Macromonomers as a Novel Way to Investigate and Tailor Silicon-Oxycarbide-Based Materials Obtained from Polymeric Preceramic Precursors
Abstract
:1. Introduction
2. Materials and Methods
2.1. Synthesis of Macromonomer (T4D2.67)
2.1.1. Materials
2.1.2. Synthesis of 2,4,6,8-Tetrahydroxyl-2,4,6,8-Tetramethylcyclotetrasiloxane (T4OH)
2.1.3. Synthesis of Chlorodimethylsilane Modified 2,4,6,8-Tetrahydroxyl-2,4,6,8-Tetramethylcyclotetrasiloxane (T4M2.67H)
2.2. Synthesis of Preceramic Polymeric Precursors
2.3. Annealing of Silicon Oxycarbide Samples
2.4. T4M2.67H Synthesis Progress and Product Structure Investigation
2.5. Precursors and Silicon Oxycarbide Structure Investigation
3. Results
3.1. T4M2.67H Synthesis and Structure
3.2. Structure of Silicon Oxycarbide Materials and Their Precursors
4. Discussion
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Annealing Step | |||
---|---|---|---|
Sample | I | II | III |
T:D | 25.06% | 15.74% | 4.38% |
T4D2.67 | 9.90% | 13.89% | 4.49% |
3T:2D | 4.06% | 6.90% | 4.09% |
3T4D2.67:T4 | 14.05% | 8.82% | 5.49% |
2T:D | 6.41% | 6.75% | 6.21% |
3T4D2.67:5T4 | 6.07% | 10.85% | 4.89% |
4T:D | 1.92% | 7.03% | 3.69% |
Sample | Carbon Atoms per Silicon Atom in the Material | ||
---|---|---|---|
Theoretical | Experimental | ||
700 °C | 800 °C | ||
T:D | 1.50 | - | 0.64 ± 0.04 |
T4D2.67 | 1.40 | 0.82 ± 0.05 | 0.74 ± 0.21 |
3T:2D | 1.40 | 0.85 ± 0.05 | 0.68 ± 0.02 |
3T4D2.67:T4 | 1.33 | 0.70 ± 0.22 | 0.64 ± 0.03 |
2T:D | 1.33 | 0.86 ± 0.18 | 0.69 ± 0.06 |
3T4D2.67:5T4 | 1.20 | - | 0.69 ± 0.03 |
4T:D | 1.20 | - | 0.94 ± 0.15 |
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Owińska, M.; Matoga, P.; Jeleń, P.; Długoń, E.; Handke, B.; Niemiec, W. Macromonomers as a Novel Way to Investigate and Tailor Silicon-Oxycarbide-Based Materials Obtained from Polymeric Preceramic Precursors. Materials 2021, 14, 3703. https://doi.org/10.3390/ma14133703
Owińska M, Matoga P, Jeleń P, Długoń E, Handke B, Niemiec W. Macromonomers as a Novel Way to Investigate and Tailor Silicon-Oxycarbide-Based Materials Obtained from Polymeric Preceramic Precursors. Materials. 2021; 14(13):3703. https://doi.org/10.3390/ma14133703
Chicago/Turabian StyleOwińska, Maria, Paulina Matoga, Piotr Jeleń, Elżbieta Długoń, Bartosz Handke, and Wiktor Niemiec. 2021. "Macromonomers as a Novel Way to Investigate and Tailor Silicon-Oxycarbide-Based Materials Obtained from Polymeric Preceramic Precursors" Materials 14, no. 13: 3703. https://doi.org/10.3390/ma14133703