Research on the Modification of Coal Adaptability and Carbon Emissions Reduction Technology for Coal-Fired Boilers
Abstract
:1. Introduction
2. Overview of the Equipment Configuration before Modification
3. Modification Plan
3.1. Coal Analysis
3.2. Specific Modification Plan
- (1)
- Pulverizing system
- (2)
- Low-NOx burner modification
- (3)
- Economizer modification
- (4)
- Low-temperature economizer
4. Experimental Research Methods
4.1. Test Conditions
4.2. Corresponding Coal Analysis
4.3. Test Method
5. Analysis and Discussion
5.1. Comparative Analysis of Burnout Rate and Exhaust Temperature before and after Modification
5.2. Comparative Analysis of Boiler Efficiency before and after Renovation
5.3. Comparative Analysis of NOx Emissions before and after Modification
- (1)
- After the modification, the higher the volatile content of bituminous coal (Vdaf > 25%), the more intermediate products NH3 and HCN are generated in the initial combustion reaction in the oxygen-deficient atmosphere of the main combustion zone with a small excess air coefficient. The NOx produced can be inhibited and reduced by these intermediate reducing products [16,17,18].
- (2)
- Thermal NOx originates from the oxidation of N2 in the air to NO during the combustion process, which occurs mainly in the high-temperature region above 1500 °C. The flame temperature and NOx generation increased exponentially, and the thermal NOx produced increased with the increase in temperature. After the lean coal is replaced by bituminous coal, the temperature of the flame center in the main combustion zone of the boiler is generally lower than 1500 °C, and the thermal NOx generation is almost negligible [19,20].
- (3)
- Air distribution can effectively control the formation of NOx. The formation of NOx in boiler exhaust flue gas is related to the residence time of coal particles in the reducing atmosphere of the boiler and the depth of air distribution. However, with the deepening of air distribution the combustion of the pulverized coal is also weakened, and the level of burnout is also reduced, so the air distribution cannot be deepened infinitely [21]. Bituminous coal has better burnout performance than lean coal, so the air distribution depth is high [22]. It can also be seen from Table 6 that, because bituminous coal is highly combustible, the CO concentration at the outlet of the cryogenic economizer does not change significantly with the reduction of excess air after the adoption of staged combustion technology; however, the concentration of NOx decreased significantly. This can reduce the concentration of NOx and maintain high combustion efficiency.
5.4. Analysis of the Influence of Low-Temperature Economizer on Coal Consumption
5.5. Comparative Analysis of Coal Consumption before and after Modification
- (1)
- After the change of lean coal into high-volatile bituminous coal, the mechanical incomplete combustion loss of the boiler was greatly reduced, and the average value of q4 for those two working conditions was only 0.747%; through the type modification of coal and economizers, the flue gas temperature of the boiler was reduced by 5.3 °C while the boiler efficiency increased by 2.35%, and the coal consumption decreased by 8.51 g/(kW·h).
- (2)
- After the low-temperature economizer was put into operation, the heat consumption rate was reduced by 34.82 kJ/(kW·h). However, the rise in resistance in the condensate increased the power consumption of the condensate pump of the steam turbine, resulting in an increase of 0.02% in the auxiliary power rate of the plant, and after deducting the extra power consumption of the condensate pump from the power gain of the unit brought about by the installation of the low-temperature economizer, the coal consumption rate was finally reduced by 1.32 g/(kW·h).
5.6. Analysis of Coal Conservation and Carbon Emission Reduction after Modification
- (1)
- Coal conservation after renovation.
- (2)
- Carbon emissions reduction after modification.
6. Conclusions
- (1)
- After the boiler was modified with bituminous coal and the installation of two, low-temperature economizers, the average boiler efficiency after the correction was 92.71%, 2.35% higher than the 90.36% before the modification (burning lean coal, after the correction). Under the coal quality and 250 MW load conditions, the measured thermal efficiency of the boiler was 92.55%, and the corrected thermal efficiency of the boiler was 92.51%. This is 2.58% higher than that loaded with 265 MW before the renovation (89.93%).
- (2)
- The average NOx content in the flue gas at the economizer outlet (denitrification inlet) was 279.4 mg/Nm3, when the two low-temperatures economizer were put into operation, which is about 68% lower than that of 864 mg/Nm3 before the modification.
- (3)
- After the boiler renovation, the average coal consumption for power supply after correction was 322.87 g/(kW·h), 9.83 g/(kW·h) lower than before the renovation. The modification of the pulverizing system and the major components of boiler reduced the coal consumption by 8.51 g/kW·h, and the addition of low-temperature economizers reduced the coal consumption rate by 1.32 g/(kW·h). The energy consumption reduction of the power generation unit brought about an annual energy savings of 16,776 tons of standard coal and a total carbon dioxide emissions reduction of 41,213.60 tons.
