Mono- and Dinuclear Carbonyl Dithiolene Complexes Related to the [FeFe]-Hydrogenases
Abstract
:1. Introduction
2. Results and Discussion
3. Materials and Methods
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
Appendix A
References
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2 | 3 | 4 | |
---|---|---|---|
Fe(1)-Fe(2) | 2.4834 (6) | 2.4772 (6) | |
P(1)-Fe(1) | 2.2496 (8) | 2.1651 (9) | 2.1621 (9) |
P(2)-Fe(1) | 2.1214 (9) | ||
S(1)-Fe(1) | 2.2852 (8) | 2.2762 (9) | 2.1762 (8) |
S(1)-Fe(2) | 2.2886 (8) | 2.2908 (9) | |
S(2)-Fe(1) | 2.2872 (8) | 2.2810 (9) | 2.1983 (8) |
S(2)-Fe(2) | 2.2742 (8) | 2.2667 (9) | |
C(1)-Fe(1) | 1.771 (3) | 1.786 (4) | 1.768 (3) |
C(2/3)-Fe(1) | 1.769 (3) | 1.778 (4) | |
C(4)-Fe(2) | 1.794 (3) | 1.789 (3) | |
C(5)-Fe(2) | 1.776 (3) | 1.793 (3) | |
C(6)-Fe(2) | 1.812 (3) | 1.811 (3) | |
C(7)-C(8) | 1.323 (4) | 1.329 (4) | 1.354 (4) |
Fe(1)-S(1)-Fe(2) | 65.77 (2) | 65.69 (3) | |
Fe(1)-S(2)-Fe(2) | 65.97 (2) | 66.01 (3) | |
C(1)-Fe(1)-S(1) | 90.95 (9) | 90.42 (11) | |
C(1)-Fe(1)-S(2) | 161.07 (10) | 163.16 (12) | 170.23 (10) |
C(2/3)-Fe(1)-S(1) | 156.84 (10) | 105.76 (12) | |
P(1)-Fe(1)-S(1) | 106.47 (3) | 156.95 (4) | 151.49 (4) |
P(2)-Fe(1)-S(1) | 116.47 (4) | ||
P(1)-Fe(1)-S(2) | 102.98 (3) | 95.07 (3) | |
P(2)-Fe(1)-S(2) | 96.24 (3) | ||
P(1)-Fe(1)-C(1) | 95.94 (10) | 87.60 (11) | 90.95 (11) |
P(2)-Fe(1)-C(1) | 93.47 (10) | ||
P(1)-Fe(1)-C(2/3) | 96.26 (9) | 97.27 (12) | |
P(1)-Fe(1)-P(2) | 93.98 (3) | ||
C(1)-Fe(1)-C(2/3) | 91.30 (3) | 97.09 (17) | |
S(1)-Fe(1)-S(2) | 79.80 (9) | 80.62 (3) | |
C(4)-Fe(2)-C(5) | 91.19 (13) | 90.11 (14) | |
C(4)-Fe(2)-S(1) | 91.50 (9) | 92.81 (10) | |
C(4)-Fe(2)-S(2) | 154.58 (10) | 146.25 (11) | |
C(5)-Fe(2)-S(1) | 159.48 (11) | 164.82 (11) | |
C(5)-Fe(2)-S(2) | 88.98 (9) | 88.71 (11) | |
C(6)-Fe(2)-Fe(1) | 149.44 (10) | 148.77 (11) | |
P(1)/C(3)-Fe(1)-Fe(2) | 153.93 (3) | 150.45 (12) |
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Kdider, M.; Elleouet, C.; Pétillon, F.Y.; Schollhammer, P. Mono- and Dinuclear Carbonyl Dithiolene Complexes Related to the [FeFe]-Hydrogenases. Molbank 2023, 2023, M1719. https://doi.org/10.3390/M1719
Kdider M, Elleouet C, Pétillon FY, Schollhammer P. Mono- and Dinuclear Carbonyl Dithiolene Complexes Related to the [FeFe]-Hydrogenases. Molbank. 2023; 2023(3):M1719. https://doi.org/10.3390/M1719
Chicago/Turabian StyleKdider, Mohamed, Catherine Elleouet, François Y. Pétillon, and Philippe Schollhammer. 2023. "Mono- and Dinuclear Carbonyl Dithiolene Complexes Related to the [FeFe]-Hydrogenases" Molbank 2023, no. 3: M1719. https://doi.org/10.3390/M1719