State-of-Charge Estimation with State-of-Health Calibration for Lithium-Ion Batteries
Abstract
:1. Introduction
2. Definitions of SOH and SOC
3. Charging and Discharging Rates
4. Calibration Procedures
4.1. Regular Calibration
4.2. Partial Calibration
5. Estimation Error
6. Experimental Verifications
7. Conclusions and Discussions
- (1)
- The accepted/released charge of a battery depends on the charging/discharging current as well as the SOC. To identify the full capacity of a battery which has not been calibrated before, the C-rate has to be correctly normalized first. An accurate normalized C-rate can be simply obtained from several regular calibrations. For lithium-ion batteries, which are with relatively small internal impedances, only two subsequent calibrations are needed.
- (2)
- The error on SOC estimation is essentially caused by current integration as well as capacity degradation. The integrated error from an inaccurate current measurement of the charging/discharging cycles results in misjudgment of the full capacity. This error can be provisionally eliminated by resetting the SOC at 0% and 100% as the battery is fully exhausted and charged, respectively.
- (3)
- The coulombic efficiencies of lithium-ion batteries are high enough to neglect the trivial difference between the accepted charge and the released charge of two consecutive regular calibrations for charging and discharging phases. In other words, the full capacity can be updated by either the charging or discharging phase of a regular calibration. For other types of batteries that have lower coulombic efficiencies, calibrations in the charging and discharging phases may result in different cumulative full capacities. With different calculation bases, the SOC estimation for charging and discharging phases needs to be calculated separately. Nevertheless, the SOC estimation is still accurate when the batteries are operated at the same phase with the same calculation base.
- (4)
- For a battery’s SOH that has not been calibrated for a long time, the full capacity calculated from the first calibration may be incorrect. In this case, a further partial or regular calibration is needed to obtain a more accurate SOH.
- (5)
- The proposed approach can be used in battery testing systems for sorting new cells to acquire the nominal capacities more precisely. It can also be used for battery power systems that are capable of individually controlling the charging/discharging currents on batteries.
- (6)
- In this research, all experiments were carried out in room temperature, ranging from 26 °C to 30 °C. However, a different ambient temperature may lead to remarkably dissimilar accepted/released charges of a fully exhausted/charged battery, even under the same operating conditions. The effects of temperature must be considered for further improvement on the proposed approach.
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Nominal Battery Capacity | 2.3 Ah | Calibrated Initial Full Capacity, Qf | 1.997 Ah |
---|---|---|---|
Nominal voltage | 3.3 V | Cut-off voltage, Vc | 2.0 V |
CV level, VCV | 3.6 V | Cut-off current at CV stage | 0.1 C |
Parameters | Curve I | Curve II | Curve III | Curve X |
---|---|---|---|---|
Current measuring error | 0.3% | 0.3% | 0.3% | 0.0% |
Full capacity, Qf | 1.997 Ah | 1.997 Ah | 1.820 Ah | 1.700 Ah |
State-of-health, SOH | 100.00% | 100.00% | 91.14% | 85.13% |
Cycles | Curve I | Curve II | Curve III | Curve X |
---|---|---|---|---|
1–6 | 100.00% | 100.00% | 91.14% | 85.13% |
7–12 | 100.00% | 100.00% | 77.52% | 77.52% |
13–19 | 100.00% | 100.00% | 77.83% | 77.83% |
19–25 | 100.00% | 100.00% | 77.23% | 77.23% |
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Wu, T.-H.; Moo, C.-S. State-of-Charge Estimation with State-of-Health Calibration for Lithium-Ion Batteries. Energies 2017, 10, 987. https://doi.org/10.3390/en10070987
Wu T-H, Moo C-S. State-of-Charge Estimation with State-of-Health Calibration for Lithium-Ion Batteries. Energies. 2017; 10(7):987. https://doi.org/10.3390/en10070987
Chicago/Turabian StyleWu, Tsung-Hsi, and Chin-Sien Moo. 2017. "State-of-Charge Estimation with State-of-Health Calibration for Lithium-Ion Batteries" Energies 10, no. 7: 987. https://doi.org/10.3390/en10070987
APA StyleWu, T.-H., & Moo, C.-S. (2017). State-of-Charge Estimation with State-of-Health Calibration for Lithium-Ion Batteries. Energies, 10(7), 987. https://doi.org/10.3390/en10070987