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Article

Selective Functionalization of High-Resolution Cu2O Nanopatterns via Galvanic Replacement for Highly Enhanced Gas Sensing Performance

1
Department of Chemical and Biomolecular Engineering (BK-21 Plus), Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-ro, Yuseong-gu, Daejeon 34141, Korea
2
Korea Advanced Institute of Science and Technology (KAIST) Institute for NanoCentury, 291 Daehak-ro, Yuseong-gu, Daejeon 34141, Korea
*
Author to whom correspondence should be addressed.
These authors contributed equally to this work.
Sensors 2018, 18(12), 4438; https://doi.org/10.3390/s18124438
Submission received: 21 November 2018 / Revised: 10 December 2018 / Accepted: 13 December 2018 / Published: 15 December 2018
(This article belongs to the Special Issue Functional Materials for the Applications of Advanced Gas Sensors)

Abstract

Recently, high-resolution patterned metal oxide semiconductors (MOS) have gained considerable attention for enhanced gas sensing performance due to their polycrystalline nature, ultrasmall grain size (~5 nm), patternable properties, and high surface-to-volume ratio. Herein, we significantly enhanced the sensing performance of that patterned MOS by galvanic replacement, which allows for selective functionalization on ultrathin Cu2O nanopatterns. Based on the reduction potential energy difference between the base channel material (Cu2O) and the decorated metal ion (Pt2+), Pt could be selectively and precisely decorated onto the desired area of the Cu2O nanochannel array. Overall, the Pt-decorated Cu2O exhibited 11-fold higher NO2 (100 ppm) sensing sensitivity as compared to the non-decorated sensing channel, the while the channel device with excessive Pt doping showed complete loss of sensing properties.
Keywords: gas sensor; nanopattern; chemical sensitization; galvanic replacement; p-type metal oxide; high-resolution gas sensor; nanopattern; chemical sensitization; galvanic replacement; p-type metal oxide; high-resolution

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MDPI and ACS Style

Kim, J.Y.; Cho, S.-Y.; Jung, H.-T. Selective Functionalization of High-Resolution Cu2O Nanopatterns via Galvanic Replacement for Highly Enhanced Gas Sensing Performance. Sensors 2018, 18, 4438. https://doi.org/10.3390/s18124438

AMA Style

Kim JY, Cho S-Y, Jung H-T. Selective Functionalization of High-Resolution Cu2O Nanopatterns via Galvanic Replacement for Highly Enhanced Gas Sensing Performance. Sensors. 2018; 18(12):4438. https://doi.org/10.3390/s18124438

Chicago/Turabian Style

Kim, Ju Ye, Soo-Yeon Cho, and Hee-Tae Jung. 2018. "Selective Functionalization of High-Resolution Cu2O Nanopatterns via Galvanic Replacement for Highly Enhanced Gas Sensing Performance" Sensors 18, no. 12: 4438. https://doi.org/10.3390/s18124438

APA Style

Kim, J. Y., Cho, S.-Y., & Jung, H.-T. (2018). Selective Functionalization of High-Resolution Cu2O Nanopatterns via Galvanic Replacement for Highly Enhanced Gas Sensing Performance. Sensors, 18(12), 4438. https://doi.org/10.3390/s18124438

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