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Article

Exergy Analyses and Modelling of a Novel Extra-Low Temperature Dedicated Outdoor Air System

1
Department of Building Services Engineering, The Hong Kong Polytechnic University, Hong Kong, China
2
Department of Built Environment and Energy Utilization Engineering, Taiyuan University of Technology; Taiyuan 030024, China
*
Author to whom correspondence should be addressed.
Energies 2018, 11(5), 1165; https://doi.org/10.3390/en11051165
Submission received: 14 March 2018 / Revised: 17 April 2018 / Accepted: 4 May 2018 / Published: 7 May 2018

Abstract

:
A novel dedicated outdoor air system (DOAS) comprising a multi-stage direct expansion coil to produce extra-low temperature (XT) outdoor air to handle the entire space cooling demand has been confirmed more efficient than conventional systems. To further enhance the performance of XT-DOAS, the optimum number of cooling stages and treated outdoor air temperature need to be determined. This process requires the development of a coil performance model that takes into account the extra-high and extra-low entering air temperatures at the first and the last cooling stages. In this study, factory test data and field measurement data were used to develop such a performance model. Different statistical analyses were employed to validate the developed model. Based on the developed model, energy and exergy analyses were conducted to evaluate use of XT-DOAS for space cooling of a typical office building in Hong Kong. EnergyPlus was employed for the energy analysis. The laws of thermodynamics were used for the exergy analysis. Their combined results indicate that for better energy efficiency and performance for air-conditioning of office buildings in subtropical region, the optimum configuration for XT-DOAS is two cooling stages with a treated outdoor air temperature of 7 °C. The model developed and the energy and exergy analyses described will contribute significantly to future research in this area.

1. Introduction

The use of a dedicated outdoor air system (DOAS) for air-conditioning of office buildings has been widely investigated in recent years for better indoor air quality and energy efficiency [1]. A conventional DOAS often comprises two systems: an outdoor air (OA) system dedicated to produce high quantities of OA that handles the entire latent loads and part of the space sensible loads; and a terminal system to handle the remaining space sensible loads. As such, OA flow rate is higher and return air (RA) does not need to be circulated across different zones to enhance the indoor air quality. The OA system often uses active-desiccant technology; whilst the terminal system can be chilled beams/ceilings [2]. Energy savings can be derived from reheating and dehumidification energy reductions. However, there are concerns with such a system configuration. The use of active-desiccant technology to produce OA, despite it is energy effective [3], is space intensive to hinder its popular use in land scarcity cities like Hong Kong [4]. The use of chilled beams/ceilings as a terminal system will cause condensation problem, especially in subtropical regions where summers are long, hot and humid [2]. To solve the condensation problem, previous works proposed to keep beam/ceiling surface temperature above the indoor dew-point temperature by using different control methods [5] and system configurations [6] and to limit the indoor humidity gain [7]. However, the proposed methods will unavoidably introduce constraints on the cooling capacity [5] and operation of the terminal system [8].
To address the concerns, research studies have been done to investigate into using other system configurations. A series of studies have been done to investigate the use of chilled water system to treat OA and the use of dry fan-coil unit as the terminal system. However, it was found that the potential energy benefit is not significant and the condensation problem still exists [9,10,11]. Another study investigated the use of fan-coil unit as the OA system and chilled ceiling as the terminal system. However, it was found that condensate-free can only be achieved on the provision of a surface temperature control [12].
Hong Kong is a subtropical city where summers are hot and humid which increases the latent load significantly. Using treated outdoor air at extra-low temperature to handle the entire space load can take advantage of the use of deep coils to reduce the by-pass factor [13] for more efficient operation of the central cooling system. In this regard, a novel DOAS has been proposed [14]. The proposed DOAS system is a cold air distribution system that consists of a DOAS central system to produce extra-low temperature (XT) OA to handle the entire space cooling load and a mixing chamber as the terminal system for XT OA and RA. With this configuration, no cooling is required at the conditioned space to avoid condensation problems.
The central system is a variable speed multi-stage direct expansion (DX) unit. A DX unit is used because of its ability to operate at low evaporator temperatures to achieve the intended cooling and dehumidification objectives [15]. Energy savings are associated with the use of XT OA, variable speed system and multi-stage configuration. Dry XT OA enables the use of high-temperature and low-humidity indoor design condition to save energy [16]. Variable-speed system capable of regulating its motor speed to modulate output is considered more energy efficient [17]. The multi-stage configuration, which is a novel concept, enables improved equipment performance associated with working under higher evaporator temperatures (1st stage) and smaller temperature lifts (between evaporator and condenser) [18]. It also enables the use of different control strategies to have further energy benefits [19].
A series of studies have been conducted by the authors to confirm the effective usage of the proposed XT-DOAS in a Hong Kong office environment. Based on the use of different system configurations, it was found that the proposed system, as compared to the conventional system, can reduce the annual indoor discomfort hours by 16.2% to 69.4%, the annual air-conditioning energy use by 12% to 22.6%, and the condensation risk to almost zero [14,20,21]. The desired indoor relative humidity can also be better achieved [14]. However, in these studies, the analyses were focused on performance comparison with conventional system and were done based on a conventional coil performance model. This is acceptable for previous studies, but for optimizing the system configuration to achieve desirable air conditions and better energy efficiency, it is not desirable because XT-DOAS receives hot and humid OA at the first cooling stage and handles extra-low temperature air at the last cooling stage to introduce substantial influence on the DX coil’s performance [22]. Unfortunately, a performance curve that takes into account the extra-high temperature range is lacking in the public literature.
Using parallel-connected units to meet cooling demand is commonly seen in central chilled water systems. A lot of studies have been done to investigate the influence of different designs on the system’s overall performance including heat rejection mediums [23], ambient conditions [24], compressor efficiencies [25], unit capacities [26] and part load performances [27]. However, for the series-connected multi-stage DX system, the overall performance is not only affected by the above factors, but also affected by the entering air thermodynamic states at different part load conditions. Previous work is virtually none.
As for energy performance evaluation, previous studies rarely take into account the exergy efficiency [28]. Exergy analysis is based on the second law of thermodynamics. It can identify localized inefficiencies and thus is commonly used for the design, and performance evaluation of energy systems [29]. For the proposed XT-DOAS using series-connected multi-stage DX system, the moist air entering and leaving individual cooling stages is of different states to affect the available energy and thus the exergy efficiency [30]. Therefore, exergy analysis is essential for the optimum design of multi-stage DX system. Considering that both energy use and exergy loss are essential energy system characteristics, the authors had conducted an exergy analysis on XT-DOAS and confirmed that it was more energy efficient than conventional system [21]. However, in the previous study, the multi-stage DX system was regarded as an integral component. The multi-stage characteristic had not been considered.
Given the limitations of previous studies, this study aims to develop a realistic coil performance to optimize the system configuration of XT-DOAS aiming to achieve desirable air conditions and better energy efficiency. The energy efficiency evaluations will be based on energy as well as exergy analyses to take into account the combined influence of the thermodynamic states of moist air entering and leaving individual cooling stages and the corresponding part load conditions on the overall performance of XT-DOAS. The multi-stage characteristics of the DX coil will be considered in the exergy analysis.

