Removal of Sulfamethoxazole, Sulfathiazole and Sulfamethazine in their Mixed Solution by UV/H2O2 Process
Abstract
:1. Introduction
2. Materials and Methods
2.1. Chemicals and Reagents
2.2. Experimental Procedures
2.3. Analytical Methods
3. Results and Discussion
3.1. Comparison of Absorption Spectra of Target Compounds
3.2. Decomposition of Sulfonamides in the Mixed System
3.3. Effect of Initial Concentration of the Mixed Solution on Degradation Efficiency
3.4. Effect of UV Light Intensity on Degradation Efficiency
3.5. Effect of H2O2 Dosages on Degradation Efficiency
3.6. Effect of Initial Solution pH on Degradation Efficiency
3.7. Identification of Sulfonamides Degradation Intermediates
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Compound Name | Sulfamethoxazole | Sulfathiazole | Sulfamethazine |
---|---|---|---|
Acronym | SMZ | STZ | SMT |
Molecular formula | C10H11N3O3S | C9H9N3O2S2 | C12H14N4O2S |
Molecular weight (g/mol) | 253.3 | 255.3 | 278.3 |
Pka1 | 1.6 ± 0.2 | 2.2 ± 0.1 | 2.6 ± 0.2 |
Pka2 | 5.7 ± 0.2 | 7.2 ± 0.4 | 8 ± 1 |
Molecular structure | |||
Chemical speciation | |||
Reference | [16,21] | [7] | [27] |
Name | Retention Time (min) | Molecular Weight (MW) | Characteristic Ions | Molecular Structure |
---|---|---|---|---|
S1 | 1.666 | 189 | 190.0182,172.0045, 122.0243,109.0524 | |
S2 | 1.713 | 132 | 133.0609,72.0449 | |
S3 | 2.615 | 287 | 288.0661,156.0119, 108.0452,92.0504 | |
S4 | 2.843 | 98 | 99.0562,72.0462 | |
S5 | 2.785 | 215 | 216.0437,156.0113, 108.0444,92.0507, 65.0395 | |
S6 | 4.049 | 269 | 270.0556,172.0065, 124.0398,109.0528 | |
S7 | 2.882 | 269 | 270.0552,156.0116, 108.0446,92.0504 | |
S8 | 4.184 | 253 | 254.0608,156.0120, 108.0451,92.0505 |
Name | Retention Time (min) | Molecular Weight (MW) | Characteristic Ions | Molecular Structure |
---|---|---|---|---|
S1 | 2.033 | 139 | 140.0824,123.0558, 99.0563,82.0302 | |
S2 | 2.160 | 123 | 124.0878,107.0610,67.0314 | |
S3 | 2.965 | 214 | 215.1301,108.0689,198.1035 | |
S4 | 3.812 | 294 | 295.0875,124.0874, 186.0336,108.0450,172.0067 | |
S5 | 3.218 | 292 | 293.0718,212.0823,184.0876 | |
S6 | 3.984 | 278 | 279.0934,186.0347,124.0882, 108.0458,92.0512,156.0126 | |
S7 | 4.313 | 312 | 313.0537,186.0336, 142.0052,124.0864 |
Name | Retention Time (min) | Molecular Weight (MW) | Characteristic Ions | Molecular Structure |
---|---|---|---|---|
S1 | 1.692 | 100 | 101.0179,74.0078,58.9978 | |
S2 | 2.208 | 225 | 226.0662,124.0222, 151.0334 | |
S3 | 2.483 | 172 | 173.0318,93.0582 | |
S4 | 2.648 | 289 | 290.0274,156.0120, 108.0452,92.0507 | |
S5 | 3.423 | 271 | 272.0176,172.0069, 124.0400,108.0453 | |
S6 | 3.864 | 255 | 256.0217,156.0120, 108.0452,92.0506 | |
S7 | 3.900 | 269 | 270.0017,189.0123, 161.0174 |
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Zhu, G.; Sun, Q.; Wang, C.; Yang, Z.; Xue, Q. Removal of Sulfamethoxazole, Sulfathiazole and Sulfamethazine in their Mixed Solution by UV/H2O2 Process. Int. J. Environ. Res. Public Health 2019, 16, 1797. https://doi.org/10.3390/ijerph16101797
Zhu G, Sun Q, Wang C, Yang Z, Xue Q. Removal of Sulfamethoxazole, Sulfathiazole and Sulfamethazine in their Mixed Solution by UV/H2O2 Process. International Journal of Environmental Research and Public Health. 2019; 16(10):1797. https://doi.org/10.3390/ijerph16101797
Chicago/Turabian StyleZhu, Guangcan, Qi Sun, Chuya Wang, Zhonglian Yang, and Qi Xue. 2019. "Removal of Sulfamethoxazole, Sulfathiazole and Sulfamethazine in their Mixed Solution by UV/H2O2 Process" International Journal of Environmental Research and Public Health 16, no. 10: 1797. https://doi.org/10.3390/ijerph16101797