Colorimetric Quantification Methods for Peracetic Acid together with Hydrogen Peroxide for Water Disinfection Process Control
Abstract
:1. Introduction
2. Materials and Methods
2.1. Chemicals
2.2. Sample Preparation and Analysis
2.2.1. ABTS Colorimetric Assay
2.2.2. DPD/Iodide Colorimetric Assay
2.2.3. TiO-Ox Colorimetric Assay
2.2.4. TiO-Ox:DPD/I− Colorimetric Assay
2.2.5. Samples
2.2.6. Iodometric Titration
2.3. Limit of Detection and Quantification of Analytical Methods
3. Results and Discussion
3.1. Principle
3.2. Selectivity of Colorimetric Reactions
3.2.1. Hydrogen Peroxide Reaction with TiO-Ox, DPD and ABTS
3.2.2. Peracetic Acid Reaction with TiO-Ox
3.2.3. Peracetic Acid Reaction with DPD/I−
3.2.4. Peracetic Acid Reaction with ABTS
3.3. Method Characterization
3.4. Suitability of Colorimetric Assay for Different Samples
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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ABTS Assay (mg·L−1) | DPD/I− Assay (mg·L−1) | TiO-Ox:DPD/I− Assay-PAA (mg·L−1) | TiO-Ox:DPD/I− Assay-H2O2 (mg·L−1) | TiO-Ox Assay (mg·L−1) | |
---|---|---|---|---|---|
LOD | 0.0425 | 0.0015 | 0.0024 | 0.0043 | 0.0080 |
LOQ | 0.0500 | 0.0025 | 0.0046 | 0.0091 | 0.0127 |
Maximum linearity | 30 | 3 | 2.5 | 5 | 75 |
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Chhetri, R.K.; Kaarsholm, K.M.S.; Andersen, H.R. Colorimetric Quantification Methods for Peracetic Acid together with Hydrogen Peroxide for Water Disinfection Process Control. Int. J. Environ. Res. Public Health 2020, 17, 4656. https://doi.org/10.3390/ijerph17134656
Chhetri RK, Kaarsholm KMS, Andersen HR. Colorimetric Quantification Methods for Peracetic Acid together with Hydrogen Peroxide for Water Disinfection Process Control. International Journal of Environmental Research and Public Health. 2020; 17(13):4656. https://doi.org/10.3390/ijerph17134656
Chicago/Turabian StyleChhetri, Ravi Kumar, Kamilla Marie Speht Kaarsholm, and Henrik Rasmus Andersen. 2020. "Colorimetric Quantification Methods for Peracetic Acid together with Hydrogen Peroxide for Water Disinfection Process Control" International Journal of Environmental Research and Public Health 17, no. 13: 4656. https://doi.org/10.3390/ijerph17134656