Wear and Corrosion Resistance of Plasma Electrolytic Oxidation Coatings on 6061 Al Alloy in Electrolytes with Aluminate and Phosphate
Abstract
:1. Introduction
2. Experimental Details
2.1. PEO Process
2.2. Surface Characterization of the Coatings
3. Results and Discussions
3.1. Morphologies of the Coatings
3.2. Cross-Sectional Morphologies and Elemental Distributions of the Coatings
3.3. Phase and Chemical Composition of the Coatings
3.4. Micro-Hardness of the Coatings
3.5. Friction and Wear Properties of the Coatings
3.6. Corrosion Behavior of the PEO Coatings
4. Conclusions
- γ-Al2O3 and α-Al2O3 are the main crystal phases of the PEO coatings, accompanied by a small amount amorphous of phosphorus-rich oxide formed in phosphate electrolyte. With the increase of PEO treating time, the ratios of Iα/Iγ increased and the surface hardness increased.
- The single-layered coatings formed in the aluminate electrolyte exhibit more desirable wear resistance than that in the phosphate electrolyte, which is relatively high α-Al2O3 content.
- The bi-layered coatings formed in the phosphate electrolyte have better excellent acid corrosion resistance, which is attributed to the dense phosphorus-rich oxide of the inner layer.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Coatings | Coefficient of Friction | Width of Wear Track (μm) | Depth of Wear Track (μm) | Wear Rate (mm3/N·m) |
---|---|---|---|---|
P30 | 0.78 ± 0.01 | 400 | 29 | 6.46 × 10−4 |
P60 | 0.81 ± 0.01 | 650 | 18 | 1.66 × 10−4 |
Al30 | 0.83 ± 0.02 | 700 | 20 | 1.37 × 10−4 |
Al60 | 0.82 ± 0.01 | 600 | 8 | 8.24 × 10−5 |
Sample | Ecorr (V vs. AgCl) | icorr (A·cm−2) |
---|---|---|
Al alloy | −0.874 | 9.28 × 10−6 |
P30 coating | −0.964 | 1.22 × 10−6 |
Al30 coating | −0.739 | 4.77 × 10−6 |
P60 coating | −0.784 | 1.09 × 10−7 |
Al60 coating | −0.610 | 5.61 × 10−7 |
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Peng, Z.; Xu, H.; Liu, S.; Qi, Y.; Liang, J. Wear and Corrosion Resistance of Plasma Electrolytic Oxidation Coatings on 6061 Al Alloy in Electrolytes with Aluminate and Phosphate. Materials 2021, 14, 4037. https://doi.org/10.3390/ma14144037
Peng Z, Xu H, Liu S, Qi Y, Liang J. Wear and Corrosion Resistance of Plasma Electrolytic Oxidation Coatings on 6061 Al Alloy in Electrolytes with Aluminate and Phosphate. Materials. 2021; 14(14):4037. https://doi.org/10.3390/ma14144037
Chicago/Turabian StylePeng, Zhenjun, Hui Xu, Siqin Liu, Yuming Qi, and Jun Liang. 2021. "Wear and Corrosion Resistance of Plasma Electrolytic Oxidation Coatings on 6061 Al Alloy in Electrolytes with Aluminate and Phosphate" Materials 14, no. 14: 4037. https://doi.org/10.3390/ma14144037