2. System Description

The proposed XT-DOAS system consists of a central OA system and a mixing box as the terminal system. They both are assumed provided with variable air volume (VAV) control because Hong Kong office buildings typically adopt VAV systems [31]. Figure 1 and Figure 2 show the schematic diagram and the psychrometric process of the proposed XT-DOAS system. The central system uses a multi-stage DX coil to generate a variable volume of OA (State O) with minimum flow setting to a saturated and XT state (State X) and subsequently delivers to the mixing box of individual zones to mix with the space return air (State R) to become supply air (State S). A variable volume of supply air successively delivers to the space to offset the instantaneous cooling demand to maintain the desired space conditions (State R). The minimum OA flow setting is to satisfy the minimum ventilation requirement of the occupied spaces [32].
The thermodynamic states in Figure 1 and Figure 2 and the associated airflow rates were preliminarily determined by common design practice. The design parameters are summarized in Table 1. It can be seen that the desired indoor conditions were set as 24.5 °C dry bulb (DB) and 35% relative humidity (RH), which according to a previous study, has the equivalent thermal comfort level as the common desired indoor condition in Hong Kong (24 °C DB/50% RH) [14]. A slightly higher indoor temperature helps reduce sensible cooling energy use to offset the additional latent cooling energy use [16]. Moreover, to avoid thermal discomfort caused by dumpling XT OA directly into the air-conditioned space, the XT OA is designed to mix with RA to become supply air at 18 °C (State S) for better thermal comfort [20]. The outdoor air conditions (State O) used in the simulation were referred to the hourly data of the Typical Meteorological Year file of Hong Kong.

3. Methodology

The energy performance of XT-DOAS is dominated by the consumption of the multi-stage DX unit and VAV fans. Thus to optimize the system configuration aiming to achieve desirable air conditions and better energy efficiency, the focus is to determine the treated OA temperature (tX, the multi-stage DX coil leaving air temperature at State X) and the number of cooling stages (N), which correspondingly affect the thermodynamic states of moist air entering and leaving individual cooling stages and the associated part load conditions.
Energy simulations and exergy analysis were performed for the use of XT-DOAS in a case study building based upon a realistic coil performance model developed to account for the extra-high and extra-low entering air temperatures. EnergyPlus Version 8.1 was employed for the energy simulations.

3.1. Case Study Building

A typical office building in Hong Kong was selected as a case study building to facilitate this study. The building’s architectural, construction and services system characteristics were established based on findings of extensive surveys conducted in Hong Kong [10]. The usage patterns of the air-conditioning, occupants, lighting and appliances, etc. were by referenced to BEAMPlus [33]. The design parameters were determined according to local codes [34]. As the same case study building has been referenced for many previous studies [14,20,21,35,36], to avoid duplications, only the typical floor layout and building characteristics are given. They are shown in Figure 3 and Table 2, respectively.
In deciding the range of values for the two studied parameters, reference was made to cold system design [15] and previous studies [14,20,21]. tX, was set as 4 °C to 10 °C (1 °C interval) and the number of cooling stage (N) was set as 2 to 4. Single cooling stage has been excluded to avoid operating at unfavourably high temperature differential [15] and to benefit from multi-stage characteristics.

3.2. Coil Performance Model Development

Owing to the high entering air temperature and extra-low leaving air temperature to affect the coil performance for XT-DOAS [22], two default performance curves in EnergyPlus (abbreviated as CAP-FT and EIR-FT) for total cooling output (CAP) and the energy input ratio (EIR), as a function of temperature (FT), need to be developed.

3.2.1. Performance Curve Formulation

According to EnergyPlus, the two performance curves to be developed are mathematically shown below [22]:
C A P - F T = C A P / C A P r a t e d = a 1 + a 2 W B e i + a 3 W B e i 2 + a 4 D B c i + a 5 D B c i 2 + a 6 W B e i D B c i ,
E I R - F T = E I R / E I R r a t e d = b 1 + b 2 W B e i + b 3 W B e i 2 + b 4 D B c i + b 5 D B c i 2 + b 6 W B e i D B c i ,
where CAP is the total cooling output, kW; CAPrated is the rated total cooling capacity, kW; EIRrated is the rated power input ratio, which is the inverse of the rated energy efficiency ratio; EIR is the operating power input ratio, which is the inverse of the operating energy efficiency ratio; WBei is the entering air wet bulb temperature at the DX coil (evaporator), °C; DBci is the entering air dry bulb temperature at the condenser, °C; a i and b i are empirical coefficients.
Regression analysis [37] was used to determine the empirical coefficients a i in CAP-FT and EIR-FT curves based on real data.

3.2.2. Data Collection

To formulate the performance curves that cover a much higher temperature range than that of a conventional system, performance data for DX unit operating at extra-high and extra-low temperature range needs to be collected.

Extra-Low Temperature Side

Performance data for the extra-low temperature side was obtained from a field measurement campaign. The field measurement was conducted at a pilot installation [38]. It comprises two DX air-conditioners each with a cooling capacity of 22.7 kW together with a total enthalpy heat exchanger. They were connected in series to generate supply air at 6 °C DB to maintain a 56 m2 store room at 10 °C DB. The store room is for dangerous goods. It requires to be maintained at around 10 °C DB year round. To reduce the explosion risk, no air recirculation is allowed, which resembles a DOAS configuration. The air-side operating conditions (outdoor air temperature, and the entering and leaving air dry bulb and wet bulb temperatures) and the power consumption of the two DX air-conditioners and the condenser fans in the pilot installation were monitored by a remote monitoring system. Given the two DX units were with different operating conditions and thus efficiencies, a sufficiently wide range of data were collected to develop the extra-low temperature part of CAP-FT and EIR-FT curves. Specifications of the DX air-conditioners and the configuration of the pilot installation are shown in Table 3 and Figure 4, respectively.

