1. Introduction
World total energy supply, excluding international aviation and marine bunkers, increased by 60% in 2015 compared to 1990, with oil and coal as dominant fuels. This growth was driven by Asia, whereas European share of energy supply fell from 37% to 19%, and that of the United States dropped from 23% to 16%, in the same period [
1]. The housing sector is one of the highest energy consumers around the world, with a final energy consumption of around 23% in 2015 [
2]. Buildings and industries each use half of the electrical energy consumed globally, with respective global CO
2 emissions of 8.4% and 23.8% in 2017 [
3].
Energy consumption in the residential sector and the resulting CO
2 emissions differ from one country to another as a consequence of geographic, social, political and economic factors. The recent evolution of final energy consumption in several countries [
2] demonstrates the need to improve energy efficiency in buildings and using renewable resources, as consumption is growing even in technologically developed countries with favourable climatic conditions, such as Italy and Spain (
Figure 1).
The refrigeration and air conditioning demand using conventional energy can be reduced by using renewable resources and waste heat recovery. Many authors have worked on thermodynamic cycles driven by solar energy. Systems based on absorption cycles are common solutions due to their current development. Under normal operation conditions, single effect absorption machines achieve typical COP values of 0.7 for driving heat temperatures of 80−100 °C, whereas adsorption cycles may have slightly lower efficiencies at low temperatures [
4]. Diffusion-absorption technology is also seen as a viable proposition for small solar refrigerators, which typically need higher activation temperatures and achieve lower COP values [
5]. More efficient conventional technologies exist, but solar systems can be advantageous if comparisons are based on sustainability indicators, such as the ratio of cooling or heating produced to electricity consumed.
For air conditioning applications, most absorption machines use the couple water and lithium bromide (H
2O/LiBr), where water is the refrigerant, but few systems are available in the low cooling capacity range. Recent statistics indicate that the largest number of small-scale solar cooling installations have been commercialized in Spain, most of them based on absorption machines supplied by ClimateWell [
6].
Absorption cooling systems work well in dry and hot climatic conditions where large daily variations in relative humidity and dry bulb temperature prevail, as is the case in Madrid [
7]. Good results have also been obtained in coastal regions of Greece, where the solar potential is satisfactory and at the same time temperatures are not extremely high [
8,
9]. With typical values of input parameters encountered in hot regions, optimal COP values of 0.80 can be achieved at hot source temperatures between 75 and 80 °C [
10]. Systems based on absorption cycles have been investigated in Arabian Gulf countries in order to provide environmental benefits, as per capita CO
2 emissions double the figures of the United States in some areas [
11]. The technology also exhibits a good performance under tropical Asia climates because the solar energy can be utilised almost throughout the entire year [
12], particularly to buildings with high cooling loads and limited available areas for solar collectors [
13]. For buildings in the subtropical region, comparative studies predict the greatest application potential for solar absorption cooling and solar-electric compression cooling [
14].
The variability of climatic conditions adds difficulty to the standardization [
15], so hybrid configurations should be analysed for each project. In general, greater cooling capacity requires a larger surface area of solar collectors [
16], and solar multi-effect chillers are not an efficient option in regions with global horizontal irradiation below 1000 kWh/(m
2·year) [
17], where the heating demand is dominant. Simultaneous heating and cooling with energy storage may be the best economical option for solar heating/cooling plants taking into consideration economic criteria [
18]. In addition, the use of biomass may be adequate for certain climatic conditions.
The lack of demonstration plants is often considered as a technological barrier that must be overcome in order to improve the performance of the installations and to transmit experiences to the economic operators [
6]. Considering this circumstance, five “Office Buildings Prototypes for Research and Demonstration” were constructed within the Singular Strategic Project ARFRISOL, in order to promote a “change in mentality” regarding the use and consumption of energy and towards the construction of more environmentally respectful buildings [
19]. For the very different climatic conditions of each building, bioclimatic strategies and technologies based on renewable sources were studied, including solar cooling. The results of the research show energy demand savings in the order of 95% in the buildings of CIESOL-Almería, CIEMAT-Madrid and Plataforma Solar de Almería (PSA), whereas 100% savings have been achieved in the buildings of CEDER-Soria and Fundación Barredo-Asturias. The contribution of passive solar systems has been approximately 60% in PSA and Asturias, and at least 40% in the remaining buildings. In Soria and Asturias, where the demand for heating is predominant, active solar systems were assisted with biomass boilers.
As a complement to the project, the Gijón Solar Cooling Laboratory (GSCL) described below was installed at the University of Oviedo. The GSCL was conceived as a modular plant that allows the testing of diverse equipment and technologies, in the typical climatic environment of the Cantabrian coast.
An innovation common to ARFRISOL buildings is that an alternative solar cooling system has been proposed, based on absorption units that store energy in salts. Results obtained with this solution in the arid climate of the PSA building have already been published [
20,
21]. From a typical meteorological year and accepting manufacturer’s operating data, simulations were made using TRNSYS, in order to analyse the solar fraction of demand covered by the system based on the collector surface, for the particular surface of the building and for various combinations of installed absorption units. It was observed that this type of machines may have advantages for smaller scale refrigeration capacity systems. These units could also serve as support for conventional systems with higher refrigeration capacity [
20]. Analogous simulations were performed in the same facility to analyse the solar fraction and the primary energy ratio, using as parameters the surface of the collector field, the efficiency curve of each type of collector, and the capacity of the external storage tank [
21]. In both works, the results were compared with a conventional absorption system with external storage. Potential advantages of the system were observed, but no information was obtained about the charging and discharging processes in the internal storage tanks.
