Preparation and Electrochemical Characterization of Organic–Inorganic Hybrid Poly(Vinylidene Fluoride)-SiO2 Cation-Exchange Membranes by the Sol-Gel Method Using 3-Mercapto-Propyl-Triethoxyl-Silane
Abstract
:1. Introduction
2. Experimental Section
2.1. Materials
2.2. Membrane Preparation
2.3. Characterization
2.3.1. Morphology and Chemical Structure
2.3.2. Ion-Exchange Capacity and Water Uptake Measurements
2.3.3. Membrane Area Resistance
2.3.4. Membrane Potential, Transport Number, and Selective Permittivity
2.3.5. Oxidative Stability
2.3.6. Treatment and Recovery of the Concentrated CoCl2 Wastewater
3. Results and Discussion
3.1. Membrane Preparation
3.2. CEM Morphology
3.3. FTIR Analysis
3.4. Electrochemical Properties of CEMs
3.4.1. Ion Exchange Capacity and Water Uptake
3.4.2. Electrical Resistance
3.4.3. Membrane Potential, Transport Number, and Selective Permittivity
3.5. Oxidative Stability
3.6. Treatment and Recovery of a High Concentration of Cobalt-Containing Wastewater
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Li, Y.; Li, Z.; Li, Y.; Guan, W.; Zheng, Y.; Zhang, X.; Wang, S. Preparation and Electrochemical Characterization of Organic–Inorganic Hybrid Poly(Vinylidene Fluoride)-SiO2 Cation-Exchange Membranes by the Sol-Gel Method Using 3-Mercapto-Propyl-Triethoxyl-Silane. Materials 2019, 12, 3265. https://doi.org/10.3390/ma12193265
Li Y, Li Z, Li Y, Guan W, Zheng Y, Zhang X, Wang S. Preparation and Electrochemical Characterization of Organic–Inorganic Hybrid Poly(Vinylidene Fluoride)-SiO2 Cation-Exchange Membranes by the Sol-Gel Method Using 3-Mercapto-Propyl-Triethoxyl-Silane. Materials. 2019; 12(19):3265. https://doi.org/10.3390/ma12193265
Chicago/Turabian StyleLi, Yanhong, Zhiwei Li, Yanjuan Li, Wenxue Guan, Yangyang Zheng, Xuemin Zhang, and Sanfan Wang. 2019. "Preparation and Electrochemical Characterization of Organic–Inorganic Hybrid Poly(Vinylidene Fluoride)-SiO2 Cation-Exchange Membranes by the Sol-Gel Method Using 3-Mercapto-Propyl-Triethoxyl-Silane" Materials 12, no. 19: 3265. https://doi.org/10.3390/ma12193265