Extra-High Temperature Side

DX units that can handle high temperature OA are rare in the market. With enormous effort made to contact different manufacturers, factory test data of a series of brand new DX units dedicated for OA conditioning were collected [39]. The test data covers performance characteristics of DX units treating OA at a maximum of 35 °C DB and 32 °C WB to a discharge temperature of 18 °C DB. It includes the total cooling capacity and input power at various outdoor air conditions. The total cooling capacity is a gross value. The total input power includes the consumption of compressor, condenser fan and auxiliary equipment (e.g., control panel power) but excludes the supply air fan.
By normalizing the field measurement and factory test data into consistent format as summarized in Table 4, regression analysis was conducted to develop a standardized set of performance curves that covers the entire operation range of XT-DOAS. In Table 4, a normalized performance coefficient of 1 refers to the performance at AHRI standard rated test condition [40].

3.2.3. Regression Models

Based on the data collected as detailed in Section 3.2.2, multiple regression analysis using SPSS [41] was conducted to determine the coefficients for the CAP-FT and EIR-FT curves (Equations (1) and (2)). The regressed coefficients and the resultant models are shown as follows:
C A P - F T = 0.79107 0.11682 × W B e i + 0.00662 × W B e i 2 + 0.01253 × D B c i 0.00014 × D B c i 2 0.00039 × W B e i × D B c i ,   ( R a 2 = 0.985 ) ,
E I R - F T = 6.91628 0.41839 × W B e i + 0.00588 × W B e i 2 0.03192 × D B c i 0.00071 × D B c i 2 + 0.00293 × W B e i × D B c i ,   ( R a 2 = 0.981 ) ,
Verification of the regression models is summarized in Appendix A. Figure 5 and Figure 6 are visual representation of the CAP-FT and EIR-FT performance curves. The CAP-FT curve shows that the DX coil’s cooling output CAP increases with entering air WB temperature WBei but varies very little with the condenser entering air DB temperature DBci. The EIR-FT curve shows that the CAP increases primarily with WBei but the power input W decreases with both WBei and DBci. In other words, a lower WBei results in a higher EIR and thus lower COP.

3.3. Energy Analysis

Based on the developed coil performance model, EnergyPlus simulations were performed. The inputs to EnergyPlus include the hourly meteorological conditions in Hong Kong, the internal heat sources (occupants, lighting and equipment), the studied building’s architectural and construction details, the air-conditioning system adopted (XT-DOAS in this case), the system and equipment characteristics and the range of studied parameters. The result generated after the simulation run is extensive. It allows users to extract the desired data, which include temperatures, moisture contents, mass flow rates, coils’ cooling outputs, space sensible and latent loads and energy usage of the equipments. Based on the resultant space air conditions, the ability of the XT-DOAS operating under the pre-defined range of studied parameters to maintain the desirable air conditions was evaluated. The corresponding energy usage was also extracted for exergy analysis.

3.4. Exergy Analysis

Based on energy simulation results from EnergyPlus, exergy analysis was performed based on the laws of thermodynamics. Exergy analysis has been used to examine the optimum air states entering and leaving the multi-stage coil associated with the changes in tX and N, which includes the calculation of moist air exergy and exergy efficiency of different system configurations.

3.4.1. Moist Air Exergy

Air-conditioning systems handle moist air. The exergy level of moist air is therefore important. Moist air exergy is the maximum useful power when moist air is converted reversibly to the environment. Most exergy research regards the reference environment state as the dead state and assumes zero exergy to calculate the exergy change [42]. While considering the unsaturated moist air still has energy available, the dead state is suggested as the saturated moist air at the same temperature and pressure as the reference environment state [43]. However, given the reference environment state varies with outdoor conditions, in this study, the hourly energy and exergy analysis based on year-round outdoor conditions were considered. By treating the moist air encountered in an air conditioning system as an ideal gas, the moist air exergy transferred from the basic forms of relevant exergy can be represented by Equation (5) which is [44]:
e x = ( C d a + w C w v ) [ T T 0 T 0 ln ( T / T 0 ) ] + ( 1 + 1.608 w ) R d a T 0 ln ( P / P 0 ) + R d a T 0 { ( 1 + 1.608 w ) ln [ ( 1 + 1.608 w 0 s ) / ( 1 + 1.608 w ) ] + 1.608 w ln ( w / w 0 s ) } ,
where ex is the exergy of moist air per unit mass dry air, kJ/kg dry air; Cda is the specific heat of dry air, kJ/kg·K; Cwv is the specific heat of water vapour, kJ/kg·K; w is the humidity ratio of moist air, kg/kg dry air; w 0 s is the humidity ratio of dead state, kg/kg dry air; T is the temperature of moist air, K; T0 is the reference environmental temperature, K; Rda is the ideal gas constant of dry air, kJ/kg·K; P is the pressure of moist air, kPa; P0 is the reference environmental barometric pressure (atmospheric pressure), kPa.
The total exergy of moist air (ex) can also be represented as the sum of thermal exergy (exth), mechanical exergy (exme) and chemical exergy (exch). Thermal exergy is the maximum useful work when moist air is transformed from the initial temperature state to the dead temperature state. Mechanical exergy is equal to the mechanical work itself. Chemical exergy represents the maximum useful work associated with the transition of moisture content of moist air from the initial state to the dead state. They are represented by Equations (6) to (8), which are derived from Equation (5):
e x t h = ( C d a + w C w v ) [ T T 0 T 0 ln ( T / T 0 ) ] ,
e x m e = ( 1 + 1.608 w ) R d a T 0 ln ( P / P 0 ) ,
e x c h = R d a T 0 { ( 1 + 1.608 w ) ln [ ( 1 + 1.608 w 0 s ) / ( 1 + 1.608 w ) ] + 1.608 w ln ( w / w 0 s ) } ,
Since w0s in Equations (5) and (8) cannot be output directly from EnergyPlus, it has to be calculated by the ideal gas law from the reference environmental barometric pressure (P0) and the saturation pressure of water vapour (Pws), as described in Equation (9):
w 0 s = 0.622 P w s / ( P 0 P w s ) ,
The saturation pressure of water vapour can be determined by Equation (10), which is of sufficient accuracy between 273.15K (0 °C) and 646.15 K (373 °C) [45].
ln ( P w s / P c ) = ( T c / T ) ( 7.860 ϑ + 1.844 ϑ 1.5 11.787 ϑ 3 + 22.681 ϑ 3.5 15.962 ϑ 4 + 1.801 ϑ 7.5 ) , ϑ = 1 T / T c ,
where Tc is the critical temperature, 647.096 K; Pc is the critical pressure, 22,064 kPa.

