate-Based AOPs
4.3. Electrocatalytic System
5. Conclusions and Prospect
- (1)
- In terms of the preparation of LDHs, the method of high-performance LDHs is relatively cumbersome and not conducive to industrial production, which limits the application. In addition, LDHs are mostly in powder form and are difficult to be recovered after the treatment process;
- (2)
- In terms of wastewater treatment using LDH-based materials, most of the studies are still on the laboratory scale. LDHs are often used to remove a single pollutant, while various pollutants usually coexist in the water environment;
- (3)
- In terms of mechanism research, there is a lack of in-depth methods, and the quantitative contribution of each mechanism to the total capacity needs to be further investigated.
- (1)
- Due to the urgent demand for high-efficient and low-cost materials for treating wastewater, there is a need to produce sustainable, low-cost, and industry-scale LDHs. For better recovery of LDHs and improvement of reusability during large-scale use, magnetic or non-powdered LDHs can be designed and synthesized for wastewater treatment;
- (2)
- To make full use of the advantages of LDHs and other nanomaterials, high-performance LDH-based composites can be prepared via various methods. For example, LDHs with multivariate ions and the combination of LDHs with other high-performance materials may be one of the research directions to obtain high-performance catalysts;
- (3)
- More work from laboratory to industrial production is urgently needed. There is also a need to strengthen the research on the performance of modified LDHs in removing specific pollutants selectively from multiple pollutants;
- (4)
- Further in-depth studies on the mechanisms of LDHs for various pollutants can be carried out by means of spectroscopic characterization, interfacial chemical methods, and theoretical calculations. The contribution of each mechanism should be conducted to understand the interfacial process.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Fu, Y.; Fu, X.; Song, W.; Li, Y.; Li, X.; Yan, L. Recent Progress of Layered Double Hydroxide-Based Materials in Wastewater Treatment. Materials 2023, 16, 5723. https://doi.org/10.3390/ma16165723
Fu Y, Fu X, Song W, Li Y, Li X, Yan L. Recent Progress of Layered Double Hydroxide-Based Materials in Wastewater Treatment. Materials. 2023; 16(16):5723. https://doi.org/10.3390/ma16165723
Chicago/Turabian StyleFu, Yanli, Xiaoqian Fu, Wen Song, Yanfei Li, Xuguang Li, and Liangguo Yan. 2023. "Recent Progress of Layered Double Hydroxide-Based Materials in Wastewater Treatment" Materials 16, no. 16: 5723. https://doi.org/10.3390/ma16165723