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Materials 2018, 11(12), 2413; https://doi.org/10.3390/ma11122413

Development and Characterization of Mechanically Durable Silicone-Polythiourethane Composites Modified with Tetrapodal Shaped ZnO Particles for the Potential Application as Fouling-Release Coating in the Marine Sector

1
Functional Nanomaterials, Institute for Materials Science, Faculty of Engineering, Kiel University, Kaiserstr. 2, D-24143 Kiel, Germany
2
Phi-Stone AG, Kaiserstr. 2, D-24143 Kiel, Germany
3
Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Str. 1, 21502 Geesthacht, Germany
*
Author to whom correspondence should be addressed.
Received: 31 October 2018 / Revised: 22 November 2018 / Accepted: 25 November 2018 / Published: 29 November 2018
(This article belongs to the Special Issue Synthesis Characterization and Applications of Block Copolymers)
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Abstract

Ecological considerations strongly necessitate the development of environmentally friendly antifouling paints. A promising alternative to biocide containing antifouling paints are fouling-release coatings, which are non-toxic and designed to prevent permanent attachment of marine organisms to the surface, due to their low surface energy. However, these coatings suffer from insufficient mechanical properties, which make them unsuitable for mechanically stressed surfaces e.g., on ship hulls. To overcome those obstacles, polydimethylsiloxane (PDMS)-polythiourethane (PTU) composites modified with tetrapodal shaped micro-nano ZnO particles (t-ZnO) were produced and characterized by evaluating the surface energy, mechanical properties, and fouling-release performance. Among all variations, PTU/1 wt.% PDMS composites with 1 wt.% t-ZnO particles possess superior properties for applications as fouling-release coatings for maritime purposes. View Full-Text
Keywords: polymer blend; fouling-release coating; tetrapodal ZnO; PDMS polymer blend; fouling-release coating; tetrapodal ZnO; PDMS
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Qiu, H.; Hölken, I.; Gapeeva, A.; Filiz, V.; Adelung, R.; Baum, M. Development and Characterization of Mechanically Durable Silicone-Polythiourethane Composites Modified with Tetrapodal Shaped ZnO Particles for the Potential Application as Fouling-Release Coating in the Marine Sector. Materials 2018, 11, 2413.

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