An Experimental and a Kinetic Modelling Study of Ethanol/Acetone/Ethyl Acetate Mixtures
Abstract
:1. Introduction
2. Experimental Set-Up
3. Data Processing
4. Results and Discussion
4.1. Flame Topography
4.2. Combustion Characteristics
4.3. Mechanism Reduction
5. Conclusions
- The order of the promoting effect of the concentrations of ET, AC, and EA on the laminar burning velocity is ET > AC > EA.
- With the change of the equivalence ratio, the Markstein number presents a parabolic trend.
- The maximum laminar burning flux appears at the equivalence ratio of 1.0–1.2, and the laminar burning flux of ETEAAC ternary fuel is closer to that of pure fuels on the lean side.
- The experimental and the simulation results of laminar burning velocities have a good consistency, and the relative deviation of ETEAAC 112 is approximately 17.5%.
- The reaction pathways show that H-abstraction reactions are significant for EA consumption; SC2H4OCOC and PC2H4OCOC are important species for EA combustion.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Acknowledgments
Conflicts of Interest
References
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Fuel Group | Ethanol (ET)/Vol. | Acetone (AC)/Vol. | Ethyl Acetate (EA)/Vol. |
---|---|---|---|
ET | 100% | - | - |
AC | - | 100% | - |
EA | - | - | 100% |
ETAC13 | 25% | 75% | - |
ETAC11 | 50% | 50% | - |
ETAC31 | 75% | 25% | - |
ETEA13 | 25% | - | 75% |
ETEA11 | 50% | - | 50% |
ETEA31 | 75% | - | 25% |
ACEA13 | - | 25% | 75% |
ACEA11 | - | 50% | 50% |
ACEA31 | - | 75% | 25% |
ETEAAC211 | 50% | 25% | 25% |
ETEAAC121 | 25% | 25% | 50% |
ETEAAC112 | 25% | 50% | 25% |
ETEAAC221 | 40% | 20% | 40% |
ETEAAC212 | 40% | 40% | 20% |
ETEAAC122 | 20% | 40% | 40% |
ETEAAC111 | 33.33% | 33.33% | 33.34% |
Species | Reaction | Rate of Production (Mole/cm3·s) | Reaction Flux (%) |
---|---|---|---|
EA | EA + H = PC2H4OCOC + H2 | −7.80 × 10−6 | 44.39% |
EA = C2H4 + CH3COOH | −3.12 × 10−6 | 17.77% | |
EA + OH = SC2H4OCOC + H2O | −2.07 × 10−6 | 11.79% | |
EA + H = SC2H4OCOC + H2 | −1.52 × 10−6 | 8.68% | |
EA + OH = PC2H4OCOC + H2O | −9.72 × 10−7 | 5.53% | |
EA + OH = C2H5OCOCH + H2O | −5.60 × 10−7 | 3.19% | |
EA + H = C2H5OCOCH + H2 | −5.28 × 10−7 | 3.00% | |
EA + O = SC2H4OCOC + OH | −4.47 × 10−7 | 2.54% | |
EA + O = C2H5OCOCH + OH | −3.90 × 10−7 | 2.22% | |
EA + O = PC2H4OCOC + OH | −1.54 × 10−7 | 0.88% | |
PC2H4OCOC | PC2H4OCOC = C2H4 + CH3CO2 | −8.92 × 10−6 | 99.95% |
PC2H4OCOC => C2H5OCOCH | −2.35 × 10−9 | 0.03% | |
H + VINACET = PC2H4OCOC | −1.62 × 10−9 | 0.02% | |
SC2H4OCOC | SC2H4OCOC = CH3CHO + CH3CO | −3.81 × 10−6 | 93.95% |
SC2H4OCOC => C2H5OCOCH | −1.65 × 10−7 | 4.07% | |
H + VINACET = SC2H4OCOC | −3.75 × 10−8 | 0.93% | |
SC2H4OCOC + O2 <=> VINCET + HO2 | −3.42 × 10−8 | 0.84% | |
SC2H4OCOC + H = EA | −8.78 × 10−9 | 0.22% |
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Liu, Y.; Liu, W.; Liao, H.; Ashan, H.; Zhou, W.; Xu, C. An Experimental and a Kinetic Modelling Study of Ethanol/Acetone/Ethyl Acetate Mixtures. Energies 2022, 15, 2992. https://doi.org/10.3390/en15092992
Liu Y, Liu W, Liao H, Ashan H, Zhou W, Xu C. An Experimental and a Kinetic Modelling Study of Ethanol/Acetone/Ethyl Acetate Mixtures. Energies. 2022; 15(9):2992. https://doi.org/10.3390/en15092992
Chicago/Turabian StyleLiu, Yangxun, Weinan Liu, Huihong Liao, Hasier Ashan, Wenhua Zhou, and Cangsu Xu. 2022. "An Experimental and a Kinetic Modelling Study of Ethanol/Acetone/Ethyl Acetate Mixtures" Energies 15, no. 9: 2992. https://doi.org/10.3390/en15092992