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Materials 2018, 11(1), 87;

Shell Layer Thickness-Dependent Photocatalytic Activity of Sputtering Synthesized Hexagonally Structured ZnO-ZnS Composite Nanorods

Institute of Materials Engineering, National Taiwan Ocean University, Keelung 20224, Taiwan
Author to whom correspondence should be addressed.
Received: 13 December 2017 / Revised: 3 January 2018 / Accepted: 5 January 2018 / Published: 7 January 2018
(This article belongs to the Special Issue Application of Photoactive Nanomaterials in Degradation of Pollutants)
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ZnO-ZnS core-shell nanorods are synthesized by combining the hydrothermal method and vacuum sputtering. The core-shell nanorods with variable ZnS shell thickness (7–46 nm) are synthesized by varying ZnS sputtering duration. Structural analyses demonstrated that the as-grown ZnS shell layers are well crystallized with preferring growth direction of ZnS (002). The sputtering-assisted synthesized ZnO-ZnS core-shell nanorods are in a wurtzite structure. Moreover, photoluminance spectral analysis indicated that the introduction of a ZnS shell layer improved the photoexcited electron and hole separation efficiency of the ZnO nanorods. A strong correlation between effective charge separation and the shell thickness aids the photocatalytic behavior of the nanorods and improves their photoresponsive nature. The results of comparative degradation efficiency toward methylene blue showed that the ZnO-ZnS nanorods with the shell thickness of approximately 17 nm have the highest photocatalytic performance than the ZnO-ZnS nanorods with other shell layer thicknesses. The highly reusable catalytic efficiency and superior photocatalytic performance of the ZnO-ZnS nanorods with 17 nm-thick ZnS shell layer supports their potential for environmental applications. View Full-Text
Keywords: sputtering; composite nanorods; shell thickness; photocatalytic activity sputtering; composite nanorods; shell thickness; photocatalytic activity

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Liang, Y.-C.; Lo, Y.-R.; Wang, C.-C.; Xu, N.-C. Shell Layer Thickness-Dependent Photocatalytic Activity of Sputtering Synthesized Hexagonally Structured ZnO-ZnS Composite Nanorods. Materials 2018, 11, 87.

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