3.4.2. Exergy Flow

For calculation of the exergy efficiency of multi-stage DX system, the exergy flow and the exergy balance have to be defined. The exergy flow in a typical DX system is shown in Figure 7, and the exergy balance is represented in Equation (11). To address the multi-stage characteristics of DX system, the exergy flow and exergy balance have to be further defined as shown in Figure 8 and Equation (12) correspondingly:
E x , e p , i n + E x , c d , i n + W = E x , e p , o u t + E x , c d , o u t + E x , l o s s ,
E x , e p , i n 1 + j = 1 N E x , c d , i n j + j = 1 N W j + W F a n = E x , e p , o u t N + j = 1 N E x . c d , o u t j + E x , t o t , l o s s ,
where j is the j-th stage DX coil; E x , e p , i n 1 is the exergy of moist air entering in the evaporator of first cooling stage, MWh; E x , e p , o u t N is the exergy of moist air out of the evaporator of last cooling stage, MWh; j = 1 N E x , c d , i n j is the sum of moist air exergy entering in the all condensers, MWh; j = 1 N E x , c d , o u t j is the sum of moist air exergy out of all condensers, MWh; j = 1 N W j is the sum of input power to the whole system, MWh; WFan is the power input of supply fan, MWh; Ex,tot,loss is the total exergy loss of multi-stage DX system, MWh.

3.4.3. Exergy Efficiency

Exergy efficiency η E x for a system is defined as the ratio of the exergy desired Ex,desired and the exergy needed for the desired effect Ex,needed [42]. A higher exergy efficiency means a more ideal system.
Based on the calculation results from Equations (5) to (12), for a multi-stage DX system where the exergy of moist air leaving the condenser is not recovered, the exergy efficiency can be determined by Equation (13)
η E x = E x , d e s i r e d / E x , n e e d e d = E x , e p , o u t N / ( E x , e p , i n 1 + j = 1 N W j + j = 1 N E x , c d , i n j + W F a n ) .

4. Results and Discussion

To optimize the system configuration of XT-DOAS for maximum performance, based on the range of tX and N explained in Section 3 and assuming only one parameter was varied, 21 cases (seven tX, and three N) were generated for hour-by-hour EnergyPlus simulations and exergy analysis. The design conditions of the 21 cases, based on common practice to allow equal sharing of load amongst cooling stages [46], are summarized in Table 5. The cooling capacity at each cooling stage was automatically adjusted according to tX, N and OA mass flow rate.
Based on the results of EnergyPlus simulations and the subsequent calculations, the year-round energy use and exergy efficiency of the 21 cases for different N and tX are presented in Figure 9, illustrating that in general, energy use (En) decreases with tX and increases with N, while exergy efficiency ( η E x ) peaks with tX at 7 °C and decreases with N. N equals 2 and thus always results in a lower energy use and higher exergy efficiency.
As far as tX is concerned, considering exergy efficiency ( η E x ) is a more meaningful indicator of efficiency that accounts for quantity and quality aspects of energy flows when compared to energy [47], the optimum tX for a 2-stage XT-DOAS is 7 °C for having the highest exergy efficiency (=10.37%).
Since tX affects also the achievement of the desirable air conditions, the achievable indoor conditions for different tX were also investigated. Given the indoor temperature can be controlled, the investigations are focused on the resultant indoor relative humidity (RH). Its achievement is one specific characteristic of XT-DOAS [14]. The Root-Mean-Square Error (RMSE) value was used to quantify the deviation between the hourly resultant space RH and the desired value (35%) for different tX. RMSE can be calculated by Equation (14). A smaller RMSERH means better humidity control:
R M S E R H = i = 1 n ( R H s p x R H d e s i g n ) 2 / n ,
where RMSERH is the RMSE of the space RH; RHspx is the resultant space RH; RHdesign is the desired space RH, 35%; n is the annual operating hour.
Table 6 presents the resultant space RH and calculated RMSERH for different tX. It can be seen that the smallest RMSERH occurs when tX is 7 °C (=3.38), which is accordant with the exergy analysis results.
To explain the influence of N and tX on the energy use, exergy efficiency and achievable space RH and thus the concluded optimum N and tX, further energy and exergy analysis, as well space humidity condition evaluations were conducted.

