1. Introduction
The impact of transportation on climate change has caused both global and national incentives to increase the amount of renewable fuels used in internal combustion engines (ICEs) [
1,
2,
3,
4,
5,
6,
7]. Liquid biofuels show advantages compared to gaseous alternatives as they exhibit higher energy density and are compatible with current infrastructure [
7,
8,
9]. For utilisation in direct-injected spark-ignited (DISI) engines, oxygenated biofuels (such as alcohols and ethers) are promising as they exhibit similar combustion behaviour to gasoline. Therefore, these fuels require less adaptation for utilisation in existing spark-ignited (SI) engines [
7,
9,
10]. Moreover, the oxygenated biofuels can be blended with gasoline, both at low and high ratios, facilitating the transition from fossil fuels to renewable fuels as production increases [
11].
In a previously conducted literature review, it was established that the use of light alcohols, such as ethanol and methanol, in SI engines is well-established and has been investigated for a long time [
12]. Light alcohols offers advantages compared to more complex molecules as they can be derived from a variety of process pathways and feedstocks [
13,
14]. Longer alcohols, such as n-butanol and iso-butanol, have gained interest as a fuel alternative in recent years [
12]. Butanols offer similar benefits like the lighter alcohols, but provide higher energy density [
15]. Other oxygenated biofuel alternatives are ethers, for example methyl tert-butyl ether (MTBE). MTBE has been used in gasoline as an octane enhancer [
16,
17] and is produced from methanol and iso-butylene [
13]. It is an interesting fuel since its octane ratings are high without a big difference in energy density compared to gasoline. However, MTBE has been restricted in many countries due to its high resistance to biodegradation which affects groundwater aquifers [
18]. The above mentioned fuels have been thoroughly investigated for port fuel injected (PFI) SI engines. However, their effect on combustion and emissions in DISI engines is less known. DISI engines have enabled increased engine efficiencies, but they also introduce challenges associated with homogeneous fuel and air mixture preparation, which could lead to increased emission rates of particles [
19].
There are several benefits to the utilisation of biofuels in DISI engines, aside from decreased impact on the climate. The main benefit is the increased knock resistance of oxygenated biofuels in comparison with commercial gasoline [
3,
20,
21]. Knock is a major constraint that limits compression ratio (CR), and therefore the efficiency of DISI engines. Biofuels will permit further downsizing and increase in engine efficiency. Most of the oxygenated biofuels exhibit higher octane numbers (RON and MON) compared to gasoline [
3,
10]. Researchers also report that light alcohols exhibit increased heat of vaporisation (HOV) [
9,
22,
23,
24,
25] and laminar flame speed (SL) [
3,
26,
27], properties known to benefit knock resistance in engines. Furthermore, gasoline exhibits a negative temperature coefficient (NTC) region, while light alcohols do not [
24,
28]. The occurrence of an NTC-region facilitates auto-ignition, hence gasoline is more prone to knock compared to alcohols, especially at boosted operation.
Several researchers conclude that biofuels can lead to increased engine efficiency [
5,
9,
11,
23,
29], increased combustion stability [
2,
6,
30,
31], and lower exhaust temperatures [
23,
32,
33] in SI engines. Moreover, due to the increased knock resistance, higher boost pressures can be used to increase peak load of the engine if the engine is optimised for biofuel combustion. Brewster achieved a 13% higher load with ethanol compared to gasoline [
34]. Nakata et al. achieved an 11% higher load with ethanol compared to gasoline when the valve timing was optimised [
35]. Moreover, several researchers report brake thermal efficiency for ethanol and methanol of 36 to 40% compared to 27 to 36% for gasoline [
15,
34]. Methanol and ethanol have also shown potential as fuels for heavy-duty (HD) SI application, where similar load and efficiency as HD diesel combustion could be reached with lean combustion of methanol and ethanol [
36]. Sileghem et al. showed increased efficiency in comparison to gasoline in a DISI engine fuelled with iso-butanol [
15]. The efficiency (brake thermal efficiency) was at the same level as ethanol except for at the highest investigated load (150 Nm). Szwaja and Naber showed that pure n-butanol increased burn rates and indicated efficiency in a single-cylinder CFR engine compared to gasoline [
37]. Topgül showed that low level blends of MTBE in gasoline (10% to 30 %) increased brake thermal efficiency, where the highest efficiency was seen for 10% MTBE [
38].
It has also been shown that biofuels may lead to decreased emissions from SI engines, such as carbon monoxide (CO) and hydrocarbons (HC) [
5,
32,
39,
40]. Masum et al. showed that CO and HC emissions decreased noticeably even at low levels of ethanol and methanol (20%) in the fuel, while a slight decrease was seen for 20% iso-butanol [
32]. Sileghem et al. showed that iso-butanol decreased CO, HC and nitrogen oxides (NOx) emissions compared to gasoline in a DISI engine [
15]. However, emissions for iso-butanol were higher than for methanol and ethanol. Sandhu et al. showed decreased levels of CO and HC emissions for n-butanol compared to gasoline both at lean and exhaust gas recirculation (EGR) diluted combustion [
41]. Schifter et al. concluded that HC and NOx emissions decreased as the volume of MTBE in the fuel increased [
33].
Several researchers report the possibility of oxygenated fuels to decrease both particle mass (PM) emissions and particle number (PN) emissions in DISI engines [
42,
43,
44]. The high levels of embedded oxygen in oxygenated biofuels, compared to gasoline, leads to a dilution effect at the flame front. The dilution effect decreases soot formation and increases oxidation rates [
45,
46,
47]. However, oxygenated fuels also exhibit properties that could lead to increased levels of particle emissions, such as decreased volatility, increased HOV and increased viscosity [
48]. Thus, early injection could cause increased rates of fuel impingement and pool fires and increase particle emissions compared to gasoline instead [
49,
50].
