Surface Functionalisation of Dental Implants with a Composite Coating of Alendronate and Hydrolysed Collagen: DFT and EIS Studies
Abstract
:1. Introduction
2. Materials and Methods
2.1. Chemicals, Solutions, and Materials
2.2. Functionalisation of the Implant Surfaces
2.3. Characterisation of the Implants
2.4. Quantum Chemical Calculations
3. Results
3.1. The As-Received Implant—Morphological, Chemical, and Phase Analysis
3.2. The Chemical Characterisation of the Implant
3.3. The Coating’s Formation Mechanism on the Implant
3.4. The Electrochemical Behaviour of Implants in Artificial Saliva Solution
4. Discussion
5. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Samples | Rs/Ω cm2 | CPE1∙106/ Ω−1 cm−2 sn1 | n1 | C1/µF cm−2 | R1/Ω cm2 | CPE2∙106/ Ω−1 cm−2 sn1 | n2 | C2/µF cm−2 | R2/MΩ cm2 | η/% |
---|---|---|---|---|---|---|---|---|---|---|
AS-RECEIVED IMPLANT | ||||||||||
1 h | 111 | 9.98 | 0.853 | 3.02 | 760 | 5.16 | 0.850 | 1.38 | 9.90 | |
1 day | 123 | 2.88 | 0.997 | 2.88 | 174 | 12.1 | 0.788 | 2.10 | 0.79 | |
7 days | 123 | 3.26 | 0.978 | 2.71 | 307 | 9.21 | 0.810 | 1.88 | 0.44 | |
IMPLANT/TiO2/ALENDRONATE | ||||||||||
1 h | 109 | 2.00 | 1 | 2.00 | 307 | 9.21 | 0.820 | 2.03 | 39.0. | 74.6 |
1 day | 119 | 1.95 | 1 | 1.95 | 332 | 8.05 | 0.806 | 1.48 | 16.5 | 95.2 |
7 days | 109 | 1.98 | 1 | 1.98 | 302 | 7.23 | 0.795 | 1.15 | 5.88 | 92.5 |
IMPLANT/TiO2/HYDROLYSED COLLAGEN | ||||||||||
1 h | 149 | 2.03 | 1 | 2.03 | 851 | 5.46 | 0.815 | 1.07 | 54.5 | 81.8 |
1 day | 147 | 2.09 | 1 | 2.09 | 641 | 6.45 | 0.809 | 0.91 | 24.0 | 96.7 |
7 days | 160 | 1.95 | 1 | 1.95 | 501 | 5.40 | 0.782 | 0.45 | 60.1 | 99.3 |
IMPLANT/TiO2/COMPOSITE COATING | ||||||||||
1 h | 169 | 3.22 | 1 | 3.22 | 182 | 9.01 | 0.804 | 1.14 | 29.4 | 66.3 |
1 day | 137 | 3.30 | 1 | 3.30 | 176 | 9.25 | 0.801 | 0.99 | 23.7 | 96.0 |
7 days | 130 | 3.85 | 1 | 3.85 | 205 | 8.33 | 0.826 | 1.26 | 24.0 | 98.2 |
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Petrović, Ž.; Šarić, A.; Despotović, I.; Katić, J.; Peter, R.; Petravić, M.; Ivanda, M.; Petković, M. Surface Functionalisation of Dental Implants with a Composite Coating of Alendronate and Hydrolysed Collagen: DFT and EIS Studies. Materials 2022, 15, 5127. https://doi.org/10.3390/ma15155127
Petrović Ž, Šarić A, Despotović I, Katić J, Peter R, Petravić M, Ivanda M, Petković M. Surface Functionalisation of Dental Implants with a Composite Coating of Alendronate and Hydrolysed Collagen: DFT and EIS Studies. Materials. 2022; 15(15):5127. https://doi.org/10.3390/ma15155127
Chicago/Turabian StylePetrović, Željka, Ankica Šarić, Ines Despotović, Jozefina Katić, Robert Peter, Mladen Petravić, Mile Ivanda, and Marin Petković. 2022. "Surface Functionalisation of Dental Implants with a Composite Coating of Alendronate and Hydrolysed Collagen: DFT and EIS Studies" Materials 15, no. 15: 5127. https://doi.org/10.3390/ma15155127