4.1. Energy Analysis

Figure 10 shows the annual energy use and COPsys for different N and tX which are basically determined by j = 1 N W j and W F a n .
It can be seen that, regardless of N, W F a n increases with tX but the rate of increase, as compared to the rate of drop in j = 1 N W j with tX, is far less significant. Thus COPsys also increases with tX. However, as for the influence of N on j = 1 N W j and thus COPsys, an analysis on the influential factors is needed. For a DX coil with defined performance curves (Section 3.2), the parameters affecting its COP, by reference to EnergyPlus, are summarized in Equations (15) through (22):
C O P = C A P / W ,
C A P = C d a m Δ t ,
W = C A P R T F E I R ,
R T F = P L R / P L F = P L R / ( 0.85 + 0.15 × P L R ) ,
P L R = C A P / C A P r a t e d ,
E I R = E I R r a t e d ( E I R - F T ) ( E I R - F F ) ,
E I R - F F = c 1 + c 2 ( m / m r a t e d ) + c 3 ( m / m r a t e d ) 2 + c 4 ( m / m r a t e d ) 3 ,
C O P = ( 0.85 × C A P r a t e d / C A P + 0.15 ) / ( E I R r a t e d ( E I R - F T ) ( E I R - F F ) ) = f ( m , Δ t , W B e i , D B c i ) ,
where Δ t is the entering and leaving air temperature difference across a DX coil, °C; RTF is the run time fraction; EIR-FF is a EIR modifier curve as a function of air flow fraction; m is the actual air mass flow rate, kg/s; mrated is the rated air mass flow rate, kg/s; c i are empirical coefficients.
In Equation (22), the CAPrated and EIRrated of each cooling stage are constant terms; EIR-FT is a function of WBei and DBci; EIR-FF is a function of air flow fraction which is the ratio of m entering the DX coil to a constant term mrated; CAP is a function of m and Δ t . DBci is affected by the outdoor air condition which is the same for all system configuration and therefore is not necessary to consider. m is determined by tX so it is not an independent variable. Thus, COP can be described as a function of Δ t and WBei as shown in Equation (23):
C O P f ( Δ t , W B e i ) ,
C O P = d 1 + d 2 W B e i + d 3 Δ t + d 4 W B e i Δ t ,
Equation (23) can then be postulated as [48]:
where d1, d2, d3, and d4 are constants.
Based on EnergyPlus simulation results, regression analysis was performed using the statistical package SPSS [41] to determine the coefficients for Equation (24). The resultant model is shown below:
C O P = 1.609 + 0.363 × W B e i 0.442 × Δ t + 0.017 × W B e i Δ t ,   ( R 2 = 0.920 ) ,
The value of c 2 and c 3 indicate that WBei has a positive effect on COP while Δ t has a negative effect. The resultant model (Equation (25)) provides a convenient way to quantify the influences of WBei and Δ t on the COP of a DX coil. This can be done by taking partial derivative of COP with respect to WBei and Δ t as follows:
( C O P / W B e i ) ( W B e i / C O P ) ,
and:
( C O P / Δ t ) ( Δ t / C O P ) ,
Based on Equations (26) through (27), and also the average values for WBei, Δ t and COP, the sensitivities of WBei and Δ t were estimated to be 2.035 and 0.179 to show that WBei introduces much higher influence on a DX coil’s COP. The result is consistent with the visual representation in Section 3.2.3, Figure 5 and Figure 6.
To confirm the need of the developed model that takes into account the extra-high entering air temperature, the energy consumptions predicted based on the developed model and a conventional model [14], were compared. It was found that for different WBei, the difference was high ranging from 7.23% to 12.67%.
In addition, for XT-DOAS with different N, the system COP (COPsys) is related to individual cooling stage’s COP and thus is also related to WBei and Δ t . Therefore, a higher COPsys can be regarded as a function of the average Δ t ( Δ t ¯ ) and WBei ( W B ¯ e i ) of all cooling stages as expressed in Equation (28). A lower Δ t ¯ and a higher W B ¯ e i result in a higher COPsys:
C O P s y s = j = 1 N C A P j / j = 1 N W = f ( C O P 1 , C O P 2 C O P N ) f ( Δ t ¯ , W B ¯ e i ) ,
Figure 11 and Figure 12 show the variations of Δ t ¯ and W B ¯ e i for different N and tX, illustrating that Δ t ¯ decreases with tX and N, and W B ¯ e i increases with tX and N. With the higher influence of W B ¯ e i than Δ t ¯ on COPsys, the results explain the preference for a smaller N (2-stage over 4-stage) and a higher tX for better COPsys and thus smaller j = 1 N W j .
The observations in Figure 11 and Figure 12 accord with the energy use in Figure 10 to confirm the influence of N and tX on the energy use.

4.2. Exergy Analysis

Table 7 and Table 8 summarize the exergy flow for the 21 cases calculated based on Equations (11) through Equation (13). j = 1 N W j and W F a n are included because according to Equation (12), they also contribute to the exergy balance.
In Table 7, under the same tX but different N, E x , e p , i n 1 , E x , e p , o u t N and W F a n are identical because they have the same entering and leaving air states (State O and State X). While for j = 1 N E x , c d , i n j , as it is determined by the refrigerant pressures at the condenser, it decreases with N. However, its influence on η E x (−2.39% to −5.90%), as compared to j = 1 N W j (4.61% to 15.10%), is far less significant. Given j = 1 N W j increases with N as confirmed earlier (Section 4.1), this can explain the percentage change in η E x relative to N at 2 are always negative (−2.47% to −9.58%), and the highest occurs when N is 2.
In Table 8, under the same N but different tX, E x , e p , i n 1 and W F a n increase with tX due to the corresponding increase in m of OA. On the contrary, E x , e p , o u t N decreases with tX due to the higher DB and higher treated OA humidity ratio of (State X). j = 1 N E x , c d , i n j and j = 1 N W j also decrease with tX as explained earlier (Section 4.1). With the counter-effect of two positive and three negative variables on η E x , the percentage change in η E x relative to tX at 7 °C are always negative (−0.20 % to −10.52%), and the highest occurs when tX is 7 °C.
It is evident from the above that the energy and exergy analyses results are well explained and consistent to confirm that the optimum N is 2 and tX is 7 °C.
The results highlight the significant influence of the entering air conditions on the overall performance of the multi-stage DX system and the need of exergy analysis to determine the number of cooling N and the treated OA temperature tX.

4.3. Space Relative Humidity Control

To explain better relative humidity control as identified earlier for tX at 7 °C, the space sensible heat ratios (SHR) and the designed equipment SHR were reviewed. Given the space relative humidity is achieved by matching the equipment sensible heat ratio (SHRsys) and the space SHR (SHRspx) [49], to explain the better humidity control for tX at 7 °C, the divergence between SHRsys and SHRspx were reviewed. The hourly SHRspx are outputs of EnergyPlus. Two indices have been employed to review the divergence between SHRsys and SHRspx for different tX, they are the index of agreement (IA) and RMSE. IA is a dimensionless indicator that enables consistency comparison between models [50]. A higher IA (from 0 to 1) means a more consistent tendency of change [51].
RMSE, as explained earlier, is used to quantify the deviation between SHRsys and SHRspx. IASHR and RMSESHR are expressed in Equations (29) and (30).
I A S H R = 1 i = 1 n ( S H R s y s S H R s p x ) 2 / i = 1 n ( | S H R s y s S H R ¯ s p x | + | S H R s p x S H R ¯ s p x | ) 2 ,
R M S E S H R = i = 1 n ( S H R s y s S H R s p x ) 2 / n ,
where S H R ¯ s p x is the annual average SHR of all zones.
Calculation results for different tX are summarized in Table 9, illustrating that the highest IASHR (=0.6705) and the smallest RMSESHR (=0.0532) occurs when tX is at 7 °C.