Previously conducted research shows great potential for biofuels in future optimised engines. However, the impact of introducing biofuels into already existing gasoline optimised engines needs to be established to facilitate the transition from fossil to renewable fuels. Moreover, the effect of different renewable fuels on engine performance and emissions in different operating points (not only during knock-limited conditions) should be further evaluated to establish their potential as future fuels. Many biofuel alternatives have been tested only as blends with gasoline and not as pure components, and only compared to methanol and/or ethanol. As MTBE has been used mainly as an octane enhancer in gasoline, research evaluating MTBE has focused mainly on blended fuel. Research on MTBE has also decreased, hence few studies on MTBE in DISI engines exist. Furthermore, few studies focus on comparing closely related biofuels, such as iso-butanol and n-butanol, as pure components in production SI engines.
In this article, the engine performance of five pure, liquid, oxygenated biofuels have been evaluated and compared to gasoline through engine experiments. The investigated biofuels are four alcohols (methanol, ethanol, n-butanol and iso-butanol) and one ether (MTBE). The effect of these fuels on engine efficiency, combustion propagation and emissions in a gasoline-optimised DISI engine was investigated under a wide range of engine operating conditions.
4. Discussion
The oxygenated biofuels increased both ITE and combustion efficiency compared to gasoline, even though no optimisation has been applied to the engine control, nor the engine hardware. The efficiency increased also if the engine was running at lower loads, where gasoline was not knock-limited. The highest efficiencies were seen for methanol. Furthermore, methanol exhibited a shorter burn duration and increased ROHR compared to the other fuels. Increased efficiencies for methanol was also reported by Sileghem et al. [
9]. They did a study of methanol and methanol–water blends in a production SI engine and compared it to gasoline for a high number of operating conditions and compared the performance to gasoline. However, those tests were performed in a port fuel injected engine. Cairns et al. reported increased efficiencies for butanol and ethanol blends in a DISI engine where fuel injection was optimised for the blends [
29]. Moreover, the same fuels (gasoline, methanol and ethanol) as used in this study showed great potential as fuel alternatives also in HD SI application [
36]. The results in that study were run at a higher compression ratio (13) and thus, more optimised for ethanol and methanol than for gasoline. A future study could investigate if efficiency could be increased even further with increased compression ratios in the light-duty DISI engine used in this study. For MTBE, only results on lower level blends have been reported [
38], but it also showed an increased engine efficiency compared to gasoline. Hence, the results in this study add combined information of the performance of different biofuels performed on the same DISI engine at different operating conditions, and in a production engine optimised for gasoline utilisation.
N-butanol was the only oxygenated fuel that was knock-limited. However, a more advanced combustion phasing than that of gasoline could be applied. The RON of n-butanol was slightly higher than for gasoline, but it also has other properties that benefit knock resistance. Increased charge cooling due to higher HOV was shown to mitigate pre-ignition and auto-ignition by Pischinger et al. [
24]. Moreover, the shorter combustion duration that was seen for n-butanol, compared to gasoline, also decreases the probability of knock.
As no hardware changes were made to the engine, the same injectors were used for all fuels. Hence, the ECU had to alter injection pressures and injection duration to reach the desired load points. This resulted in a significant increase in injection pressure for methanol compared to the other fuels. The increased injection pressure may increase spray atomization and might improve the in-cylinder turbulence of a spray-guided engine, such as this one. This could affect not only burn rates but also CO, HC and particle formation.
The COV for all fuels were similar to the baseline gasoline and well within the recommended limits for an SI engine. There was no clear trend in COV depending on the properties of the fuels. Daniel et al. [
62] noted that combustion instability is reduced due to the increased burn rate of the oxygenated fuels. For low load conditions, ethanol and methanol showed decreased COV compared to the other fuels. However, since the fuel injection in this production engine was calibrated for gasoline, the end of injection varied more when the engine was run with the oxygenated fuels compared to gasoline. This could have had an impact on the COV. Thus, it is possible that with proper fuel injection calibration, the oxygenated fuels would show even lower levels of COV compared to gasoline, corresponding to the shorter CA010. As a result, these fuels could have a higher tolerance for lean or EGR diluted combustion.
The exhaust temperature was lower for the alcohols and showed a good correlation with the increased HOV of the fuels, as supported by previous research [
23,
32,
33]. The charge cooling of the alcohols is beneficial as it lowers in-cylinder temperature and thus heat losses, as could be seen in the performed energy balance. Moreover, if the exhaust gas temperature is lower, it decreases the need for fuel enrichment to protect hardware located in the exhaust stream (turbine and TWC). With this condition, it is possible that the fuels with increased HOV will exhibit an even higher difference in ITE compared to gasoline. Previous studies support the decrease of CO and HC emissions in DISI engines, as the oxygen content of the fuel increases [
5,
32,
39,
40]. Sileghem et al. also showed decreased levels of NOx emissions compared to gasoline [
15]. In this study, it was shown that the level of emissions depends on the operating conditions, the injection strategy, and the fuel properties. The volatility of the fuel seems to have a higher impact on the engine emissions than the oxygen content, as in this engine, it increases fuel impingement. The effect of injection timing on CO, HC, and NOx emissions could be investigated in a future study.
The low volatility of some of the oxygenated fuels showed a major impact on the particle emissions. Increased levels of PN and PM could be handled by after-treatment systems, such as gasoline particle filters (GPF), or by optimising the fuel injection of the engine. However, researchers have reported increased levels of smaller particles for oxygenated fuels (down to 10 nm) [
73], which are harder to trap using a GPF. A more detailed analysis of the particle emissions, including sub-23 nm particles, would give a deeper understanding of the particle emissions from the oxygenated fuels.