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Article

Reasons for Reduced Moisture Resistance of Sulfur-Extended Asphalt Concrete

REC “Nanomaterials and Nanotechnology”, Research Center “MGSU Stroy-Test”, National Research Moscow State University of Civil Engineering, 129337 Moscow, Russia
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Materials 2021, 14(23), 7218; https://doi.org/10.3390/ma14237218
Submission received: 1 November 2021 / Revised: 21 November 2021 / Accepted: 23 November 2021 / Published: 26 November 2021

Abstract

The paper presents the results of a study of the mechanism for reducing the moisture resistance of sulfur-extended asphalt concrete. It is shown that a decrease in moisture resistance occurs due to the occurrence of chemical and physical processes. At the same time, it was found that during the manufacture of sulfur-bitumen composites, toxic gases H2S and SO2 are formed, which are capable of interacting with a mineral filler, as well as the interaction of sulfur with a mineral powder with the formation of sulfur-containing water-soluble salts, the extraction of which leads to a decrease in the moisture resistance of sulfur-bitumen materials. The change in the rate of leaching of these substances from the composite is due to the physical process caused by the crystallization of sulfur and the formation of a capillary structure, which significantly increases the rate of leaching of calcium and magnesium salts, which are products of dissolution or hydrolytic decomposition of water-soluble products of the interaction of sulfur, H2S and SO2 gases with calcium and magnesium carbonates. The intensity of chemical and physical processes intensifies with an increase in the amount of sulfur in sulfur-bitumen materials.
Keywords: sulfur-bitumen binder; sulfur-bitumen paste; sulfur-extended asphalt concrete; moisture resistance; technical sulfur; chemical interaction of sulfur with mineral fillers; hydrogen sulfide; sulfur dioxide; sulfur-containing water-soluble calcium; and magnesium salts sulfur-bitumen binder; sulfur-bitumen paste; sulfur-extended asphalt concrete; moisture resistance; technical sulfur; chemical interaction of sulfur with mineral fillers; hydrogen sulfide; sulfur dioxide; sulfur-containing water-soluble calcium; and magnesium salts
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MDPI and ACS Style

Le, H.T.; Korolev, E.V.; Grishina, A.N.; Gladkikh, V.A. Reasons for Reduced Moisture Resistance of Sulfur-Extended Asphalt Concrete. Materials 2021, 14, 7218. https://doi.org/10.3390/ma14237218

AMA Style

Le HT, Korolev EV, Grishina AN, Gladkikh VA. Reasons for Reduced Moisture Resistance of Sulfur-Extended Asphalt Concrete. Materials. 2021; 14(23):7218. https://doi.org/10.3390/ma14237218

Chicago/Turabian Style

Le, Huu Tuan, Evgenij V. Korolev, Anna N. Grishina, and Vitaly A. Gladkikh. 2021. "Reasons for Reduced Moisture Resistance of Sulfur-Extended Asphalt Concrete" Materials 14, no. 23: 7218. https://doi.org/10.3390/ma14237218

APA Style

Le, H. T., Korolev, E. V., Grishina, A. N., & Gladkikh, V. A. (2021). Reasons for Reduced Moisture Resistance of Sulfur-Extended Asphalt Concrete. Materials, 14(23), 7218. https://doi.org/10.3390/ma14237218

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