5. Conclusions

In this study, a realistic DX coil performance model that covers an exceptionally large entering air temperature range (from 6 °C DB to 35 °C DB), which is absent in the current literature, was developed for energy simulations and analyses. The model was developed based on a set of factory test and field measurement data. Its validity was verified by different statistical analyses. Based on the developed performance model, hour-by-hour simulations under varying outdoor conditions, together with exergy analyses for moist air at different entering and leaving states associated with variations in system configurations, were conducted for the use of a novel XT-DOAS in a typical office building. It was confirmed that the optimum configuration for XT-DOAS, taking into account the combined effect of the entering air states and part load conditions on the overall energy and exergy efficiency of the multi-stage DX system, is two cooling stage with a treated outdoor air temperature of 7 °C. The optimum treated OA temperature, through checking of divergence between equipment and space sensible heat ratios, was confirmed able to achieve a better space humidity control. The results of this study enable optimizing the configuration of XT-DOAS for better energy efficiency and performance of office buildings in subtropical region. The developed model, which is validated, will contribute significantly for future study of atypical systems. The energy and exergy analyses described in this study would become a reference protocol to enhance future research in this area.

Author Contributions

Conceptualization, Yani Bao and Wai Ling Lee; Methodology, Yani Bao; Validation, Yani Bao; Formal Analysis, Yani Bao and Jie Jia; Investigation, Yani Bao; Data Curation, Jie Jia; Writing-Original Draft Preparation, Yani Bao; Writing-Review & Editing, Wai Ling Lee.

Acknowledgments

This work was supported by the RGC funding No. B-Q42W.

Conflicts of Interest

The authors declare that there is no conflicts of interest.

Nomenclature

a i i-th empirical coefficient
b i i-th empirical coefficient
CAPtotal cooling capacity (kW)
Cdadry air specific heat (kJ/kg·K)
c i i-th empirical coefficient
COPcoefficient of performance
Cwvwater vapour specific heat (kJ/kg·K)
DBdry bulb
DXdirect expansion
d i i-th empirical coefficient
EIRenergy input ratio
eresidual
Enenergy use (MWh)
exexergy of moist air (kJ/kg dry air)
Ex,cd,inexergy of moist air entering in the condenser (MWh)
Ex,cd,outexergy of moist air out of the condenser (MWh)
Ex,desiredexergy desired for a system (MWh)
Ex,ep,inexergy of moist air entering in the evaporator (MWh)
Ex,ep,outexergy of moist air out of the evaporator (MWh)
Ex,lossexergy loss of DX unit (MWh)
Ex,neededexergy needed for the desired effect of the system (MWh)
Ex,tot,losstotal exergy loss of multi-stage DX system (MWh)
FFfunction of air flow fraction
FTfunction of temperature
IAindex of agreement
mair mass flow rate (kg/s)
Ncooling stage number of multi-stage DX system
OAoutdoor air
Ppressure (kPa)
PLFpart load fraction
PLRpart load ratio
RAreturn air
Rdathe ideal gas constant of dry air (kJ/kg·K)
RHrelative humidity
RMSEroot-mean-square error
RTFrun time fraction
SHRsensible heat ratio
Ttemperature (K)
ttemperature (°C)
Δ t temperature difference between air in and out of DX coil (°C)
WBwet bulb
Wcompressor power (MWh)
w moist air humidity ratio (kg/kg dry air)
XTextra-low temperature
ZREstandard residual
Greek symbols
ε exergy loss ratio
η E x exergy efficiency
Subscripts
0reference environmental state
0sdead state
ccritical state
chchemical
cicondenser inlet
designdesign condition
eievaporator (DX coil) inlet
Fanfan
jj-th stage DX coil
memechanical
ratedrated condition
spxconditioned spaces
sysmulti-stage DX system
ththermal
wssaturated state of water vapour
Xstate of outdoor air treated by the last cooling stage
yannual value