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Item | Elemental Analysis (%) | Proximate Analysis (%) | Net Calorific Value (MJ·kg−1) | |||||||
---|---|---|---|---|---|---|---|---|---|---|
Car | Har | Oar | Nar | Sar | Var | Mar | Aar | FCar | Qnet,ar | |
Original design coal | 57.20 | 2.25 | 3.11 | 1.17 | 0.34 | 14.27 | 8.08 | 27.85 | 49.80 | 20.91 |
Original check coal | 63.36 | 2.55 | 3.68 | 0.94 | 0.44 | 11.87 | 6.33 | 22.70 | 59.10 | 23.41 |
New Design Coal | 58.40 | 3.38 | 8.20 | 0.83 | 2.10 | 25.74 | 14.20 | 12.89 | 47.17 | 22.63 |
New check coal | 54.02 | 3.08 | 5.76 | 0.94 | 1.30 | 17.77 | 11.10 | 23.81 | 47.32 | 20.72 |
Item | A | B | C | D |
---|---|---|---|---|
Burner number after retrofit | A-1, A-2, A-3, A-4 | B-1, B-2, B-3, B-4, D-1, D-3 | C-1, C-2, C-3, C-4, D-2, D-4 | E-1, E-2, E-3, E-4 |
Item | Working Condition A-01 | Working Condition A-02 | Working Condition A-03 | Working Condition B-04 | Working Condition B-05 | Working Condition B-06 | Working Condition B-07 |
---|---|---|---|---|---|---|---|
Load/MW | 319.40 | 318.80 | 265.30 | 307.70 | 308.40 | 305.70 | 249.60 |
Mill in operation/set | 3 | 2 | 4 | 4 | 3 | 3 | |
exhauster in operation/set | ABD | ABCD | ABD | ABC | ABC | ABC | ABC |
Low temperature economizer in operation or not | NO | NO | NO | In operation | In operation | NO | NO |
Working Condition | Elemental Analysis (%) | Proximate Analysis (%) | Net Calorific Value (MJ·Kg −1) | |||||||
---|---|---|---|---|---|---|---|---|---|---|
Car | Har | Oar | Nar | Sar | Var | Mar | Aar | FCar | Qnet, Our | |
A-01 | 53.17 | 2.34 | 3.44 | 0.89 | 1.08 | 11.01 | 7.94 | 31.14 | 49.91 | 22.11 |
A-02 | 52.89 | 2.44 | 3.09 | 0.91 | 1.06 | 11.21 | 7.53 | 32.09 | 49.17 | 22.12 |
A-03 | 51.69 | 2.37 | 4.66 | 0.92 | 0.90 | 12.05 | 6.48 | 32.98 | 48.49 | 17.31 |
B-04 | 53.97 | 3.52 | 3.52 | 0.93 | 0.81 | 26.76 | 9.70 | 22.02 | 41.53 | 20.74 |
B-05 | 53.90 | 3.46 | 3.46 | 0.92 | 0.81 | 26.40 | 10.50 | 21.59 | 41.51 | 20.56 |
B-06 | 53.96 | 3.55 | 3.55 | 0.93 | 0.85 | 26.59 | 9.30 | 22.25 | 41.86 | 20.72 |
B-07 | 54.97 | 3.48 | 8.44 | 0.95 | 0.85 | 26.04 | 9.00 | 22.28 | 42.69 | 20.83 |
Serial Number | Name | Working Condition A-01 | Working Condition A-02 | Working Condition A-03 | Working Condition B-04 | Working Condition B-05 | Working Condition B-06 | Working Condition B-07 |
---|---|---|---|---|---|---|---|---|
1 | Unit load (MW) | 319.40 | 318.80 | 265.30 | 307.70 | 308.40 | 305.70 | 249.60 |
2 | Main steam flow (t·h−1) | 1055.00 | 1049.00 | 842.00 | 1000.60 | 999.70 | 1000.30 | 786.20 |
3 | Ambient temperature (°C) | 35.97 | 37.00 | 37.20 | 28.90 | 29.30 | 26.90 | 26.40 |
4 | Ambient relative humidity (%) | 43.30 | 44.00 | 41.40 | 63.40 | 61.40 | 68.10 | 68.20 |
5 | Atmospheric pressure (kPa) | 99.72 | 99.72 | 99.99 | 100.76 | 100.80 | 100.80 | 100.80 |
6 | Flue gas oxygen (%) | 5.67 | 5.52 | 6.66 | 4.68 | 4.76 | 5.33 | 5.45 |
7 | Flue gas temperature (°C) | 154.69 | 156.35 | 156.35 | 144.40 | 146.20 | 143.90 | 142.70 |
8 | Ash combustibles (%) | 4.70 | 4.76 | 2.93 | 1.96 | 2.12 | 1.96 | 1.61 |
