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Multi-Walled Carbon Nanotube-Doped Tungsten Oxide Thin Films for Hydrogen Gas Sensing

Department of Physics and Center of Nanoscience and Nanotechnology, Faculty of Science, Mahidol University, Ratchathewee, Bangkok 10400, Thailand
Nanoelectronics and MEMS Laboratory, National Electronics and Computer Technology Center, Klong Luang, Pathumthani 12120, Thailand
NANOTEC Center of Excellence at Mahidol University, National Nanotechnology Center, Thailand
Author to whom correspondence should be addressed.
Sensors 2010, 10(8), 7705-7715;
Received: 20 June 2010 / Revised: 15 July 2010 / Accepted: 30 July 2010 / Published: 17 August 2010
(This article belongs to the Special Issue Gas Sensors - 2010)
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In this work we have fabricated hydrogen gas sensors based on undoped and 1 wt% multi-walled carbon nanotube (MWCNT)-doped tungsten oxide (WO3) thin films by means of the powder mixing and electron beam (E-beam) evaporation technique. Hydrogen sensing properties of the thin films have been investigated at different operating temperatures and gas concentrations ranging from 100 ppm to 50,000 ppm. The results indicate that the MWCNT-doped WO3 thin film exhibits high sensitivity and selectivity to hydrogen. Thus, MWCNT doping based on E-beam co-evaporation was shown to be an effective means of preparing hydrogen gas sensors with enhanced sensing and reduced operating temperatures. Creation of nanochannels and formation of p-n heterojunctions were proposed as the sensing mechanism underlying the enhanced hydrogen sensitivity of this hybridized gas sensor. To our best knowledge, this is the first report on a MWCNT-doped WO3 hydrogen sensor prepared by the E-beam method. View Full-Text
Keywords: WO3; hydrogen sensor; nanochannels; E-beam evaporation; carbon nanotube WO3; hydrogen sensor; nanochannels; E-beam evaporation; carbon nanotube

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This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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Wongchoosuk, C.; Wisitsoraat, A.; Phokharatkul, D.; Tuantranont, A.; Kerdcharoen, T. Multi-Walled Carbon Nanotube-Doped Tungsten Oxide Thin Films for Hydrogen Gas Sensing. Sensors 2010, 10, 7705-7715.

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