Appendix A

The acceptability of the regression models presented in Section 3.2.3 was verified by checking both goodness of fit and linearity as follows:
The goodness-of-fit indices, R 2 and the adjusted R 2 ( R a 2 ) were used to determine how well the regression models fit the observations and predictions. R a 2 is more suitable for multiple regression in this study as it can adjust the goodness-of-fit for the additional variables. They are mathematically shown in Equations (A1) and (A2) [37]:
R 2 = 1 i = 1 n ( y i y ^ i ) 2 / i = 1 n ( y i y ¯ ) 2
R a 2 = 1 ( 1 R 2 ) ( n 1 ) / ( n p 1 )
where y i is the i-th actual value of C A P / C A P r a t e d and E I R / E I R r a t e d based on different WBei and DBci in Equations (1) and (2); y ¯ is the mean of actual values; y ^ i is the i-th fitted value which can be calculated from the different WBei , DBci and regressed coefficients; n is total number of data pairs; p is the number of independent variables.
The results show that the R 2 and R a 2 are 0.986 and 0.985 for the CAP-FT model and 0.982 and 0.981 for the EIR-FT model which are close to 1 to confirm their accuracy [37].
In addition to checking of goodness-of-fit, the linearity validation has been considered. In general, the validity of linear assumption can be confirmed by examining the scatter plot of the data pairs, but considering the large number of variables for the CAP-FT and EIR-FT models, the scatter plots of the standardized residuals and fitted values have been used instead. The i-th standardized residual ZREi has been introduced to standardize the ordinary least squares residual ei as shown in Equations (A3) to (A4), and the result of the scatter plots with a random distribution confirmed the validity of linear assumption [52].
e i = y i y ^ i
Z R E i = e i / i = 1 n e i 2 / ( n p 1 )
Figure A1 and Figure A2 correspondingly show the deviation between the actual values y i and the fitted values y ^ i for CAP-FT and EIR-FT. They reflect the distribution of the corresponding ordinary least squares residual ei and no obvious deviation is noted.
Consistent result from the goodness of fit and linearity checks confirmed the acceptability of the developed coil model.
Figure A1. CAP-FT actual values Vs fitted values.
Figure A1. CAP-FT actual values Vs fitted values.
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Figure A2. EIR-FT actual values Vs fitted values.
Figure A2. EIR-FT actual values Vs fitted values.
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Figure 1. Schematic diagram of XT-DOAS.
Figure 1. Schematic diagram of XT-DOAS.
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Figure 2. Psychrometric process of XT-DOAS.
Figure 2. Psychrometric process of XT-DOAS.
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Figure 3. Typical floor layout of the studied building.
Figure 3. Typical floor layout of the studied building.
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Figure 4. Configuration of the pilot installation.
Figure 4. Configuration of the pilot installation.
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Figure 5. CAP-FT performance curve.
Figure 5. CAP-FT performance curve.
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Figure 6. EIR-FT performance curve.
Figure 6. EIR-FT performance curve.
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Figure 7. Exergy flow of a typical DX unit. (Ex,ep,in—exergy of moist air entering in the evaporator; Ex,ep,out—exergy of moist air out of the evaporator; Ex,cd,in—exergy of moist air entering in the condenser; Ex,cd,out—exergy of moist air out of the condenser; W—Input power for DX unit; Ex,loss—exergy loss of DX unit.).
Figure 7. Exergy flow of a typical DX unit. (Ex,ep,in—exergy of moist air entering in the evaporator; Ex,ep,out—exergy of moist air out of the evaporator; Ex,cd,in—exergy of moist air entering in the condenser; Ex,cd,out—exergy of moist air out of the condenser; W—Input power for DX unit; Ex,loss—exergy loss of DX unit.).
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Figure 8. Exergy flow of a multi-stage DX system. ( E x , e p , i n 1 —exergy of moist air entering in the evaporator of first cooling stage; E x , e p , o u t N —exergy of moist air out of the evaporator of last cooling stage; j = 1 N E x , c d , i n j —the sum of moist air exergy entering in the all condensers; j = 1 N E x , c d , o u t j — the sum of moist air exergy out of all condensers; j = 1 N W j —the sum of input power to whole system; W F a n —the power input of supply fan; Ex,tot,loss —the total exergy loss of multi-stage DX system).
Figure 8. Exergy flow of a multi-stage DX system. ( E x , e p , i n 1 —exergy of moist air entering in the evaporator of first cooling stage; E x , e p , o u t N —exergy of moist air out of the evaporator of last cooling stage; j = 1 N E x , c d , i n j —the sum of moist air exergy entering in the all condensers; j = 1 N E x , c d , o u t j — the sum of moist air exergy out of all condensers; j = 1 N W j —the sum of input power to whole system; W F a n —the power input of supply fan; Ex,tot,loss —the total exergy loss of multi-stage DX system).
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Figure 9. Energy use and exergy efficiency of multi-stage DX system for different N and tX.
Figure 9. Energy use and exergy efficiency of multi-stage DX system for different N and tX.
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Figure 10. Energy use of multi-stage DX system for different N and tX.
Figure 10. Energy use of multi-stage DX system for different N and tX.
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Figure 11. Δ t ¯ y for different N and tX.
Figure 11. Δ t ¯ y for different N and tX.
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Figure 12. W B ¯ e i , y for different N and tX.
Figure 12. W B ¯ e i , y for different N and tX.
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Table 1. Design conditions of XT-DOAS.
Table 1. Design conditions of XT-DOAS.
ParametersValue
Indoor dry bulb temperature (°C)24.5
Indoor relative humidity (%)35
Coil sensible load (kW)63.82
Coil latent load (kW)25.59
State conditions (T °C [DB]/RH%)O33/68
X4/100
S18/48
R24.5/35
OA mass flow rate (kg/s)3.1
Table 2. Building and design characteristics.
Table 2. Building and design characteristics.
DescriptionParameterValue
Physical detailsNo. of storeys1
Area per floor (m2)1296
Air-conditioned area per floor (m2)1071
Floor to floor height (m)3.2
Envelope detailsWallResistance (m2·°C/W)
(thickness (m)/conductivity (W/m·°C))
Granite panel0.009 (0.025/2.9)
Cavity0.157
Concrete0.046 (0.1/2.16)
