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Short Note

8-[4-(2-Hydroxypropane-2-yl)Phenyl]-1,3,4,4,5,7-Hexamethyl-4-Boron-3a,4a-Diaza-S-Indacene

1
Department of Physics, Novosibirsk State University, 1 Pirogov Street, 630090 Novosibirsk, Russia
2
Novosibirsk Institute of Organic Chemistry, 9 Lavrentiev avenue, 630090 Novosibirsk, Russia
*
Author to whom correspondence should be addressed.
Academic Editor: Luke R. Odell
Molbank 2021, 2021(4), M1286; https://doi.org/10.3390/M1286
Received: 15 September 2021 / Revised: 1 October 2021 / Accepted: 5 October 2021 / Published: 8 October 2021
(This article belongs to the Section Organic Synthesis)
During recent years, the BODIPY core became a popular scaffold for designing photoremovable protecting groups (PPG). In this paper, we report the synthesis of a new molecule—8-[4-(2-hydroxypropane-2-yl)phenyl]-1,3,4,4,5,7-hexamethyl-4-boron-3a,4a-diaza-S-indacene—by the treatment of meso-(4-CO2Me-phenyl)-BODIPY with excess of MeMgI. The product was characterized by 1H, 13C NMR and HRMS. The combination of BODIPY core with tertiary benzilyc alcohol might be promising for utilizing this molecule as visible light removable PPG.
Keywords: BODIPY; photoremovable protecting group; methylmagnesium iodide; tertiary alcohol BODIPY; photoremovable protecting group; methylmagnesium iodide; tertiary alcohol
MDPI and ACS Style

Zobnina, A.; Moskalensky, A.; Vorob’ev, A. 8-[4-(2-Hydroxypropane-2-yl)Phenyl]-1,3,4,4,5,7-Hexamethyl-4-Boron-3a,4a-Diaza-S-Indacene. Molbank 2021, 2021, M1286. https://doi.org/10.3390/M1286

AMA Style

Zobnina A, Moskalensky A, Vorob’ev A. 8-[4-(2-Hydroxypropane-2-yl)Phenyl]-1,3,4,4,5,7-Hexamethyl-4-Boron-3a,4a-Diaza-S-Indacene. Molbank. 2021; 2021(4):M1286. https://doi.org/10.3390/M1286

Chicago/Turabian Style

Zobnina, Anastasiya, Alexander Moskalensky, and Aleksey Vorob’ev. 2021. "8-[4-(2-Hydroxypropane-2-yl)Phenyl]-1,3,4,4,5,7-Hexamethyl-4-Boron-3a,4a-Diaza-S-Indacene" Molbank 2021, no. 4: M1286. https://doi.org/10.3390/M1286

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