9 | Slag combustibles (%) | 4.68 | 6.46 | 2.64 | 2.34 | 2.03 | 2.12 | 1.73 |
10 | Heat loss due to exhaust gases q2 (%) | 6.10 | 6.08 | 6.67 | 5.80 | 5.94 | 6.07 | 6.14 |
11 | Chemical incomplete combustion loss q3 (%) | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
12 | Mechanical incomplete combustion loss q4 (%) | 2.59 | 2.80 | 2.28 | 0.76 | 0.73 | 0.60 | 0.73 |
13 | Leakage heat loss q5 (%) | 0.41 | 0.41 | 0.51 | 0.43 | 0.43 | 0.55 | 0.43 |
14 | Ash residue heat loss q6 (%) | 0.26 | 0.27 | 0.38 | 0.17 | 0.18 | 0.17 | 0.17 |
15 | Total heat loss (%) | 9.36 | 9.56 | 9.83 | 7.30 | 7.40 | 7.45 | 7.14 |
16 | Boiler thermal efficiency (%) | 90.64 | 90.44 | 90.17 | 92.86 | 92.70 | 92.60 | 92.55 |
17 | Corrected flue gas temperature (°C) | 144.20 | 145.26 | 145.27 | 138.62 | 140.17 | 139.41 | 138.53 |
18 | Corrected boiler efficiency (%) | 90.46 | 90.25 | 89.93 | 92.79 | 92.62 | 92.55 | 92.51 |
Serial Number | Name | Working Condition A-01 | Working Condition A-02 | Working Condition A-03 | Working Condition B-04 | Working Condition B-05 | Working Condition B-06 | Working Condition B-07 |
---|---|---|---|---|---|---|---|---|
1 | Oxygen (%) | 3.95 | 4.00 | 5.05 | 3.03 | 2.60 | 2.43 | 3.49 |
2 | CO concentration (ppm) | 16.50 | 13.75 | 5.40 | 6.35 | 6.50 | 8.60 | 5.45 |
3 | NOx concentration (ppm) | 458.00 | 453.50 | 426.50 | 152.85 | 160.95 | 168.20 | 139.50 |
4 | NOx concentration after conversion (mg·(Nm3)−1) (Dry basis, standard state, 6% oxygen) | 866.50 | 862.00 | 865.00 | 275.30 | 283.45 | 293.05 | 257.80 |
Name | Before Modification (After Fixing) | After Modification (After Fixing) | After Modification Minus Before Modification |
---|---|---|---|
Boiler efficiency at rated condition (%) | 90.36 | 92.71 | 2.35 |
Heat consumption rate of turbine under rated conditions (kJ·(kW·h) −1) | 8159.40 | 8124.58 | –34.82 |
The auxiliary power rate of plant under rated conditions (%) | 5.978 | 5.973 | –0.005 |
Pipeline efficiency in rated condition (%) | 98.5 | 98.5 | 0 |
Coal consumption for power supply under rated, pure condensing condition (g·(kW·h)−1) | 332.70 | 322.87 | –9.83 |
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Peng, D.; Wang, B.; Cai, X.; Bei, L. Research on the Modification of Coal Adaptability and Carbon Emissions Reduction Technology for Coal-Fired Boilers. Energies 2022, 15, 9533. https://doi.org/10.3390/en15249533
Peng D, Wang B, Cai X, Bei L. Research on the Modification of Coal Adaptability and Carbon Emissions Reduction Technology for Coal-Fired Boilers. Energies. 2022; 15(24):9533. https://doi.org/10.3390/en15249533
Chicago/Turabian StylePeng, Dan, Ben Wang, Xingfei Cai, and Lei Bei. 2022. "Research on the Modification of Coal Adaptability and Carbon Emissions Reduction Technology for Coal-Fired Boilers" Energies 15, no. 24: 9533. https://doi.org/10.3390/en15249533
APA StylePeng, D., Wang, B., Cai, X., & Bei, L. (2022). Research on the Modification of Coal Adaptability and Carbon Emissions Reduction Technology for Coal-Fired Boilers. Energies, 15(24), 9533. https://doi.org/10.3390/en15249533