Plaster0.053 (0.02/0.38)
Heat transfer coefficient (W/m2·°C)3.8
Single glazing windowShading coefficient (SC)0.9
Window to wall ratio (WWR)0.5
Heat transfer coefficient (W/m2·°C)5.5
RoofHeat transfer coefficient (W/m2·°C)0.8
Table 3. Specifications of the DX air-conditioners.
Table 3. Specifications of the DX air-conditioners.
ComponentParameterSpecification
DX Air HandlerSupply air volume flow rate (m3/s)0.21
Outdoor air volume flow rate (m3/s)0.21
Power consumption (kW)2.20
Condensing UnitCooling capacity (kW)22.70
Compressor capacity controlVariable speed
Power consumption (kW)9.63
Table 4. The normalized data sets.
Table 4. The normalized data sets.
Range of WBei6–32 °C
Range of DBci6–35 °C
Range of normalized performance coefficientCAP-FT (0.4–27)
EIR-FT (0.5–3.876)
Total number of data sets104
Table 5. Design conditions of 21 cases.
Table 5. Design conditions of 21 cases.
NLeaving Air Temperature (°C)OA Mass Flow Rate m (kg/s)
Stage 1Stage 2Stage 3Stage 4
218.54--3.10
195--3.25
19.56--3.43
207--3.62
20.58--3.84
219--4.09
21.510--4.37
323134-3.10
23145-3.25
24156-3.43
24.5167-3.62
24.516.58-3.84
25179-4.09
25.51810-4.37
425181143.10
26191253.25
26191263.43
26.52013.573.62
26201483.84
27211594.09
272115104.37
Table 6. The resultant indoor air conditions for different tX.
Table 6. The resultant indoor air conditions for different tX.
Design tX (°C)Resultant Indoor Air RH (%)
MeanRMSERH
430.675.52
532.244.56
633.913.64
735.703.38
837.574.10
939.535.52
1041.627.35
Table 7. Annual exergy results for the same tX but different N (% changed in bracket) *.
Table 7. Annual exergy results for the same tX but different N (% changed in bracket) *.
tX (°C)Cases with NExergy Flow (MWh) η E x (%)
E x , e p , i n 1 j = 1 N E x , c d , i n j j = 1 N W j W F a n E x , e p , o u t N j = 1 N E x , c d , o u t j Ex,tot,loss
421.0424.00140.0322.6618.0527.09142.599.61
323.05 (−3.94%)152.41 (8.84%)26.65154.479.06 (−5.74%)
422.75 (−5.19%)161.17 (15.10%)25.97163.618.69 (−9.58%)
Average1.0423.27151.2022.6618.0526.57153.559.12
521.0923.60129.5222.7917.6726.52132.829.98
323.04 (−2.39%)143.64 (10.90%)26.24146.659.27 (−7.11%)
422.31 (−5.48%)144.57 (11.62%)25.28147.829.26 (−7.21%)
Average1.0922.98139.2422.7917.6726.01142.439.50
621.1523.39120.7523.0717.2926.26124.8010.27
322.75 (−2.74%)132.78 (9.96%)25.90136.559.62 (−6.34%)
422.01 (−5.90%)136.91 (13.39%)25.20140.649.44 (−8.07%)
Average1.1522.71130.1523.0717.2925.79134.009.78
721.2123.14115.1523.3916.9026.03119.9610.37
322.40 (−3.18%)123.87 (7.57%)25.57128.409.89 (−4.67%)
421.97 (−5.03%)127.41 (10.64%)24.93132.159.71 (−6.37%)
Average1.2122.50122.1423.3916.9025.51126.849.99
821.2822.94112.8723.7416.5025.89118.4410.26
322.29 (−2.83%)119.81 (6.14%)25.45125.179.87 (−3.76%)
421.79 (−5.01%)123.42 (9.35%)24.84128.899.69 (−5.52%)
Average1.2822.34118.7023.7416.5025.39124.179.94
921.3622.64111.1424.1416.0925.66117.5310.10
321.93 (−3.14%)118.04 (6.21%)25.19124.199.72 (−3.74%)
421.35 (−5.70%)119.44 (7.47%)24.44125.769.67 (−4.22%)
Average1.3621.97116.2124.1416.0925.10122.499.83
1021.4522.38109.4024.5915.6925.50116.649.94
321.34 (−4.64%)114.44 (4.61%)24.74121.399.70 (−2.47%)
421.08 (−5.80%)117.57 (7.47%)24.42124.599.53 (−4.17%)
Average1.4521.60113.8024.5915.6924.88120.879.72
Note: * % changed is based on N = 2.
Table 8. Annual exergy results for the same N but different tX (% changed in bracket) #.
Table 8. Annual exergy results for the same N but different tX (% changed in bracket) #.
NtX (°C)Exergy Flow (MWh) η E x (%)
E x , e p , i n 1 j = 1 N E x , c d , i n j j = 1 N W j W F a n E x , e p , o u t N j = 1 N E x , c d , o u t j Ex,tot,loss
241.04 (−14.33%)24.00 (3.72%)140.03 (21.60%)22.66 (−3.09%)18.05 (6.79%)27.09142.599.61 (−7.34%)
51.09 (−10.07%)23.60 (2.01%)129.52 (12.48%)22.79 (−2.53%)17.67 (4.54%)26.52132.829.98 (−3.80%)
61.15 (−5.27%)23.39 (1.08%)120.75 (4.86%)23.07 (−1.36%)17.29 (2.32%)26.26124.8010.27 (−1.00%)
71.2123.14115.1523.3916.9026.03119.9610.37
81.28 (5.92%)22.94 (−0.86%)112.87 (−1.98%)23.74 (1.50%)16.50 (−2.39%)25.89118.4410.26 (−1.14%)
91.36 (12.58%)22.64 (−2.15%)111.14 (−3.48%)24.14 (3.22%)16.09 (−4.80%)25.66117.5310.10 (−2.65%)
101.45 (20.18%)22.38 (−3.26%)109.40 (−5.00%)24.59 (5.15%)15.69 (−7.13%)25.50116.649.94 (−4.15%)
Average1.2323.16119.8423.4816.8826.13124.6810.08
341.04 (−14.33%)23.05 (2.90%)152.41 (23.04%)22.66 (−3.09%)18.05 (6.79%)26.65154.479.06 (−8.38%)
51.09 (−10.07%)23.04 (2.84%)143.64 (15.95%)22.79 (−2.53%)17.67 (4.54%)26.24146.659.27 (−6.26%)
61.15 (−5.27%)22.75 (1.55%)132.78 (7.19%)23.07 (−1.36%)17.29 (2.32%)25.90136.559.62 (−2.73%)
71.2122.40123.8723.3916.9025.57128.409.89
81.28 (5.92%)22.29 (−0.49%)119.81 (−3.28%)23.74 (1.50%)16.50 (−2.39%)25.45125.179.87 (−0.20%)
91.36 (12.58%)21.93 (−2.11%)118.04 (−4.71%)24.14 (3.22%)16.09 (−4.80%)25.19124.199.72 (−1.69%)
101.45 (20.18%)21.34 (−4.72%)114.44 (−7.62%)24.59 (5.15%)15.69 (−7.13%)24.74121.399.70 (−1.94%)
Average1.2322.40129.2823.4816.8825.68133.839.59
441.04 (−14.33%)22.75 (3.54%)161.17 (26.50%)22.66 (−3.09%)18.05 (6.79%)25.97163.618.69 (−10.52%)
51.09 (−10.07%)22.31 (1.53%)144.57 (13.47%)22.79 (−2.53%)17.67 (4.54%)25.28147.829.26 (−4.66%)
61.15 (−5.27%)22.01 (0.15%)136.91 (7.46%)23.07 (−1.36%)17.29 (2.32%)25.20140.649.44 (−2.80%)
71.21 21.97 (0.00%)127.41 23.39 16.90 24.93132.159.71
81.28 (5.92%)21.79 (−0.84%)123.42 (−3.13%)23.74 (1.50%)16.50 (−2.39%)24.84128.899.69 (−0.24%)
91.36 (12.58%)21.35 (−2.84%)119.44 (−6.25%)24.14 (3.22%)16.09 (−4.80%)24.44125.769.67 (−0.40%)
101.45 (20.18%)21.08 (−4.05%)117.57 (−7.72%)24.59 (5.15%)15.69 (−7.13%)24.42124.599.53 (−1.90%)
Average1.2321.90132.9323.4816.8825.01137.649.43
Note: # % change based on tX = 7 °C.
Table 9. Divergence results for different tX.
Table 9. Divergence results for different tX.
tX (°C)IASHRRMSESHR
40.66020.0545
50.66590.0538
60.66820.0535
70.67050.0532
80.66970.0534
90.66410.0541
100.66190.0543

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Bao, Y.; Lee, W.L.; Jia, J. Exergy Analyses and Modelling of a Novel Extra-Low Temperature Dedicated Outdoor Air System. Energies 2018, 11, 1165. https://doi.org/10.3390/en11051165

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Bao Y, Lee WL, Jia J. Exergy Analyses and Modelling of a Novel Extra-Low Temperature Dedicated Outdoor Air System. Energies. 2018; 11(5):1165. https://doi.org/10.3390/en11051165

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Bao, Yani, Wai Ling Lee, and Jie Jia. 2018. "Exergy Analyses and Modelling of a Novel Extra-Low Temperature Dedicated Outdoor Air System" Energies 11, no. 5: 1165. https://doi.org/10.3390/en11051165

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