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[Dicyclohexyl(sulfanylidene)-λ5-phosphanyl]methanol

1
Chemistry, School of Science, University of Waikato, Private Bag 3105, Hamilton, New Zealand
2
Research Centre for Crystalline Materials, School of Science and Technology, Sunway University, No. 5 Jalan Universiti, Bandar Sunway 47500, Selangor Darul Ehsan, Malaysia
*
Authors to whom correspondence should be addressed.
Molbank 2019, 2019(3), M1069; https://doi.org/10.3390/M1069
Received: 18 June 2019 / Revised: 27 June 2019 / Accepted: 28 June 2019 / Published: 2 July 2019
(This article belongs to the Section Structure Determination)
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Abstract

The title compound, [dicyclohexyl(sulfanylidene)-λ5-phosphanyl]methanol, Cy2P(=S)CH2OH (1), was obtained from the reaction between [Cy2P(CH2OH)2]Cl with one molar equivalent of NaOH and an excess of elemental sulfur (powdered). Characterization was by a single-crystal X-ray structure determination as well as IR, and 1D-NMR (1H, 13C{1H}, 31P{1H}), and 2D-NMR (DEPT-135 and HSQC) spectroscopy, ESI mass spectrometry, and elemental analysis. X-ray crystallography on Compound 1 shows the phosphorus atom to be tetrahedrally coordinated within a non-symmetric C3S donor set but with relatively minor distortions from the ideal geometry. In the molecular packing, hydroxyl-O–H⋯S(thione) hydrogen bonds led to supramolecular helical chains along the b-axis direction. View Full-Text
Keywords: phosphane sulfide; hydrogen bonding; ESI mass spectrometry; X-ray crystallography phosphane sulfide; hydrogen bonding; ESI mass spectrometry; X-ray crystallography
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Henderson, W.; Okpareke, O.C.; Azizan, A.H.S.; Tiekink, E.R.T. [Dicyclohexyl(sulfanylidene)-λ5-phosphanyl]methanol. Molbank 2019, 2019, M1069.

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