This article deals with the tests carried out with a unit of the same type installed in the GSCL, with particular attention to the charging and discharging processes. The duration of such processes is an important characteristic that influences the design of the system, along with other variables that have not been the subject of this study because they are external to the cooling unit, such as climatic conditions, thermal loads and the thermal inertia of the building.
2. Materials and Methods
2.1. Description of the GSCL
The GSCL was designed and implemented aiming to test different configurations, strategies and technologies for solar cooling production in buildings. The laboratory is located in the facilities that the University of Oviedo has in Gijón, a coastal city in the north of Spain. The laboratory consists of various circuits, which connect a cooling machine, a heat source, a heat sink and a cooling device.
Figure 2 shows the conceptual scheme of the GSCL with the possible options of configuration.
The cooling machine tested in this work is a ClimateWell-CW10 absorption machine (
Figure 3), which main characteristics are listed in
Table 1. The CW10 machine is not a typical absorption chiller as it has two different barrels containing lithium chloride and water, making possible the internal storage of energy in one barrel while the other is discharging.
The main feature operation of the machine is that each barrel can be charged or discharged independently, providing two operation modes. With the machine working in the standard mode, one barrel is charged while the other is discharged at the same time, enabling continuous cooling. The double mode makes it possible to charge or discharge both barrels at the same time, achieving higher thermal power, but once the barrels are discharged, a charge period of time is required, so continuous cooling supply is not possible in this operation mode.
Each barrel has two separate bowls, the one is filled with salts (reactor) and the other is filled with water (evaporator). When a barrel is charged, the lithium chloride is dried and crystallized using the heat received from the heat supply circuit while the water returns to the evaporator and the heat excess is rejected to the dissipation circuit. In this process chemical energy is stored in the salt crystals. In the discharging process, the bowl containing the salts absorbs water from the evaporator with the corresponding cooling supply and heat rejection.
The heat supply circuit allows different heat sources to be used: solar collectors, electrical boiler and a biomass boiler (
Figure 4). Technical details of each heat source are listed in
Table 2.
The dissipation circuit can be configured for the use of different heat sinks (
Figure 5): air heat exchanger, evaporative cooling tower, water reservoir and ground heat exchangers with also different configurations. The main specifications of the dissipation systems are listed in
Table 3.
Regarding the chilled water circuit, it can be configured in two ways, as can be seen in
Figure 6: fan-coils or water tanks with the characteristics of
Table 4.
The installation is monitored with more than 200 PT100 temperature probes, 17 Kobold inductive flowmeters and one CMP-11 Kipp and Zonen pyranometer. The data acquisition is carried out with National Instruments Field Point technology. For control purposes, Grundfos variable speed pumps were installed in the circuits.
In summary, the GSCL has possibilities that probably are not frequent in similar installations, being possible to replace the type of cooling machine and carry out tests with different heat sources, dissipation systems and cooling equipment.
2.2. Test Setup
Experimental tests have been made varying the operating conditions of the absorption chiller, working in the refrigeration mode. All experiments have been performed with the machine operating in the double mode, charging or discharging both barrels at the same time.
For the charging process, the electric boiler has been used as thermal power supply in order to guarantee the heat supply with independence on the local weather conditions, and the water reservoir has been used as dissipation system. Several cycles have been measured varying the driving heat temperature at the inlet of the machine between 70 °C and 90 °C, maintaining the cooling water around 20 °C. The flow rate through the thermal power supply circuit has been fixed at 16 L/min. The flow rate trough the dissipation circuit varied between 10 L/min and 14 L/min due to the normal operation of the absorption chiller (openings and closures of the internal valves), but this does not affect the dissipation capacity of the water reservoir.
For the discharging process, the chilled water produced was stored in a water tank, maintaining the water reservoir as dissipation system. Different cycles were performed varying the set-point of the chilled water temperature from 7 °C to 15 °C. The temperature in the water reservoir was kept around 20 °C. The flow rate through the cooling distribution circuit has been fixed at 14 L/min. The flow rate through the dissipation circuit varied in the same range as in the charging process.
4. Conclusions
The use of renewable resources and improved energy efficiency can help reduce final energy consumption in buildings, which is growing even in technologically developed countries with favourable climatic conditions.
Cooling machines can be tested in the Gijón Solar Cooling Laboratory (GSCL) with a variety of heat sources and sinks, as well as different technologies and strategies.
A ClimateWell CW10 absorption machine, with internal energy storage in LiCl salts, has been tested at the GSCL, measuring power and temperatures as a function of time during several charging and discharging cycles.
In the experiments it has been observed that, with a heat sink temperature close to 20 °C, it is necessary to have a driving heat temperature level at least of 75 °C, in order to obtain a charging time of practical interest. Under these conditions, the machine can store about 286,000 kJ for a charging time ranging from 4 to 6 h, with an average supplied power ranging from 13 to 20 kW depending on the hot temperature.
During the discharge cycles, the chilled water temperature at the machine outlet was approximately between 10 °C and 13 °C, with the return temperature being practically equal to 20 °C in all cases. In these conditions, the machine produced approximately cooling energy values between 120,000 kJ and 173,500 kJ, with discharge times between 5.5 h and 7 h and more uniform refrigeration capacity values, between 6.3 kW and 7.8 kW.
The machine achieves COP values that match the literature references, but results predict that extra use of auxiliary heating systems may be needed for applications with low levels of insolation.