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Open AccessArticle

Peptide Controlled Shaping of Biomineralized Tin(II) Oxide into Flower-Like Particles

Institute for Materials Science, University of Stuttgart, Heisenbergstraße 3, 70569 Stuttgart, Germany
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Materials 2019, 12(6), 904; https://doi.org/10.3390/ma12060904
Received: 11 February 2019 / Revised: 5 March 2019 / Accepted: 13 March 2019 / Published: 18 March 2019
The size and morphology of metal oxide particles have a large impact on the physicochemical properties of these materials, e.g., the aspect ratio of particles affects their catalytic activity. Bioinspired synthesis routes give the opportunity to control precisely the structure and aspect ratio of the metal oxide particles by bioorganic molecules, such as peptides. This study focusses on the identification of tin(II) oxide (tin monoxide, SnO) binding peptides, and their effect on the synthesis of crystalline SnO microstructures. The phage display technique was used to identify the 7-mer peptide SnBP01 (LPPWKLK), which shows a high binding affinity towards crystalline SnO. It was found that the derivatives of the SnBP01 peptide, varying in peptide length and thus in their interaction, significantly affect the aspect ratio and the size dimension of mineralized SnO particles, resulting in flower-like morphology. Furthermore, the important role of the N-terminal leucine residue in the peptide for the strong organic–inorganic interaction was revealed by FTIR investigations. This bioinspired approach shows a facile procedure for the detailed investigation of peptide-to-metal oxide interactions, as well as an easy method for the controlled synthesis of tin(II) oxide particles with different morphologies. View Full-Text
Keywords: tin(II) oxide; biomineralization; inorganic-binding peptide; phage display tin(II) oxide; biomineralization; inorganic-binding peptide; phage display
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MDPI and ACS Style

Kilper, S.; Jahnke, T.; Wiegers, K.; Grohe, V.; Burghard, Z.; Bill, J.; Rothenstein, D. Peptide Controlled Shaping of Biomineralized Tin(II) Oxide into Flower-Like Particles. Materials 2019, 12, 904.

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