Synthesis and Characterization of the Metal–Organic Framework CIM-80 for Organic Compounds Adsorption
Abstract
:1. Introduction
2. Materials and Methods
Characterization
3. Results and Discussion
3.1. Reaction Yield
3.2. X-ray Diffraction
3.3. Textural Properties—N2 Adsorption
3.4. Scanning Electron Microscopy (SEM) and Transmision Electronic Microscopy (TEM)
3.5. Thermogravimetric Analysis (TGA) and Fourier Transform Infrared Spectroscopy (FTIR)
3.6. Characterization of Calcined Samples
3.7. Water and VOC Adsorption on MOF CIM-80_6
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Sample | Amount of Urea | % Yield |
---|---|---|
CIM-80_2 | 2 mmol | 20 |
CIM-80_4 | 4 mmol | 37 |
CIM-80_6 | 6 mmol | 67 |
CIM-80_7.5 | 7.5 mmol | 41 |
CIM-80_8.5 | 8.5 mmol | 30 |
CIM-80_10 | 10 mmol | 27 |
CIM-80_10_CTAB | 10 mmol + CTAB | 27 |
AlO(OH) | 10 mmol | 98 |
Sample | Specific Surface BET (m2/g) | V0 (cm3/g) | Vmeso (cm3/g) | Vtotal (cm3/g) |
---|---|---|---|---|
CIM-80_2 | 787 | 0.39 | 0.17 | 0.56 |
CIM-80_4 | 787 | 0.40 | 0.06 | 0.46 |
CIM-80_6 | 798 | 0.41 | 0.05 | 0.46 |
CIM-80_7.5 | 610 | 0.31 | 0.22 | 0.53 |
CIM-80_8.5 | 265 | 0.12 | 0.47 | 0.59 |
CIM-80_10 | 205 | 0.08 | 0.70 | 0.78 |
CIM-80_10_CTAB | 177 | 0.07 | 0.62 | 0.69 |
AlO(OH) | 72 | 0.03 | 0.41 | 0.44 |
Sample | BET (m2/g) | Vo (cm3/g) | Vmeso | Vtotal |
---|---|---|---|---|
CIM-80_10-C-550 °C | 181 | 0.08 | 0.59 | 0.67 |
AlOOH-C-550 °C | 150 | 0.06 | 0.42 | 0.47 |
VOCs | Density, ρ (g/mL, 25 °C) | M (g/mol) | D (nm) | σ (nm2) | Q0 (mg/g) | V (mL/g) |
---|---|---|---|---|---|---|
Toluene | 0.866 | 92.15 | 0.585 | 0.344 | 250.26 | 0.289 |
Cyclohexane | 0.779 | 84.16 | 0.600 | 0.347 | 159 | 0.204 |
m-xylene | 0.860 | 106.16 | 0.680 | 0.379 | 18.29 | 0.021 |
Material | Precursor | B.E.T. (m2/g) | Vtotal (cm3/g) | V0 (cm3/g) | Pore Size (nm) | Green Synthesis | Q0(mg/g) Toluene | Ref |
---|---|---|---|---|---|---|---|---|
AC | Anthracite | 2746 | 0.97 | 0.8 | - | ↓ B | 640 | [16] |
AC | Organic biomass | 990 | - | 0.09 | 2.7 | ↓ B | 109 | [45] |
AC | Organic biomass | 805 | - | 0.47 | 2.35 | ↓ B | 59.2 | [46] |
Zeolite 13× | Si/Al | 440 | 0.12 | - | 9.9 | ↓ B | 16.02 | [45] |
MIL-100 | Fe | 1398 | 1.08 | 0.46 | 1.36 | ↑ WS | 663 | [47] |
MIL-101 | Cr | 3980 | 1.85 | - | 2.6 | ↑ WS | 1067 | [44] |
MOF-177 | Zn | 2970 | 1.11 | - | 0.94 | ↓ OS | 585 | [28] |
MIL-125-NH2 | Ti | 1280 | - | 0.56 | 0.4 | ↓ OS | 293 | [48] |
UiO-66-NH2 | Zr | 1250 | 0.62 | - | 1.98 | ↓ OS | 147 | [49] |
UiO-66 | Zr | 1414 | 0.68 | - | 1.93 | ↓ OS | 64.2 | [49] |
ZIF-67 | Co | 1401 | 1.22 | - | 3.49 | ↑ WS | 50.8 | [49] |
MOF-5 | Zn | 424 | 0.22 | - | 2.07 | ↓ OS | 32.9 | [49] |
CIM-80 | Al | 798 | 0.46 | 0.41 | 0.63 | ↑ WS | 250.6 | This work |
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Figueroa-Quintero, L.; Ramos-Fernandez, E.V.; Narciso, J. Synthesis and Characterization of the Metal–Organic Framework CIM-80 for Organic Compounds Adsorption. Materials 2022, 15, 5326. https://doi.org/10.3390/ma15155326
Figueroa-Quintero L, Ramos-Fernandez EV, Narciso J. Synthesis and Characterization of the Metal–Organic Framework CIM-80 for Organic Compounds Adsorption. Materials. 2022; 15(15):5326. https://doi.org/10.3390/ma15155326
Chicago/Turabian StyleFigueroa-Quintero, Leidy, Enrique Vicente Ramos-Fernandez, and Javier Narciso. 2022. "Synthesis and Characterization of the Metal–Organic Framework CIM-80 for Organic Compounds Adsorption" Materials 15, no. 15: 5326. https://doi.org/10.3390/ma15155326